Article
Chemistry, Multidisciplinary
Laura Lamkowski, Daniel Komisarek, Klaus Merz
Summary: This study describes the successful synthesis of the pharmaceutical interesting metastable polymorph H of the API gamma-aminobutyric acid (GABA) using a controlled pH-based crystallization approach with acetic acid, a method previously accessible only through sublimation. It also presents the synthesis and single crystal characterization of a nonhydrated chiral [GABA-H] [malate] compound.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Infal Iqbal, Arshad Mehmood, Sajida Noureen, Claude Lecomte, Maqsood Ahmed
Summary: This study reports on a combined thermal analysis, variable temperature diffraction analysis, and X-ray charge density analysis of 2:2 nicotinic acid: gallic acid (NAGA) co-crystal, which provides insights into the dynamics of co-crystal growth. The transformation of precursor gallic acid monohydrate to gallic acid anhydrate upon heating leads to the disintegration of the co-crystal assembly. Electrostatic and topological analysis of intermolecular interactions in the co-crystal assembly were performed using experimental charge density analysis and compared with theoretical structure factors obtained from DFT calculations, resulting in excellent agreement. The co-crystallization begins with the formation of an NAMIDLINE HORIZONTAL ELLIPSISNA zwitterion backbone, followed by the binding of the hydrated gallic acid coformer via electrostatic interactions. This study highlights the importance of thermal analysis and in situ diffraction analysis combined with multipolar refinement in understanding co-crystal growth.
Article
Biotechnology & Applied Microbiology
Lei Sun, Yingguo Bai, Xiu Zhang, Cheng Zhou, Jie Zhang, Xiaoyun Su, Huiying Luo, Bin Yao, Yuan Wang, Tao Tu
Summary: Three recombinant GAD genes from Bacillus strains were identified and successfully expressed heterologously in Escherichia coli. Using the engineered E. coli strain as a whole-cell biocatalyst, the biosynthesis of GABA from L-Glu was achieved, showing potential for industrial production of GABA.
MICROBIAL CELL FACTORIES
(2021)
Article
Medicine, Research & Experimental
Nathaniel Miller, Michael Noller, Alex Yang, Edward D. McCoul, Anthony M. Tolisano, Charles A. Riley
Summary: This study comprehensively summarized and synthesized the existing evidence for lesser known uses of gabapentin and pregabalin in otolaryngology. The most promising potential uses identified were for improving swallowing, trismus, and narcotic overuse after radiation therapy. Additionally, GABA analogues showed potential in improving nonorganic voice disorders, but the benefit for globus pharyngeus related to laryngeal sensory neuropathy remains inconclusive.
Article
Nutrition & Dietetics
Yingchun Jin, Jie Tu, Xinyao Han, Jun Zhuo, Guanhui Liu, Yanhui Han, Hengjun Du, Jun Wang, Hang Xiao
Summary: The functional properties of mulberry leaves were improved by enriching them with gamma-aminobutyric acid (GABA). The application of sodium glutamate immersion, cold shock, and anoxic treatment significantly increased the GABA content and the quantity of active phenolics. The particle size of the GABA-enriched mulberry leaf powders affected their physical properties, release of active compounds, and antioxidant and inhibition abilities. The addition of powders effectively delayed the staling of bread without altering its taste.
FRONTIERS IN NUTRITION
(2022)
Article
Chemistry, Analytical
Xinying Ma, Huiping Lv, Meifeng Chen, Hua Liu, Shouqing Xue, Qi Zhu, Xueliang Wang
Summary: A highly sensitive sensor for determination of propyl gallate (PG) in foodstuffs was developed and demonstrated excellent specificity and good recoveries. The sensor has potential applications in food safety control.
MICROCHEMICAL JOURNAL
(2022)
Article
Environmental Sciences
Qing Shan, Minghui Liu, Rui Li, Qinghua Shi, Yan Li, Biao Gong
Summary: In this study, we investigated the role of GABA in crops and found that exogenous application or endogenous regulation of GABA by gene-editing technology can promote pesticide detoxification and enhance crop tolerance. This is achieved by regulating the GABA shunt pathway and polyamine pathway in plants. Additionally, we unexpectedly discovered that GABA promotes stomatal closure, reducing pesticide absorption.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Plant Sciences
Zainab Waris, Zahra Noreen, Anis Ali Shah, Sheeraz Usman, Adnan Noor Shah, Muhammad Rizwan, Ryan Casini, Hosam O. O. Elansary
Summary: The research shows that cadmium can enter plants easily from the soil solution and cause harmful effects, even at low concentrations. The experiment conducted on lettuce (Lactuca sativa) demonstrates that the addition of γ-aminobutyric acid (GABA) can mitigate the toxicity of cadmium by promoting plant growth and enhancing antioxidant enzyme activity.
JOURNAL OF PLANT GROWTH REGULATION
(2023)
Article
Plant Sciences
Xu Li, Xiaozhao Xu, Fei Shen, Wei Li, Changpeng Qiu, Ting Wu, Yi Wang, Xuefeng Xu, Zhenhai Han, Xinzhong Zhang
Summary: The study showed that in adult-phase cuttings, exogenous indole butyric acid (IBA) can significantly induce GABA accumulation and inhibit AR formation, which is not the case in juvenile-phase cuttings. GABA may impact AR formation by inhibiting polar auxin transport.
JOURNAL OF PLANT GROWTH REGULATION
(2021)
Article
Plant Sciences
Chujiang Zhou, Wanqi Dong, Shuwan Jin, Qingli Liu, Liyu Shi, Shifeng Cao, Saisai Li, Wei Chen, Zhenfeng Yang
Summary: The treatment of peach fruit with GABA can reduce chilling injury during cold storage by up-regulating the biosynthetic genes and candidate transcription factors related to ascorbic acid and glutathione.
FRONTIERS IN PLANT SCIENCE
(2022)
Article
Agriculture, Dairy & Animal Science
Zhen Wu, Pengyu Wang, Daodong Pan, Xiaoqun Zeng, Yuxing Guo, Guangsheng Zhao
Summary: The study demonstrated that GABA-enriched adzuki bean sprout fermented milk may alleviate and even prevent mild depression symptoms in mice by enhancing social interaction and pleasure derived from movement. The research also highlighted the involvement of the GABA(B)-cAMP-PKA-CREB signaling pathway and increased neurotransmitter levels in the hippocampus after treatment. This suggests a potential dietary therapy for chronic social stress.
JOURNAL OF DAIRY SCIENCE
(2021)
Article
Materials Science, Ceramics
Shao-Min Lin, Ya-Ling Yu, Ming-Feng Zhong, Huan Yang, Chen-Yang Zhang, Zhi-Jie Zhang, Wei Xu, Jiong-Yan Xie, Yu-Chun Qiu
Summary: The study investigated the effect of oxalic acid activation on gamma-Al2O3, revealing that activation could significantly reduce the formation temperature of alpha-Al2O3, facilitating the phase transformation process and promoting the formation of pentavalent aluminum in gamma-Al2O3, which increased reaction activity and lowered the formation temperature of alpha-Al2O3.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Applied
Zhendong He, Jing Zhao, Changqi Liu, Weiwei Li, Yaosong Wang
Summary: The study showed that adding different concentrations of GABA had significant effects on the physical properties of whey protein isolate films. Low concentrations of GABA improved hydration and thermal properties, while high concentrations of GABA caused impairment in these properties.
FOOD HYDROCOLLOIDS
(2022)
Review
Agriculture, Multidisciplinary
Jiarun Han, Xilian Zhao, Xin Zhao, Qi Wang, Ping Li, Qing Gu
Summary: This article provides a comprehensive review of the different sources, production methods, isolation and purification technologies, and applications of GABA. By gaining a deeper understanding of GABA, its full potential can be unlocked and further contribute to human health and well-being.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2023)
Article
Food Science & Technology
Pooja Pandey, Hari Niwas Mishra
Summary: In this study, gamma-aminobutyric acid (GABA) and Lactobacillus plantarum (LP) were co-encapsulated using spray drying in a biocompatible matrix. The optimal shell composition obtained by mixture design maintained the stability of microcapsules. The research showed that the produced microcapsules had high thermal stability and good viability of bacteria and GABA retention.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Pedro F. N. Souza, Jackson L. Amaral, Leandro P. Bezerra, Francisco E. S. Lopes, Valder N. Freire, Jose T. A. Oliveira, Cleverson D. T. Freitas
Summary: Through in silico methods, it was found that ACE2-derived peptides could potentially interfere with the interaction between SARS-CoV-2 and the ACE2 receptor, inhibiting virus entry into human cells and providing new directions for treating COVID-19.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2022)
Article
Biochemistry & Molecular Biology
Jackson L. Amaral, Jose T. A. Oliveira, Francisco E. S. Lopes, Cleverson D. T. Freitas, Valder N. Freire, Leonardo V. Abreu, Pedro F. N. Souza
Summary: This study identified three synthetic peptides that strongly interact with the main protease of SARS-CoV-2, potentially affecting its activity and virus replication. These peptides have no toxicity to human cells and could offer new perspectives in the treatment of COVID-19.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2022)
Article
Biochemistry & Molecular Biology
J. G. de Oliveira Neto, J. G. Silva Filho, E. M. Bittar, L. M. Silva, F. F. de Sousa, H. V. Domingos, L. V. Costa-Lotufo, A. S. Reis, A. O. dos Santos
Summary: A complex of chloro(glycinato-N,O)(1,10-phenanthroline-N,N ')-copper(II) trihydrate was synthesized and its properties were studied via various analytical methods. The complex exhibited potential antitumor activity in experimental colorectal cancer cells, confirming its cytotoxic effect.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2022)
Article
Spectroscopy
Ana Beatriz M. L. A. Tavares, Eudenilson L. Albuquerque
Summary: Inhibition of PD-1 and its ligands PD-L1 and PD-L2 by monoclonal antibodies pembrolizumab and nivolumab has shown breakthrough therapies in a wide range of cancers. However, little is known about their vibrational features. This study employed quantum chemistry calculations to explore the binding modes and vibrational properties of these antibody drugs using Raman scattering spectroscopy. The results provide insights into their harmonic vibrational wavenumbers, particularly in the range of 2,750 to 3,750 (1,200 to 1,750) cm(-1).
JOURNAL OF RAMAN SPECTROSCOPY
(2022)
Article
Materials Science, Multidisciplinary
Thaina Araujo Oliveira, Paloma Vieira Silva, Aldilene Saraiva-Souza, Jose Gadelha da Silva Filho, Eduardo Costa Girao
Summary: In this study, a set of nonconventional graphyne lattices inspired by sp(2) nanocarbon sheets, known as haeckelites, is proposed and their electronic properties are investigated using density functional theory methods. These lattices exhibit stability and metallic nature, but differ significantly from the original haeckelites in terms of electronic properties.
PHYSICAL REVIEW MATERIALS
(2022)
Article
Microbiology
Ito Liberato, Leticia A. Lino, Juan K. D. Souza, Joao B. A. Neto, Livia G. A. Sa, Vitoria P. F. Cabral, Cecilia R. Silva, Bruno C. Cavalcanti, Manoel O. Moraes, Valder N. Freire, Hello V. N. Junior, Claudia R. Andrade
Summary: The antifungal activity of gallic acid against fluconazole-resistant Candida strains was evaluated, and its potential mechanism of action was determined.
FUTURE MICROBIOLOGY
(2022)
Article
Multidisciplinary Sciences
Ana Beatriz M. L. A. Tavares, Eudenilson L. Albuquerque
Summary: This study investigates the binding of three different anticancer drugs to human serum albumin using a quantum chemistry approach. The results demonstrate the importance of quantum calculations in the drug design process and suggest that the interactions between HSA and ligands can be used to design new anticancer compounds. Furthermore, the multi-drug complex shows enhanced targeting ability compared to individual drugs.
ADVANCED THEORY AND SIMULATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
V. F. de Paula, M. I. F. Guedes, M. F. van Tilburg, I. G. P. Vieira, J. B. Silva, R. C. R. dos Santos, J. P. Echeverry, G. Costa, B. P. Silva, F. F. Maia, E. W. S. Caetano, V. N. Freire
Summary: UV-vis optical absorption measurements and Density Functional Theory (DFT) calculations were used to study the optical properties and electronic structure of ethanol solvated quercetin molecule and different hydrated forms of quercetin crystals. The results showed that anhydrous quercetin exhibited semiconductor behavior with a large direct bandgap, while hydrated forms had smaller indirect bandgaps and showed optical anisotropy.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Victor L. B. Franca, Jackson L. Amaral, Yandara A. Martins, Ewerton W. S. Caetano, Kellen Brunaldi, Valder N. Freire
Summary: Atrazine, a widely used herbicide, has been found to cause persistent contamination of water and soil due to its high resistance to degradation. It is associated with fertility issues, increased risk of prostate cancer, and birth defects. This study characterizes the binding of atrazine to human serum albumin (HSA) and identifies the most likely binding sites and the amino acid residues involved in the binding interactions.
CHEMICO-BIOLOGICAL INTERACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Jose Barbosa Silva, Juan Pablo Echeverry, Regina Claudia Rodrigues dos Santos, Valdir Ferreira de Paula Jr, Maria Izabel Florindo Guedes, Bruno Poti e Silva, Antoninho Valentini, Ewerton Wagner Santos Caetano, Valder Nogueira Freire
Summary: This study presents the growth of monoclinic gamma-aminobutyric acid (GABA) crystals from an aqueous ethanol solution. The crystal structure was confirmed to be monoclinic with space group P21/c using X-ray diffraction analysis. Thermal stability and melting point of the GABA crystal were investigated. Experimental characterization and DFT calculations were performed to understand the optical properties of GABA crystals. The monoclinic GABA crystal was found to have an indirect band gap semiconductor behavior with a gap value of 5.02 eV and the highest optical absorption in the 5-6 eV energy range.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Spectroscopy
E. K. S. Pinho, J. G. da Silva Filho, F. F. Sousa, P. T. C. Freire, J. A. Lima, A. O. dos Santos, P. F. F. Filho
Summary: In this study, L-histidinium hydrogen oxalate crystal was successfully synthesized using the slow solvent evaporation method, and its vibrational behavior under different pressures was investigated by Raman spectroscopy. A conformational phase transition was observed from the analysis of the band behavior within the pressure range of 1.5-2.8 GPa, characterized by the disappearance of lattice modes. A second phase transition, now of structural type, close to 5.1 GPa was also observed.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Review
Virology
Maria Karolaynne da Silva, Daniel Melo de Oliveira Campos, Shopnil Akash, Shahina Akter, Leow Chiuan Yee, Umberto Laino Fulco, Jonas Ivan Nobre Oliveira
Summary: This article reviews the advances of reverse vaccinology in designing mRNA vaccines against SARS-CoV-2, discussing the steps, in silico tools, challenges, and future directions for improvement.
Article
Biology
Juliana Tatiara da Costa Siqueira, Aryane Campos Reis, Juliana Mainenti Leal Lopes, Luiz Orlando Ladeira, Lyderson Facio Viccini, Humberto de Mello Brandao, Michele Munk, Saulo Marcal de Sousa
Summary: Carbon nanotubes (CNTs) are important nanomaterials with various applications, but their increased production and use raise concerns about their potential impacts on the environment. In this study, we assessed the cytogenotoxic potential of carboxylated multi-walled carbon nanotubes (MWCNT-COOH) and their influence on the methylation patterns of Lactuca sativa meristematic cells. Our results showed that MWCNT-COOH induced root elongation at lower concentrations and decreased seed germination at higher concentrations. Cytogenetic analysis revealed increased chromosomal aberrations and micronucleus frequency, suggesting genotoxic effects. Additionally, MWCNT-COOH altered cytosine methylation profiles, with hypermethylation at lower concentrations and hypomethylation at higher concentrations.
Article
Chemistry, Multidisciplinary
Eveline M. Bezerra, Erika C. de Alvarenga, Ricardo P. dos Santos, Jeanlex S. de Sousa, Umberto L. Fulco, Valder N. Freire, Eudenilson L. Albuquerque, Roner F. da Costa
Summary: Losartan, a widely used hypertension medication, acts as a selective antagonist of angiotensin II receptor to reduce blood pressure. In this study, we investigated the interaction between losartan and sACE enzyme using molecular docking assays and quantum biochemistry calculations. Our findings reveal a new mechanism of action that has important implications for understanding the effects of losartan on hypertension.
Correction
Chemistry, Physical
Chen Luo, Yan Shao, Hua Yu, Hong-zhi Ma, Yu-hao Zhang, Long Gu, Bo Yin, Ming-bo Yang
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Stefano Borocci, Armando Camerlingo, Felice Grandinetti, Maria Rutigliano, Nico Sanna
Summary: The complexes of He, Ne, Ar, Kr, and Xe with B3N3H6 were investigated using MP2, CCSD(T), and SAPT ab initio methods. The complexes can be described as mono-, di-, and tri-coordinated to the N atoms, with stability following the order N-mono < N-di < N-tri. The interactions are dominated by dispersion and the binding energies are within the range of 1 or 2 kcal mol(-1). The results were compared with a recent DFT study on larger BN sheets complexes [Phys. Chem. Chem. Phys. 24 (2022) 2554-2566.].
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
V. Nagarajan, R. Bhuvaneswari, R. Chandiramouli
Summary: In this study, stable phosphoborane was used as a sensor to detect isobutane and n-propane in Liquefied Petroleum Gas (LPG). Phosphoborane demonstrated structural stability and semiconducting nature, and exhibited promising adsorption properties for the LPG molecules.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Xiaoxi Xu, Zijiang Yang, Bayaer Buren, Maodu Chen
Summary: In this study, the time-dependent wave packet method was used to investigate the reaction channels and mechanisms of Ca+ + HD. The results show that the CaH+ + D reaction channel plays a primary role, which is consistent with experimental results. Complex forming and direct-abstraction reaction mechanisms exist in this reaction process.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Keshab Pandey, Hae Kyung Jeong
Summary: A free-standing silicon-carbon nanofiber composite film was synthesized and investigated for supercapacitor applications. It exhibited high specific capacitance, energy density, and power density. After 5000 cycles, the film showed excellent specific capacitance retention and Coulombic efficiency.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Xinyu Zhang, Haosong Li, Xiaoyu Cao, Jing Gao, Yong Wei, Jianzhuo Zhu
Summary: The evaporation behavior of nanosized water aggregations on two-dimensional electroneutral solid surfaces with different surface polar unit densities was investigated. The results showed that the evaporation rate changes non-monotonically with the surface polar unit density, and the minimum evaporation rate is obtained when the surface has a modest surface polar unit ratio of 66.7%.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Yanyan Xu, Rui Dai, Xiaojie Wang, Zhijun Qiao, Haowei Wen, Dianbo Ruan, Yuzuo Wang
Summary: This article presents an innovative solvothermal sodium insertion method for synthesizing Triphylite-NaFePO4, which demonstrates optimal electrochemical performance in sodium-ion batteries.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Meiyi Jiang, Kun Yang, Yancheng Liu, Li Yao
Summary: The geometric structure and electronic properties of transition metal M (M = Cu, Fe, Mn)-TiO2 (101) surface adsorbed by NO2 and N2O were calculated by density functional theory (DFT) and DFT + U theory. The results showed that the adsorption of NO2 and N2O on Mn and Fe atoms is more stable, and a large number of active electrons are formed around these atoms, facilitating the catalytic reactions.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Sergey A. Vyrko, Yulia G. Polynskaya, Nikita A. Matsokin, Andrey M. Popov, Andrey A. Knizhnik, Nikolai A. Poklonski, Yurii E. Lozovik
Summary: In this study, carbon nanobracelets, which are cyclic molecules composed of alternating polycyclic regions and double carbon chains, were investigated using spin-polarized density functional theory. The results show that carbon nanobracelets with odd number of monomers exhibit distinct electronic energy levels, band gaps, and carbon chain deformation compared to those with even number of monomers.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Chanchan Wang, Quan Yang, Yanzhi Ding, Xiaoyong Lu, Dong Tian
Summary: It has been found that the introduction of buffer layers improves the electrical performance of solid oxide fuel cells (SSOFCs). In this study, varying ratios of Gd-doped CeO2 were used as buffer layers in YSZ-based SSOFCs. The results demonstrate that the performance of SSOFCs is enhanced when a buffer layer is added, with the highest performance achieved using Ce0.8Gd0.2O2-delta (GDC20) as the buffer layer. This suggests that the use of GDC series buffer layers is an attractive strategy to optimize performance loss due to electrolyte-electrode interactions.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Wang Li, Yi-Fan Zhang, Jia-Bin Huang, Chang-Yang Wang, Feng Zhang, Jiu-Zhong Yang, Long Zhao
Summary: The gas-phase reaction of propargyl with vinylacetylene was investigated using synchrotron photoionization and molecular-beam mass spectrometry methodologies. The formation mechanisms of the resulting cyclic structures were examined using quantum computations. Two previously unidentified isomers were detected and identified for the first time.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Avijit Pramanik, Sanchita Kundu, Olorunsola Praise Kolawole, Kaelin Gates, Paresh Chandra Ray
Summary: This study investigates the influence of aspect ratio and quantum confinement on the single-photon and two-photon absorption cross-section of perovskite CsPbI3 nanorods. Experimental data shows that CsPbI3 nanorods have an extremely high two-photon absorption cross-section, significantly surpassing organic chromophores and other CsPbBr3 nanocrystals. Moreover, adjusting the aspect ratio can significantly enhance the absorption ability. Additionally, the study also reveals a moderate quantum confinement effect on the single-photon and two-photon absorption cross-section of the nanorods.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Hyon-Tae Pak, Jin-A Choe, Kyong-Sik Ju, Yong -Son Rim
Summary: Drug-loaded cellulose diacetate (CDA) membranes were prepared using different compositions of mixed solvent. The microstructure and performance of the membranes were investigated, and a method to predict drug release properties was proposed. The results showed that the composition of the mixed solvent significantly affected the overall performance of CDA membranes, and the release rates of drugs were related to Δdelta and the intrinsic viscosity of CDA.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Gabriella E. Ravin, E. Curotto
Summary: We have developed a systematic approach to optimize the training set sizes for neural networks in fitting ab initio potential energy surfaces. Using this approach, we have constructed several spectroscopic quality potential energy surfaces for [Li(H2)n]+, n = 1 - 9. The ground state properties have been computed for all the systems and selected states.
CHEMICAL PHYSICS LETTERS
(2024)
Article
Chemistry, Physical
Guohua Xu, Lei Xu, Feng Zhang, Chunling Yu, Yu Song
Summary: NiS1.03@Ni7S6/carbon composite was successfully prepared using corn stalk as a carbon source via a simple adsorption-sulphurization process. The composite exhibited a specific capacitance of 1554.6 F/g at 1 A/g as a supercapacitor electrode, with a capacitance retention rate of 80.4% after 5000 cycles. Furthermore, the NiS1.03@Ni7S6/carbon//AC asymmetric supercapacitor showed a high energy density of 41.2 Wh kg-1 at a power density of 750 W kg-1, and excellent cycling stability with 86.8% capacitance retention after 10,000 cycles.
CHEMICAL PHYSICS LETTERS
(2024)
