Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

Direct access to isoindolines through tandem Rh(iii)-catalyzed alkenylation and cyclization of N-benzyltriflamides

(2014) Neeraj Kumar Mishra et al.   CHEMICAL COMMUNICATIONS

Rh(III)-Catalyzed Oxidative Coupling of 1,2-Disubstituted Arylhydrazines and Olefins: A New Strategy for 2,3-Dihydro-1H-Indazoles

(2014) Sangil Han et al.   ORGANIC LETTERS

Palladium-Catalyzed Decarboxylative Acylation ofO-Phenyl Carbamates with α-Oxocarboxylic Acids at Room Temperature

(2013) Satyasheel Sharma et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(ii)-catalyzed decarboxylative acylation of phenylacetamides with α-oxocarboxylic acids via C–H bond activation

(2013) Jihye Park et al.   CHEMICAL COMMUNICATIONS

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

(2013) Mirim Kim et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Oxidant-Free Rh(III)-Catalyzed Direct C–H Olefination of Arenes with Allyl Acetates

(2013) Chao Feng et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Tandem C–H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

(2013) Ana Cajaraville et al.   ORGANIC LETTERS

Direct Functionalization Processes: A Journey from Palladium to Copper to Iron to Nickel to Metal-Free Coupling Reactions

(2012) James J. Mousseau et al.   ACCOUNTS OF CHEMICAL RESEARCH

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

(2012) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids

(2012) Minyoung Kim et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage

(2012) Yuto Hashimoto et al.   CHEMISTRY LETTERS

Ruthenium-Catalyzed C6-Propenylation Reactions of Substituted Pyridine Derivatives: Directed and Direct CH Activation

(2012) Yogesh Goriya et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper- and Phosphine-Ligand-Free Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes with Allylic Chlorides

(2012) Yan-Bo Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Cross-Coupling of Allylboronic Acid Pinacol Ester Derivatives with Aryl Halides via Pd-PEPPSI-IPent

(2012) Jennifer L. Farmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C(sp2)–H Bond Hydroxylation: Site-Selective C–O Bond Formation on Benzamides

(2012) Vedhagiri S. Thirunavukkarasu et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed Synthesis of Hydroxylated Arenes with Ester as an Effective Directing Group

(2012) Yiqing Yang et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C–H Functionalization

(2012) Yuto Hashimoto et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Highly Regio- and Stereoselective Ruthenium(II)-Catalyzed Direct ortho-Alkenylation of Aromatic and Heteroaromatic Aldehydes with Activated Alkenes under Open Atmosphere

(2012) Kishor Padala et al.   ORGANIC LETTERS

Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Stereospecific Copper-Catalyzed CH Allylation of Electron-Deficient Arenes with Allyl Phosphates

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

(2011) Shilu Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

(2011) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Acylation of Arylpyridines with Acyl Chlorides viaortho-Selective C–H Bond Cleavage

(2011) Takuya Kochi et al.   CHEMISTRY LETTERS

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C–H Bond Cleavage Directed by a Nitrogen-containing Group

(2011) Yuto Hashimoto et al.   CHEMISTRY LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C–H/N–H Bond Functionalizations

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

A Straightforward Synthetic Entry to Cleavamine-Type Indole Alkaloids by a Ring-Closing Metathesis−Vinyl Halide Heck Cyclization Strategy

(2011) M.-Lluïsa Bennasar et al.   ORGANIC LETTERS

Ruthenium-CatalyzedOrtho-Alkenylation of Aromatic Ketones with Alkenes by C–H Bond Activation

(2011) Kishor Padala et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage

(2011) Takumi Ueyama et al.   ORGANIC LETTERS

Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles

(2011) Lutz Ackermann et al.   Chemical Science

Ruthenium(IV) Complexes Featuring P,O-Chelating Ligands: Regioselective Substitution Directly from Allylic Alcohols

(2010) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Total Syntheses of Variecolortides A and B through an Unusual Hetero-Diels-Alder Reaction

(2010) Christian A. Kuttruff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Tryprostatins A and B

(2010) Takayuki Yamakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calcium-Catalyzed Friedel-Crafts Alkylation at Room Temperature

(2010) Meike Niggemann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2-Arylbenzofuran Derivatives fromMorus cathayana

(2009) Gang Ni et al.   JOURNAL OF NATURAL PRODUCTS

Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C−H Bond Cleavage

(2009) Takuya Kochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Prenylation of Aromatic and α,β-Unsaturated Carboxamides via Iridium-Catalyzed C−H Oxidative Addition−Allene Insertion

(2009) Yong Jian Zhang et al.   ORGANIC LETTERS

Enantioselective Iridium-Catalyzed Allylic Arylation

(2008) Damien Polet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fast and Highly Regioselective Allylation of Indole and Pyrrole Compounds by Allyl Alcohols Using Ru-Sulfonate Catalysts

(2008) Alexey B. Zaitsev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between Allylic Acetates and Arylboronic Acids

(2008) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RuCl3-Catalyzed Alkenylation of Aromatic C−H Bonds with Terminal Alkynes

(2008) Kai Cheng et al.   ORGANIC LETTERS

Picolinoxy Group, a New Leaving Group for anti SN2′ Selective Allylic Substitution with Aryl Anions Based on Grignard Reagents

(2008) Yohei Kiyotsuka et al.   ORGANIC LETTERS

Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes

(2008) Shuichi Oi et al.   TETRAHEDRON