Enantioselective organocatalytic oxidative enamine catalysis–1,5-hydride transfer–cyclization sequences: asymmetric synthesis of tetrahydroquinolines

A Branched Domino Reaction: Asymmetric Organocatalytic Two-Component Four-Step Synthesis of Polyfunctionalized Cyclohexene Derivatives

(2013) Xiaofei Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Merging organocatalysis with transition metal catalysis and using O2 as the oxidant for enantioselective C–H functionalization of aldehydes

(2013) Yong-Long Zhao et al.   CHEMICAL COMMUNICATIONS

Photoredox Activation for the Direct  -Arylation of Ketones and Aldehydes

(2013) M. T. Pirnot et al.   SCIENCE

Enantioselective decarboxylative aldol addition of β-ketoacids to isatins catalyzed by binaphthyl-modified organocatalyst

(2013) Chang Won Suh et al.   TETRAHEDRON LETTERS

Synthesis of Aromatic α-Aminoesters: Palladium-Catalyzed Long-Range Arylation of Primary C sp 3H Bonds

(2012) Sam Aspin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonnatural Amino Acid Synthesis by Using Carbon-Hydrogen Bond Functionalization Methodology

(2012) Ly Dieu Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Direct C sp 3H Functionalization of Ethers: A Highly Efficient Approach to Chiral Spiroethers

(2012) Zhi-Wei Jiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic C–H activation reactions

(2012) Subhas Chandra Pan   Beilstein Journal of Organic Chemistry

Oxidative Enamine Catalysis: Direct Catalytic Enantioselective β-Functionalization of Aldehydes

(2012) Jian Xiao   ChemCatChem

Total Synthesis of Polyene Natural Product Dihydroxerulin by Mild Organocatalyzed Dehydrogenation of Alcohols

(2012) Hexin Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective tert-Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer

(2012) Liujuan Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical Studies of the Asymmetric Binary-Acid-Catalyzedtert-Aminocyclization Reaction: Origins of the C sp 3H Activation and Stereoselectivity

(2012) Long Zhang et al.   Chemistry-An Asian Journal

C–H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1,2,3,4-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C–H Bonds

(2012) Paul A. Vadola et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(II) Triflate Catalyzed Amination and Aziridination of 2-Alkyl Substituted 1,3-Dicarbonyl Compounds

(2012) Thi My Uyen Ton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Dehydrogenative β′-Functionalization of β-Keto Esters with Indoles at Room Temperature

(2012) Mikko V. Leskinen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Methylene C(sp3)–H Bond Activation with a Pd(II) Catalyst

(2012) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp3)–H Bond Functionalization and Its Application to Formal Synthesis of (±)-Tetrahydropalmatine

(2012) Keiji Mori et al.   ORGANIC LETTERS

Direct oxidative conversion of 3-aryl propionaldehydes to 3-aryl acroleins promoted by SOMO catalysis

(2012) Jin Zhu et al.   TETRAHEDRON LETTERS

Enantio- and diastereoselective Michael addition reactions of α-cyanoketones to nitroalkenes catalyzed by binaphthyl-derived organocatalyst

(2012) Hyun Joo Lee et al.   TETRAHEDRON LETTERS

Organocatalytic enantioselective decarboxylative Michael addition of β-ketoacids to α,β-unsaturated ketones

(2012) Young Ku Kang et al.   RSC Advances

Oxidative and Enantioselective Cross-Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether

(2011) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Microwave-Assisted Organocatalytic Synthesis of Tetrahydroquinolines via Hydride Transfer and Cyclization

(2011) You-Kyung Kwon et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Enantioselective Gold-Catalyzed Functionalization of Unreactive sp3 CH Bonds through a Redox-Neutral Domino Reaction

(2011) Guanghua Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expeditious Construction of a Carbobicyclic Skeleton via sp3-C−H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process

(2011) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Indole Annulation Cascades

(2011) Michael C. Haibach et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Activation of Enantiotopic C(sp3)−Hydrogen by Means of Chiral Phosphoric Acid: Asymmetric Synthesis of Tetrahydroquinoline Derivatives

(2011) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Synthesis of Tetrahydroquinolines via Cobalt(II)-Catalyzed Tandem 1,5-Hydride Transfer/Cyclization

(2011) Weidi Cao et al.   ORGANIC LETTERS

Asymmetric sp3 C–H functionalization via a chiral Brønsted acid-catalyzed redox reaction for the synthesis of cyclic aminals

(2011) Yu-Ping He et al.   TETRAHEDRON LETTERS

Organocatalytic enantioselective β-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions

(2011) Shi-Lei Zhang et al.   Nature Communications

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzed Olefination ofsp3C−H Bonds

(2010) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic C−H Bond Functionalization via Tandem 1,5-Hydride Transfer/Ring Closure: Asymmetric Synthesis of Tetrahydroquinolines

(2010) Young Ku Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expeditious Synthesis of Benzopyrans via Lewis Acid-Catalyzed C−H Functionalization: Remarkable Enhancement of Reactivity by anOrthoSubstituent

(2010) Keiji Mori et al.   ORGANIC LETTERS

Enantio- and Diastereoselective Mannich-Type Reactions of α-Cyano Ketones withN-Boc Aldimines Catalyzed by Chiral Bifunctional Urea

(2009) Ju Hee Lee et al.   ADVANCED SYNTHESIS & CATALYSIS

Nickel-Catalyzed Formation of a Carbon-Nitrogen Bond at the β Position of Saturated Ketones

(2009) Satoshi Ueno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric Povarov reactions with 2- and 3-vinylindoles

(2009) Giulia Bergonzini et al.   CHEMICAL COMMUNICATIONS

Expeditious Construction of Quinazolines via Brønsted Acid-induced C–H Activation: Further Extension of “tert-Amino Effect”

(2009) Keiji Mori et al.   CHEMISTRY LETTERS

Organocatalytic Highly Enantio- and Diastereoselective Mannich Reaction of β-Ketoesters withN-Boc-aldimines

(2009) Young Ku Kang et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

(2009) Hua Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (−)-PNU-286607 by Asymmetric Cyclization of Alkylidene Barbiturates

(2009) J. Craig Ruble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines

(2009) Sandip Murarka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3C−H Bonds Catalyzed by Platinum Tetraiodide

(2009) Paul A. Vadola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins

(2009) Daisuke Shikanai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Synthesis of Dihydrobenzopyrans fromortho-Vinylaryl Akyl Ethers

(2009) Kevin M. McQuaid et al.   ORGANIC LETTERS

Functionalization of Csp3–H bond—Sc(OTf)3-catalyzed domino 1,5-hydride shift/cyclization/Friedel–Crafts acylation reaction of benzylidene Meldrum’s acids

(2009) Stuart J. Mahoney et al.   TETRAHEDRON LETTERS

Organocatalytic synthesis of quaternary stereocenter bearing a fluorine atom: enantioselective conjugate addition of α-fluoro-β-ketoesters to nitroalkenes

(2009) Yeonock Oh et al.   TETRAHEDRON LETTERS

Enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to α,β-unsaturated ketones catalyzed by chiral bifunctional organocatalysts

(2009) Hyoung Wook Moon et al.   TETRAHEDRON LETTERS

[1,5]-Hydride Transfer/Cyclizations on Alkynyl Fischer Carbene Complexes: Synthesis of 1,2-Dihydroquinolinyl Carbene Complexes and Cascade Reactions

(2008) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines

(2008) Qun-Sheng Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Tunable Bisphosphine Ligands and Their Application in Asymmetric Hydrogenation of Quinolines

(2008) Xiao-Bing Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Formation of Cyclic Aminals through a Brønsted Acid-Promoted Redox Process

(2008) Chen Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

(2008) Kevin M. McQuaid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Catalyzed Formation of Tetrahydroquinolines via an Intramolecular Redox Process

(2008) Sandip Murarka et al.   ORGANIC LETTERS

Synthesis of substituted 1,2,3,4-tetrahydroquinones by the Povarov reaction. New potentials of the classical reaction

(2008) V A Glushkov et al.   RUSSIAN CHEMICAL REVIEWS

Rapid synthesis of the tetrahydroquinoline alkaloids: angustureine, cuspareine and galipinine

(2008) Aisling O'Byrne et al.   TETRAHEDRON

Recent synthetic developments in a powerful imino Diels–Alder reaction (Povarov reaction): application to the synthesis of N-polyheterocycles and related alkaloids

(2008) Vladimir V. Kouznetsov   TETRAHEDRON

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals

(2007) Chen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY