Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Generation of Stereochemically Defined Tetrasubstituted Enolborinates by 1,4-Hydroboration of α,β-Unsaturated Morpholine Carboxamides with (Diisopinocampheyl)borane

(2013) Christophe Allais et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Concise Total Synthesis of (R)-Puraquinonic Acid

(2013) Erica A. Tiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All-Carbon Quaternary Stereogenic Centers in Acyclic Systems

(2013) Pierre-Olivier Delaye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and stereoselective carbometallation reactions ofN-alkynylamides and sulfonamides

(2013) Yury Minko et al.   Beilstein Journal of Organic Chemistry

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

NHC-Promoted Asymmetric β-Lactone Formation from Arylalkylketenes and Electron-Deficient Benzaldehydes or Pyridinecarboxaldehydes

(2013) James Douglas et al.   JOURNAL OF ORGANIC CHEMISTRY

Merging allylic carbon–hydrogen and selective carbon–carbon bond activation

(2013) Ahmad Masarwa et al.   NATURE

Stereodefined trisubstituted enolates as a unique entry to all-carbon quaternary stereogenic centers in acyclic systems

(2013) Yury Minko et al.   Nature Protocols

Oxenoids in organic synthesis

(2013) Yury Minko et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Simple, Scalable Synthetic Route to (+)- and (−)-Pseudoephenamine

(2013) Kevin T. Mellem et al.   ORGANIC LETTERS

The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic Systems

(2013) Morgane Pasco et al.   ORGANOMETALLICS

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

A Concise and Versatile Double-Cyclization Strategy for the Highly Stereoselective Synthesis and Arylative Dimerization of Aspidosperma Alkaloids

(2012) Jonathan William Medley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pseudoephenamine: A Practical Chiral Auxiliary for Asymmetric Synthesis

(2012) Marvin R. Morales et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynes

(2012) Yury Minko et al.   NATURE

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Mechanisms of Nucleophilic Organocopper(I) Reactions

(2011) Naohiko Yoshikai et al.   CHEMICAL REVIEWS

Combined Carbometalation–Zinc Homologation–Allylation Reactions as a New Approach for Alkoxyallylation of Aldehydes

(2011) Tom Mejuch et al.   ORGANIC LETTERS

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products

(2009) Elizabeth A. Ilardi et al.   CHEMICAL SOCIETY REVIEWS

A unique approach to aldol products for the creation of all-carbon quaternary stereocentres

(2009) Jaya Prakash Das et al.   Nature Chemistry

Studies Toward the Synthesis of Spirolides: Assembly of the Elaborated E-Ring Fragment

(2009) Craig E. Stivala et al.   ORGANIC LETTERS

Stereoselective Formation of α-Quaternary Stereocenters in the Mannich Reaction

(2009) Erica A. Tiong et al.   ORGANIC LETTERS

Organocatalytic Formation of Quaternary Stereocenters

(2009) Marco Bella et al.   SYNTHESIS-STUTTGART

A Shift in Retrosynthetic Paradigm

(2008) Ilan Marek   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Substituted Enol Derivatives From Terminal Alkynes and Their Synthetic Utility

(2008) John R. DeBergh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrolled Alkylative Construction of Quaternary Carbon Centers

(2008) David A. Kummer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (+)-Pinnatoxin A

(2008) Craig E. Stivala et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY