Applications of pentafluorophenyl boron reagents in the synthesis of heterocyclic and aromatic compounds

Dibenzopentalenes from B(C6F5)3-Induced Cyclization Reactions of 1,2-Bis(phenylethynyl)benzenes

(2013) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

(2013) Miguel Yus et al.   CHEMICAL REVIEWS

Cyclisation versus 1,1-Carboboration: Reactions of B(C6F5)3with Propargyl Amides

(2013) Rebecca L. Melen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cycloaddition reactions between dicyclohexylboron azide and alkynes

(2013) Rebecca L. Melen et al.   DALTON TRANSACTIONS

Boron azides in Staudinger oxidations and cycloadditions

(2013) Rebecca L. Melen et al.   DALTON TRANSACTIONS

Borata–alkene derivatives conveniently made by frustrated Lewis pair chemistry

(2013) Juri Möbus et al.   DALTON TRANSACTIONS

Facile 1,1-Carboboration Reactions of Acetylenic Thioethers

(2013) Christina Eller et al.   ORGANOMETALLICS

Facile 1,1-Carboboration Reaction of a Diarylphosphino-substituted Conjugated Diyne with Tris(pentafluorophenyl)borane

(2013) Philipp Feldhaus et al.   ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

Gold-Catalyzed Synthesis of Dibenzopentalenes - Evidence for Gold Vinylidenes

(2012) A. Stephen K. Hashmi et al.   ADVANCED SYNTHESIS & CATALYSIS

The 1,1-Carboboration of Bis(alkynyl)phosphanes as a Route to Phosphole Compounds

(2012) Juri Möbus et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic control in frustrated Lewis pair chemistry: adduct formation of intramolecular FLP systems with –P(C6F5)2 Lewis base components

(2012) Annika Stute et al.   DALTON TRANSACTIONS

Double Arylation of Acetylenedicarboxylate with B(C6F5)3

(2012) Hiroshi Nakatsuka et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carboboration Reactions of 1,2-Bis[(diarylphosphino)ethynyl]benzenes with Tris(pentafluorophenyl)borane

(2012) René Liedtke et al.   HELVETICA CHIMICA ACTA

Iodocyclization of o-Alkynylbenzamides Revisited: Formation of Isobenzofuran-1(3H)-imines and 1H-Isochromen-1-imines Instead of Lactams

(2012) Claudine Schlemmer et al.   JOURNAL OF ORGANIC CHEMISTRY

Regio- and Stereoselective Synthesis of Cyclic Imidates via Electrophilic Cyclization of 2-(1-Alkynyl)benzamides. A Correction

(2012) Saurabh Mehta et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Activation of H–H and Si–H Bonds by Boranes

(2012) Georgii I. Nikonov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

1,1-Carboboration Route to Substituted Naphthalenes

(2012) René Liedtke et al.   ORGANIC LETTERS

[3 + 2]-Dipolar Cycloaddition Reactions of an N-Heterocyclic Carbene Boryl Azide

(2012) Everett Merling et al.   ORGANIC LETTERS

Preparation of Dihydroborole Derivatives by a Simple 1,1-Carboboration Route

(2012) Andreas Feldmann et al.   ORGANOMETALLICS

Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C6F5)3 Pairs

(2012) Tanja Voss et al.   ORGANOMETALLICS

Alkenylborane-Derived Frustrated Lewis Pairs: Metal-Free Catalytic Hydrogenation Reactions of Electron-Deficient Alkenes

(2012) J. Sreedhar Reddy et al.   ORGANOMETALLICS

Transition metal-catalyzed addition of C-, N- and O-nucleophiles to unactivated C–C multiple bonds

(2012) Nitin T. Patil et al.   TETRAHEDRON

Frustrated Lewis pair olefin addition reactions: P-, N-, C- and H-based nucleophilic additions to an olefin-tethered borane

(2012) Xiaoxi Zhao et al.   Chemical Science

Characterization of Vinylgold Intermediates: Gold-Mediated Cyclization of Acetylenic Amides

(2011) Olga A. Egorova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Frustrated Lewis Pairs with Conjugated Ynones-Selective Hydrogenation of the Carbon-Carbon Triple Bond

(2011) Bao-Hua Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous π-Acid Catalysis with Metal Nanoparticles

(2011) Nitin T. Patil   ChemCatChem

Chemistry of a geminal frustrated Lewis pair featuring electron withdrawing C6F5 substituents at both phosphorus and boron

(2011) Annika Stute et al.   CHEMICAL COMMUNICATIONS

1,1-Carboboration

(2011) Gerald Kehr et al.   CHEMICAL COMMUNICATIONS

Synthesis and Reactivity of Alkynyl-Linked Phosphonium Borates

(2011) Xiaoxi Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold Catalysis: Products and Intermediates Obtained from N-Propargylcarboxamides Bearing Additional Substituents on Nitrogen

(2011) A. Stephen K. Hashmi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Cyclization of Nonterminal Propargylic Amides to Substituted Alkylideneoxazolines and -oxazines

(2011) A. Stephen K. Hashmi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions

(2011) Xiaoxi Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pair Reactions With Bis-Acetylenic Substrates: Exploring the Narrow Gap Separating Very Different Competing Reaction Pathways

(2011) René Liedtke et al.   ORGANOMETALLICS

6-Dimethylaminopentafulvene as a Lewis Base Component in Frustrated Lewis Pairs: Reversible Carbon–Carbon Coupling in FLP Chemistry

(2011) Bao-Hua Xu et al.   ORGANOMETALLICS

The Thioether–Methyleneborane (PhSCH2B(C6F5)2)2: Synthesis and Reactivity with Donors and Alkynes

(2011) Cheryl A. Tanur et al.   ORGANOMETALLICS

Electronic Control of Frustrated Lewis Pair Behavior: Chemistry of a Geminal Alkylidene-Bridged Per-pentafluorophenylated P/B Pair

(2011) Christoph Rosorius et al.   ORGANOMETALLICS

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

(2010) Cornelia M. Mömming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinaphthopentalenes: Pentalene Derivatives for Organic Thin-Film Transistors

(2010) Takeshi Kawase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkably variable reaction modes of frustrated Lewis pairs with non-conjugated terminal diacetylenes

(2010) Chao Chen et al.   CHEMICAL COMMUNICATIONS

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

CC Coupling by Thermolysis of Alkynyl Phosphonium Borates

(2010) Xiaoxi Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes

(2010) Tanja Voss et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zwitterionic Ladder Bis(arylethenyl)benzenes with Large Two-Photon Absorption Cross Sections

(2010) Aiko Fukazawa et al.   Chemistry-An Asian Journal

Fused Silacarbacycles Containing a Silole Unit: 1,2-Hydroboration and 1,1-Organoboration of Alkynyl(vinyl)silanes

(2010) Bernd Wrackmeyer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Structural Characterization of 9-Azido-9-Borafluorene: Monomer and Cyclotrimer of a Borole Azide

(2010) Sunanda Biswas et al.   INORGANIC CHEMISTRY

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds

(2010) Andrey Solovyev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Bond Activation by 1,1-Carboboration of Internal Alkynes

(2010) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

1,1-Carboboration of 1-Alkynes: A Conceptual Alternative to the Hydroboration Reaction

(2010) Chao Chen et al.   ORGANIC LETTERS

Addition of Enamines or Pyrroles and B(C6F5)3“Frustrated Lewis Pairs” to Alkynes

(2010) Meghan A. Dureen et al.   ORGANOMETALLICS

Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes

(2010) Meghan A. Dureen et al.   ORGANOMETALLICS

Synthesis of oxazoles through Pd-catalyzed cycloisomerization–allylation of N-propargylamides with allyl carbonates

(2010) Akio Saito et al.   TETRAHEDRON LETTERS

Synthesis and Reactions of Dibenzo[a,e]pentalenes

(2010) Masaichi Saito   Symmetry-Basel

Gold Catalysis: Isolation of Vinylgold Complexes Derived from Alkynes

(2009) A. Stephen K. Hashmi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Click Chemistry beyond Metal-Catalyzed Cycloaddition

(2009) C. Remzi Becer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Cyclization of Propargylic Amides: Mild Access to Oxazole Derivatives

(2009) Jan P. Weyrauch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ladder π-Conjugated Materials Containing Main-Group Elements

(2009) Aiko Fukazawa et al.   Chemistry-An Asian Journal

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Synthesis and Molecular Structure of Silole Derivatives Bearing Functional Groups on Silicon: 1,1-Organoboration of Dialkynylsilanes

(2009) Ezzat Khan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

(2009) Meghan A. Dureen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction

(2009) Cornelia M. Mömming et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphonium- and Borate-Bridged Zwitterionic Ladder Stilbene and Its Extended Analogues

(2008) Aiko Fukazawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study

(2008) András Stirling et al.   CHEMICAL COMMUNICATIONS

Solution structure, dynamics and speciation of perfluoroaryl boranes through 1H, 11B and 19F NMR spectroscopy

(2008) Tiziana Beringhelli et al.   COORDINATION CHEMISTRY REVIEWS

A Novel Addition Mechanism for the Reaction of “Frustrated Lewis Pairs” with Olefins

(2008) Yong Guo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Intramolecular Pd(II)-Catalyzed Cyclization of Propargylamides: Straightforward Synthesis of 5-Oxazolecarbaldehydes

(2008) Egle M. Beccalli et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(III) iminophosphorane complexes as catalysts in C–C and C–O bond formations

(2008) David Aguilar et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations

(2008) Dennis G. Hall   PURE AND APPLIED CHEMISTRY

Silver-Catalyzed Preparation of Oxazolines from N-Propargylamides

(2008) Michael Harmata et al.   SYNLETT