Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H2 activation

A coordination chemistry dichotomy for icosahedral carborane-based ligands

(2011) Alexander M. Spokoyny et al.   Nature Chemistry

Monophosphine-o-Carborane Sulfide as a Noninnocent Ligand for C,S, S,S′, and B,S,S′ Coordination Modes of Half-Sandwich Iridium and Rhodium Complexes

(2011) Zi-Jian Yao et al.   ORGANOMETALLICS

Neutral and zwitterionic half-sandwich Ir, Rh complexes supported by P,S-substituted o-carboranyl ligands: Synthesis, characterization and reactivity

(2010) Xian-Kuan Huo et al.   DALTON TRANSACTIONS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenation of imines by phosphonium borate zwitterions: a theoretical study

(2009) Timofei Privalov   DALTON TRANSACTIONS

Dehydrogenation of LGeH by a LewisN-Heterocyclic Carbene Borane Pair under the Formation of L′Ge and its Reactions with B(C6F5)3and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

An unexpected cluster opening upon the formation of electronically unsaturated η3-(cyclooctenyl)metallacarboranes of rhodium(III) and iridium(III) with sterically reduced [(PhCH2)2C2B9H9]2− ligand

(2009) Leonid S. Alekseev et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Hydrogen activation on organometallic complexes and H2 production, utilization, and storage for future energy

(2009) Gregory J. Kubas   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium–Ruthenium Complex

(2008) Tsuyoshi Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(κ2-P,S)Pt(benzyl) complexes derived from 1/3-PiPr2-2-StBu-indene: facile synthesis of carbanion- and borate-containing zwitterions

(2008) Kevin D. Hesp et al.   CHEMICAL COMMUNICATIONS

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

(2008) Huadong Wang et al.   CHEMICAL COMMUNICATIONS

A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C–C bond in ortho-carboranyl diphosphines

(2008) Jonathan P. H. Charmant et al.   DALTON TRANSACTIONS

A Study on the Coordinative Versatility of the Zwitterionic S,N,S Ligand EtNHC(S)­Ph2P=NPPh2C(S)NEt in Its Anionic, Neutral and Cationic Forms – Determination of Absolute pKa Values in CH2Cl2 of RhI Complexes

(2008) Massimiliano Delferro et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

New Cationic and Zwitterionic Cp*M(κ2-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation

(2008) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Heterolysis of H2Mediated by an M−S(Thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase

(2008) Yasuhiro Ohki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effects of Alkaline Earth Metal Ion Complexation on Amino Acid Zwitterion Stability: Results from Infrared Action Spectroscopy

(2008) Matthew F. Bush et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY