Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 91, Pages 11211-11213Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36197c
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Funding
- Grants-in-Aid for Scientific Research [21106002, 21106001, 12J05642] Funding Source: KAKEN
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We found that an integrated flow microreactor system enables the preparation of boronic esters bearing electrophilic functional groups using organolithium chemistry and that it allows for their use in Suzuki-Miyaura cross-coupling without intentionally added base. Based on this method, cross-coupling of two aryl halides bearing electrophilic functional groups was accomplished to obtain the corresponding biaryl compounds in one flow.
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