Review
Chemistry, Organic
Abhishek Pareek, Garima Singh, Srinivasarao Yaragorla
Summary: C-acylimines are compounds obtained through the reaction of glyoxals and amines, which exhibit similar structures to naturally occurring substances and have unique reactivity in the synthesis of nitrogen-containing cyclic compounds. Despite the lack of available reviews in this specific area, numerous synthetic methods have been developed.
ASIAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Natalia Szynkiewicz, Jaroslaw Chojnacki, Rafal Grubba
Summary: In this study, a simple synthesis method for mixed-valent phosphinophosphoranes was presented, and their properties were investigated. By reacting different ligands and reagents, phosphinophosphoranes with different structures could be obtained, allowing for the control of their properties. Through experiments and calculations, the properties of various compounds were compared.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Alex Moerman, E. Daiann Sosa Carrizo, Benjamin Theron, Helene Cattey, Pierre Le Gendre, Paul Fleurat-Lessard, Adrien T. Normand
Summary: A series of complexes with pincer-type ligands were synthesized via P-P bond cleavage reaction, which exhibited stereoselectivity and showed reactivity towards C???O bond activation and transmetallation.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Katarina Paskaruk, David J. H. Emslie, James F. Britten
Summary: This study investigates the products of the reaction between (Me2PCH2AlMe2)(2) and transition metal precursors, as well as the effect of reaction conditions on the products. The structures of the products are determined by crystallography.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Sneha Parambath, S. J. Jishnu Narayanan, Pattiyil Parameswaran
Summary: The structure, bonding, and reactivity of nitrogen-containing beryllium compounds were investigated at the theoretical level. It was found that the best bonding representation is an interaction between Be+ and the ligands. Both compounds exhibited high proton and hydride affinity, indicating their ambiphilic reactivity. These compounds showed exothermic reaction energy for adduct formation with electron donor ligands.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Thomas D. Hettich, Richard Rudolf, Christoph M. Feil, Nicholas Birchall, Martin Nieger, Dietrich Gudat
Summary: Unprecedented metalated phosphonite boranes were prepared from PH-substituted precursors and silyl amides. These compounds exhibited ambiphilic character and demonstrated synthetic potential as nucleophilic building blocks, leading to the synthesis of the first stannylated phosphonite representing a new structural motif in phosphine chemistry.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Shuo Wang, Han-Jung Li, Ting-Shen Kuo, Li-Ching Shen, Hsueh-Ju Liu
Summary: The synthesis and characterization of a series of divalent Ge and Sn compounds with an ambiphilic nature is described. These compounds are obtained by forcing divalent group 14 elements into a planar geometry using a sterically constrained pincer-type ligand. The reactions of these compounds with various Lewis bases and acids are investigated, showing formation of both dimeric and monomeric species.
Article
Chemistry, Organic
Dean D. Roberts, Mark G. McLaughlin
Summary: In this study, a highly regioselective hydrosilylation of propargylic amines was described for the first time. The reaction utilizes a PtCl2/XantPhos catalyst system to deliver hydrosilanes across the alkyne, resulting in multifunctional allylic amines in high yields. The reaction is tolerant to a wide variety of functional groups and provides high value intermediates with two distinct functional handles, as shown through the synthesis of diverse ambiphilic aziridines.
Article
Chemistry, Multidisciplinary
Tian-Ming Liao, Wen-Jiang Ma, Yu-Ning Gao, Ming Bian, Min Jiang, Jin-Tao Liu, Hui-Yu Chen, Zhen-Jiang Liu
Summary: This study presents two green and facile protocols for the synthesis of polyfluoroalkanesulfinyl or alkylsulfinyl 4-isoxazolines. Various aldehyde and ketone derived nitrones reacted with alpha-alkynyl sulfoxides under catalyst- and solvent-free conditions at room temperature, providing a series of polyfluoroalkanesulfinyl or alkylsulfinyl 4-isoxazolines with high efficiency. The synthesis was further improved to a one-pot process in aqueous medium, eliminating the need for isolating the nitrones. These reactions offer easy and environmentally friendly methods for the preparation of sulfinyl 4-isoxazolines.
Article
Chemistry, Multidisciplinary
Chihiro Tsukano, Ryotaro Yagita, Takayoshi Heike, Tagwa A. Mohammed, Kazuya Nishibayashi, Kazuhiro Irie, Yoshiji Takemoto
Summary: In this study, the first total synthesis of shagenes A and B, tricyclic terpenoids containing a cis-substituted cyclopropane, was reported. The synthesis was achieved through ring-closing metathesis and Ir-catalyzed double-bond isomerization, with control over chemo- and diastereoselectivity in the distorted cis-substituted structures. The total synthesis also provided insights into the absolute configuration of shagenes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Han-Ying Liu, Ryan J. Schwamm, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Nasir A. Rajabi
Summary: The reactivity of copper-alumanyl complexes is dependent on the identity of the carbene co-ligand, suggesting an ambiphilicity in the Cu-Al interaction. This divergent reactivity with carbodiimides and CO2 implies a complex relationship between the two metals in the complex.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Inorganic & Nuclear
Zhao Zhao, Jingjie Tan, Ting Chen, Zahid Hussain, Yanguo Li, Yile Wu, Douglas W. Stephan
Summary: This study investigates the reactions of germylene chloride and germylene thiocyanate with phenylacetylene and B(C6F5)3, leading to the formation of different products due to the difference in their reactant structures. The results provide insights into the reactivity and bonding of these compounds.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Organic
Xiangyu Tan, Qianqian Gu, Xingjiang Yang, Yingying Yang, Bingwei Hu, Shuai Mao, Jun Lin, Yi Jin
Summary: Here, a Pd-catalyzed reaction for the selective and diastereoselective synthesis of dendralenc-functionalized dihydrofurans using allenyl acetates is described. Mechanistic studies revealed the formation of an epoxide from a carbonyl bond through cycloaddition, which has practical and mechanistic significance for the construction of other bioactive heterocyclic epoxides. The research also highlights the utility and potential of allenic esters as C2 synthons and 1,2-biselectrophiles in cycloaddition reactions.
Article
Chemistry, Multidisciplinary
Olaya Bernardo, Silvia Gonzalez-Pelayo, Israel Fernandez, Luis A. Lopez
Summary: The gold-catalyzed reaction of propargyl esters with alkynylsilanes produces vinylallene derivatives through consecutive [1,2]-acyloxy/[1,2]-silyl rearrangements. This transformation features good yields, full atom-economy, a broad substrate scope, easy scale-up, and low catalyst loadings. The reaction mechanism involves the generation of a gold vinylcarbene intermediate and a type II-Dyotropic rearrangement involving the silyl group and the metal fragment.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Haruo Matsuzaki, Norihiko Takeda, Motohiro Yasui, Mayuko Okazaki, Seishin Suzuki, Masafumi Ueda
Summary: A method for synthesizing N-alkyl-1H-1,2,4-triazoles from N,N-dialkylhydrazones and nitriles via a formal [3+2] cycloaddition including the C-chlorination/nucleophilic addition/cyclisation/dealkylation sequence was developed in this study. The in situ generation of hydrazonoyl chloride based on the ambiphilic reactivity of hydrazones allowed for the synthesis of various multi-substituted N-alkyl-triazoles in high yields. The synthetic utility of multi-substituted triazoles was further demonstrated by additional transformations.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Jesus Lopez, Maria Murillo, Gines Lifante-Pedrola, Eugenio Cantelar, Javier Gonzalez-Platas, Ulises R. Rodriguez-Mendoza, Pilar Amo-Ochoa
Summary: This study presents a detailed investigation of a one-dimensional coordination polymer with potential semiconductor behavior, showing luminescent properties under ambient conditions. The flexible and asymmetric structure of the polymer plays a crucial role in understanding its optoelectronic behavior, with strong mechanochromic behavior observed under pressure.
Article
Chemistry, Inorganic & Nuclear
Robin Turnbull, Javier Gonzalez-Platas, Fernando Rodriguez, Akun Liang, Catalin Popescu, Zhangzhen He, David Santamaria-Perez, Placida Rodriguez-Hernandez, Alfonso Munoz, Daniel Errandonea
Summary: The interplay between crystal structure and electronic structure in semiconductor materials is crucial for their potential technological applications. In this study, the high-pressure behavior of semiconducting antiferromagnetic material beta-Cu2V2O7 was investigated, revealing a pressure-induced phase transition to gamma-Cu2V2O7 below 4000 atm. The structural and electronic changes were studied using techniques such as single-crystal X-ray diffraction, absorption spectroscopy, and ab initio density functional theory calculations. These findings not only shed light on the potential barocaloric effects of beta-Cu2V2O7, but also suggest its significance as a multiferroic material with a decreased electronic band gap and a significant structural volume collapse.
INORGANIC CHEMISTRY
(2022)
Article
Medicine, Research & Experimental
Ruben L. Rodriguez-Exposito, Maria Reyes-Batlle, Ines Sifaoui, David Tejedor, Fernando Garcia-Tellado, Jose E. Pinero, Jacob Lorenzo-Morales
Summary: This study assessed the IC50 of isobenzofuranone derivatives against Acanthamoeba strains and identified two active derivatives with low IC50. Additionally, the study showed that both compounds triggered programmed cell death in Acanthamoeba strains.
BIOMEDICINE & PHARMACOTHERAPY
(2022)
Article
Biochemistry & Molecular Biology
Carlos J. Bethencourt-Estrella, Samuel Delgado-Hernandez, Atteneri Lopez-Arencibia, Desiree San Nicolas-Hernandez, David Tejedor, Fernando Garcia-Tellado, Jacob Lorenzo-Morales, Jose E. Pinero
Summary: Leishmaniasis is one of the most important tropical diseases, with approximately one million new cases each year. Current treatments are not fully effective and are toxic, so there is a need to develop new therapies that are more effective and less toxic. This study found that certain acrylonitrile derivatives have good selectivity in killing Leishmania parasites and induce programmed cell death.
BIOORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Daniel Diaz-Anichtchenko, Enrico Bandiello, Javier Gonz ales-Platas, Akun Liang, Zhangzhen He, Daniel Errandonea, Catalin Popescu, Alfonso Mun, Placida Rodriguez-Hernandez
Summary: Metal vanadates MxV2O5-x, are compounds of technological interest for energy storage and photocatalysis. We report the high-pressure behavior of Co2V2O7 and find it to be structurally stable up to at least 6 GPa, attributed to the 6-fold coordination of the Co2+ atom. Co2V2O7 has an indirect band gap, which decreases under compression due to the shortening of the Co-O bonds. Ab initio simulations support and extend our findings.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Akun Liang, Javier Gonzalez-Platas, Robin Turnbull, Catalin Popescu, Ismael Fernandez-Guillen, Rafael Abargues, Pablo P. Boix, Lan-Ting Shi, Daniel Errandonea
Summary: The high-pressure crystal structure evolution of CH3NH3PbBr3 perovskite has been investigated using single-crystal X-ray diffraction and synchrotron-based powder X-ray diffraction. The study reveals two phase transitions in the crystal structure, with pressure affecting the lattice parameters and bandgap.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Organic
Tanausu Santos, Yaiza Perez-Perez, David S. Rivero, Raquel Diana-Rivero, Fernando Garcia-Tellado, David Tejedor, Romen Carrillo
Summary: Dynamic Covalent Chemistry (DCvC) plays an increasingly important role in supramolecular chemistry and materials science. In this study, we demonstrate the dynamic nature of the exchange between phenols and vinyl ethers. The fast exchange at room temperature and under mild conditions has been observed. The equilibrium constants and electronic effects of phenol substituents have been calculated. This novel incorporation into the DCvC toolbox holds great potential and has been successfully applied in the synthesis of a responsive molecular cage.
Article
Crystallography
Julia Torres, Javier Gonzalez-Platas, Carlos Kremer
Summary: The synthesis, crystal structures, and luminescence of two lanthanide polynuclear complexes with the general formula [Ln(2)(tda)(3)(H2O)(5)]center dot 3H(2)O (Ln = Sm, Eu; tda = thiodiacetato anion) have been investigated. The compounds were obtained by direct reaction of H(2)tda and lanthanide(III) chloride in an aqueous solution. The structure of the polymeric complexes contains Ln(III) ions in a tricapped trigonal prism geometry. The versatility of this ligand allows for different coordination modes and leads to the formation of thick 2D sheets. Direct excitation of the Ln(III) ions results in sharp luminescence emission in the solid state for both complexes.
Article
Crystallography
Javier Gonzalez-Platas, Ulises R. Rodriguez-Mendoza, Amagoia Aguirrechu-Comeron, Rita R. Hernandez-Molina, Robin Turnbull, Placida Rodriguez-Hernandez, Alfonso Munoz
Summary: A study on two isomorphous copper(I) halide compounds, [C8H6Cu2X2N2] (X = Br, I), was conducted using high-pressure single-crystal X-ray diffraction and luminescence experiments, as well as ab initio simulations. The experiments revealed pressure-dependent changes in the structural properties and emission bands of the compounds, which were also confirmed by the simulations. Notably, a second-order phase transition was observed around 3.3 GPa, accompanied by redshifts in the emission bands due to shortening of the Cu-Cu distances.
Article
Biochemistry & Molecular Biology
Javier Chao-Pellicer, Inigo Arberas-Jimenez, Samuel Delgado-Hernandez, Ines Sifaoui, David Tejedor, Fernando Garcia-Tellado, Jose E. Pinero, Jacob Lorenzo-Morales
Summary: This article discusses the research on primary amoebic meningoencephalitis (PAM) caused by the pathogenic amoeba Naegleria fowleri, as well as the treatment methods. The study found that QOET-51, QOET-59, QOET-64, QOET-67, QOET-72, QOET-77, and QOET-79 among the 46 synthesized compounds were the most effective molecules. Additionally, the study investigated the mechanism of action of these compounds.
ACS CHEMICAL NEUROSCIENCE
(2023)
Article
Crystallography
Mario Pacheco, Javier Gonzalez-Platas, Carlos Kremer, Miguel Julve, Francesc Lloret, Alicia Cuevas
Summary: Our research group investigates the coordination chemistry of rhenium(II) and its potential use in molecular magnetism. We prepared four novel Re(II) compounds and characterized them using various techniques. The crystal structures of these compounds consist of mononuclear [Re(NO)Br-4(L)](-) complex anions and NBu4+ cations. Cryomagnetic measurements showed quasi-magnetically isolated spin doublets with weak antiferromagnetic interactions at low temperatures. The magnetic behavior of Re(II) was influenced by ligand field, tetragonal distortion, spin-orbit coupling, and covalence effects, as well as intermolecular interactions.
Article
Chemistry, Inorganic & Nuclear
Maria Murillo, Reinhold Wannemacher, Juan Cabanillas-Gonzalez, Ulises R. Rodriguez-Mendoza, Javier Gonzalez-Platas, Akun Liang, Robin Turnbull, Daniel Errandonea, Gines Lifante-Pedrola, Andrea Garcia-Hernan, Jose I. Martinez, Pilar Amo-Ochoa
Summary: This work presents two isostructural Cu(I)-I 2-fluoropyrazine (Fpyz) luminescent and semiconducting 2D coordination polymers (CPs) with reversible luminescent response to temperature and pressure. The structural flexibility of the Cu(I)-I chain is significantly linked to the corresponding alterations in luminescence and conductivity under pressure and temperature changes. The CPs also show promising behavior as heterogeneous photocatalysts for persistent organic dyes.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Natalia M. Padial, Clara Chinchilla-Garzon, Neyvis Almora-Barrios, Javier Castells-Gil, Javier Gonzalez-Platas, Sergio Tatay, Carlos Marti-Gastaldo
Summary: Titanium-organic frameworks have intrinsic photoactivity and high stability, but the hydrolysis of Ti4+ cations limits their systematic design. Researchers have used heterobimetallic clusters as building units to design titanium frameworks with tunable porosity and interpenetration, achieving the highest reported gravimetric surface area for titanium(IV) MOFs.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Parasitology
Carlos J. Bethencourt-Estrella, Samuel Delgado-Hernandez, Atteneri Lopez-Arencibia, Desiree San Nicolas-Hernandez, David Tejedor, Fernando Garcia-Tellado, Jacob Lorenzo-Morales, Jose E. Pinero
Summary: Chagas disease is a serious illness that can cause megacolon, heart disease, and even death. Current therapies for this disease are outdated and have significant side effects. Therefore, there is a need to search for new compounds that are safer, less toxic, and more effective against the parasite. This study investigated the antichagasic activity of 46 novel cyanomethyl vinyl ether derivatives and identified four compounds that showed selective activity and triggered programmed cell death in the parasites, making them potential candidates for future Chagas disease therapeutics.
INTERNATIONAL JOURNAL FOR PARASITOLOGY-DRUGS AND DRUG RESISTANCE
(2023)
Article
Materials Science, Multidisciplinary
Tania Garcia-Sanchez, Samuel Gallego-Parra, Akun Liang, Jose Luis Rodrigo-Ramon, Alfonso Munoz, Placida Rodriguez-Hernandez, Javier Gonzalez-Platas, Juan angel Sans, Vanesa Paula Cuenca-Gotor, Hussien H. Osman, Catalin Popescu, Veaceslav Ursaki, Ion M. Tiginyanu, Daniel Errandonea, Francisco Javier Manjon
Summary: The effect of pressure on the structural, vibrational, and optical properties of room-temperature crystallized PbGa2S4 is investigated. X-ray diffraction, Raman scattering, and optical-absorption measurements are conducted at pressures beyond 20 GPa, and the results are compared to ab initio calculations and related compounds. The study reveals a partially reversible pressure-induced decomposition of PbGa2S4 into a mixture of Pb6Ga10S21 and Ga2S3 above 15 GPa, offering a route for the high-pressure synthesis of Pb6Ga10S21, which is isostructural to the stable Pb6In10S21 compound.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Review
Chemistry, Multidisciplinary
Dan He, Yawen Li, Fuwen Zhao, Yuze Lin
Summary: High trap density in organic solar cells leads to localized charge carriers and reduced carrier lifetime, limiting device efficiency. This feature article summarizes the recent advances of trap suppression by material design and device engineering.
CHEMICAL COMMUNICATIONS
(2024)
Review
Chemistry, Multidisciplinary
Olivier Monfort, Arshitha Madhusudhan, Martin Motola
Summary: This article presents the advantages of coupling photocatalysis and Fenton-based processes for environmental remediation and discusses their synergy. It critically examines the simultaneous triggering of these two processes and provides insights into research approaches. The study aims to enhance understanding of this complex process and highlight the potential integration of new catalysts in current wastewater treatment technology.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Manideepa Dhar, Chittaranjan Mishra, Avijit Das, Uttam Manna
Summary: An approach of 'polymerization of monomers in its aggregated form' has been introduced to tailor the water wettability of fibrous and porous substrates, achieving hydrophobicity to superhydrophobicity transition, as well as patterned wettability. This facile chemical method provides a durable coating with adjustable and patterned wettability for various potential applications.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Saswat Ranjan Bhoi, Chhanda Debnath, Shikha Gandhi
Summary: In this article, a novel catalytic reaction using Pd(0) and Bronsted acid is reported for the synthesis of biologically important imidazolidinone-fused N-heterocycles through redox-neutral intramolecular N-allylation of indoles and pyrroles with alkynes. This atom-economical method is applicable to a wide range of substrates and eliminates the need for leaving groups or oxidizing agents commonly used in traditional allylation reactions.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Longkun Chen, Mingshuai Zhang, Meichen Liu, Zhuoyuan Liu, Yuetong Qiu, Zhilai Zhang, Fuchao Yu, Jiuzhong Huang
Summary: In this study, an efficient Rh(III)-catalyzed selective mono- and dual-C-H bond functionalization/cyclization with iodonium ylide as the sole coupling partner was demonstrated. Fused benzodiazepine skeletons were obtained in excellent yields, providing an improved approach to dual C-H unsymmetrical functionalization.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Alice Kennett, Sven Epple, Gabriella van der Valk, Irene Georgiou, Evelyne Gout, Romain R. Vives, Angela J. Russell
Summary: This study presents the design and synthesis of sulfated disaccharide inhibitors based on IdoA(2S)-GlcNS(6S), which showed potent inhibition of Sulf-2. The results suggest that IdoA(2S)-GlcNS(6S) is the shortest fragment size required for effective inhibition of Sulfs, and a trisulfated disaccharide is identified as the minimal fragment size of heparan sulfate for effective endosulfatase inhibition.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Mauro Garbini, Andrea Brunetti, Riccardo Pedrazzani, Magda Monari, Massimo Marcaccio, Giulio Bertuzzi, Marco Bandini
Summary: The self-adaptability of galvanostatic electrolysis was found to be helpful in a multistage chemo- and diastereoselective electrochemically promoted cyclodimerization of chalcones. Through a series of reductive events, densely functionalized cyclopentanes with five contiguous stereocenters were obtained (25 examples, yields up to 95%, dr values up to >20:1). Further experimental and electrochemical investigations indicated the crucial role of dynamic kinetic resolution of the aldol intermediate in the reaction mechanism.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Dhananjay S. Nipate, Neha Meena, Prakash N. Swami, Krishnan Rangan, Anil Kumar
Summary: In this study, the synthesis of functionalized benzo[a]phenazines and indazolo[2,3-a]quinolines was achieved through Rh(III)-catalyzed oxidative annulation of 2-arylquinoxalines and 2-aryl-2H-indazoles with allyl alcohols. The method showed a wide substrate scope, excellent functional group tolerance, good to high yields of annulated products, and the capability for scaled-up synthesis. A tentative mechanism of the annulation reaction was proposed based on a preliminary mechanistic investigation.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan
Summary: A new lead tellurium borate material with a unique fundamental building block [B4O10] was synthesized and found to exhibit high birefringence. The structure-property relationship was discussed using first-principles calculations.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Amresh Kumar Singh, Baishali Thakurta, Anupam Giri, Monalisa Pal
Summary: This study introduces three key concepts for the quick synthesis of large-scale high-quality 2D materials films and their utilization in device fabrication.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Reina Hagiwara, Shun Nishimura, Kosuke Okeyoshi
Summary: A copolymer-conjugated nanocatalytic system has been developed to improve electron transfer and enhance photoinduced H2 generation.
CHEMICAL COMMUNICATIONS
(2024)
