4.7 Article

Unrefined wood hydrolysates are viable reactants for the reproducible synthesis of highly swellable hydrogels

Journal

CARBOHYDRATE POLYMERS
Volume 108, Issue -, Pages 281-290

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2014.02.060

Keywords

Hemicellulose; Biomass; Hydrogel; Renewable; Swelling; Wood hydrolysate

Funding

  1. FORMAS [2011-1542]

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A value-adding robust and sequential synthetic pathway was elaborated to produce hydrogel structures with ionic character from crude acetylated galactoglucomannan-rich wood hydrolysate (WH). The WH was first-step liquor originating from a sulphite cracking pulp process for dissolving pulp. The synthetically modified WH fractions were verified at each step by NMR and FTIR, and the hydrogels were characterized with respect to their swelling and mechanical properties. Altering the crosslinking chemistry and the content of ionic moieties resulted in hydrogels with various swelling ratios and mechanical properties. Renewable hydrogel formulations with swelling ratios as high as Q(eq) = 270 were achieved. (C) 2014 Elsevier Ltd. All rights reserved.

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