4.7 Article

Effect of CO2 sorption-induced anisotropic swelling on caprock sealing efficiency

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 103, Issue -, Pages 685-695

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2014.08.024

Keywords

Fracture-matrix system; Anisotropy; Two-phase flow within factures; CO2 diffusion; Anisotropic matrix swelling; Caprock sealing efficiency

Funding

  1. National Natural Science Funds for Distinguished Young Scholar of China [51125017]
  2. National Natural Science Foundation of China [51374213, 51404250]
  3. China Postdoctoral Science Foundation [2014M550316]
  4. State Basic Research Program of China [2010CB226804, 2011CB201201]

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Caprock sealing integrity is a key issue to CO2 sequestration in a saline aquifer over a long period. Caprock as a sealing layer is defined as water-saturated formation with a sufficient capillary entry pressure to prevent the upward migration of a buoyant fluid. Most caprocks are naturally anisotropic, hence the effect of CO2 sorption-induced anisotropic swelling may heavily impact their sealing efficiency. This paper proposes a numerical model based on a conceptual model for the investigation of the sealing efficiency of anisotropic caprocks, where caprock is a composite body of fracture network and shale matrix. Two-phase flow of brine water and CO2 is observed only in the fracture network but the CO2 in the fractures further diffuses into shale matrix through a much slower diffusion process and makes the shale matrix anisotropically swell or shrink, thus significantly altering the directional porosity and permeability of the fracture network. This numerical model is verified by a storage reservoir and applied to a caprock layer to explore the mechanism for self-enhancement or self-limiting in the CO2-brine mixing zone if anisotropic swelling is considered. These examples demonstrate that this model is able to numerically simulate the CO2 storage relevant geological systems within anisotropic shale. The sorption-induced anisotropic swelling of shale matrix has significant impacts on the caprock sealing efficiency. This work provides an alternative tool to enrich the numerical modeling for the assessment of CO2 caprock sealing efficiency in natural shale caprocks. (C) 2014 ElSevier Ltd. All rights reserved.

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