4.7 Article

Saturated CO2 absorption near 1.6 μm for kilohertz-accuracy transition frequencies

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 142, Issue 19, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4921557

Keywords

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Funding

  1. Universite Joseph Fourier (UJF) Pole SMINGUE
  2. LabexOSUG [ANR10 LABX56]
  3. Reseau FEMTO
  4. Italian Ministry of Research and Education

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Doppler-free saturated-absorption Lamb dips were measured on weak rovibrational lines of (CO2)-C-12-O-16 between 6189 and 6215 cm(-1) at sub-Pa pressures using optical feedback frequency stabilized cavity ring-down spectroscopy. By referencing the laser source to an optical frequency comb, transition frequencies for ten lines of the 30013 <- 00001 band P-branch and two lines of the 31113 <- 01101 hot band R-branch were determined with an accuracy of a few parts in 10(11). Involving rotational quantum numbers up to 42, the data were used for improving the upper level spectroscopic constants. These results provide a highly accurate reference frequency grid over the spectral interval from 1599 to 1616 nm. (C) 2015 AIP Publishing LLC.

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