4.6 Article

Where is the Ag in FePt-Ag composite films?

Journal

APPLIED PHYSICS LETTERS
Volume 98, Issue 13, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3574538

Keywords

-

Funding

  1. Ministry of Education, Singapore [T11-1001-P04]
  2. A*STAR under SERC [092 156 0118]
  3. Seagate Technology
  4. U.S. Office of Naval Research [N00014-06-1-0157]
  5. US Department of Energy-Basic Energy Sciences
  6. NSERC
  7. University of Washington
  8. Simon Fraser University
  9. Advanced Photon Source
  10. U.S. DOE [DE-AC02-06CH11357]

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The miscibility of Ag with FePt composited films was investigated with anomalous x-ray scattering (AXS) and extended x-ray absorption fine structure (EXAFS) at Ag K edge. In the AXS spectra for FePt Bragg peaks, the cusp near Ag K edge was observed, indicating alloying between Ag and FePt in the FePt-Ag thin films. Semiquantitative analysis showed 4.2 at. % and 5.9 at. % Ag were in FePt lattice for the samples with 20 vol % and 30 vol % Ag, respectively. EXAFS studies indicated in the alloyed FePt-Ag phase, Ag replaced the Fe sites in FePt lattice. Most of Ag segregated from FePt and formed fcc phase. This segregated Ag phase only had short range order, which may be due to that segregated Ag had small grain size and/or some disordered Ag phase existed in FePt grain boundaries. (C) 2011 American Institute of Physics. [doi:10.1063/1.3574538]

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