Article
Chemistry, Multidisciplinary
Vincent Grenier, Sylvain Finot, Bruno Gayral, Catherine Bougerol, Gwenole Jacopin, Joel Eymery, Christophe Durand
Summary: The strain relaxation of nonpolar GaN/Al0.6Ga0.4N multiple quantum wells in core-shell structure grown on GaN wires was investigated. Increasing the thickness of GaN QW and reducing the thickness of AlGaN barriers can effectively reduce crack density and keep the strain energy density below the relaxation limit of similar to 4 J/m(2).
CRYSTAL GROWTH & DESIGN
(2021)
Article
Chemistry, Physical
Sonachand Adhikari, Felipe Kremer, Mykhaylo Lysevych, Chennupati Jagadish, Hark Hoe Tan
Summary: GaN/AlGaN core-shell nanowires with various Al compositions have been grown on GaN nanowire array. The AlGaN shells have lower Al compositions than the gas phase input ratio. Defect-related luminescence has been observed in the AlGaN shells, with partial dislocations as the dominant defects. Growth of nonpolar m-plane AlxGa1-xN/AlyGa1-yN quantum wells on the sidewalls of the GaN nanowires shows excellent morphology and optical emission.
NANOSCALE HORIZONS
(2023)
Article
Chemistry, Multidisciplinary
Julien Bosch, Pierre-Marie Coulon, Sebastien Chenot, Marc Portail, Christophe Durand, Maria Tchernycheva, Philip A. Shields, Jesus Zuniga-Perez, Blandine Alloing
Summary: This paper proposes three different strategies, chemical, physical, or thermal etching, to remove the SiGaxNy layer on the sidewalls of GaN core-shell wires, thereby improving their optical quality. Chemical etching with H3PO4 enhances the emissive coverage and luminescence intensity, while removing deep-defect emissions from the high growth temperature.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Nanoscience & Nanotechnology
Irene Manglano Clavero, Christoph Margenfeld, Jonas Quatuor, Hendrik Spende, Lukas Peters, Ulrich T. Schwarz, Andreas Waag
Summary: Three-dimensional InGaN/GaN nano- and microstructures with high aspect ratios and large active sidewall areas are of great interest in optoelectronics. However, their optical performance can be negatively affected by gradients in thickness and peak emission wavelength along their sidewalls when grown by MOCVD. This study investigates the mechanisms causing these gradients and proposes means to alleviate them.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Jaime Segura-Ruiz, Damien Salomon, Andrei Rogalev, Joel Eymery, Benito Alen, Gema Martinez-Criado
Summary: Time-resolved cathodoluminescence is a crucial tool with high temporal and spatial resolution, while optical spectroscopic information can also be extracted using synchrotron pulses in a hard X-ray nanoprobe, through X-ray excited optical luminescence. This study used time-resolved X-ray microscopy to analyze individual core-shell InGaN/GaN multiple quantum well heterostructures deposited on GaN wires, revealing the importance of m-plane related multiple quantum well states in governing carrier dynamics and the influence of In incorporation in recombination rates. The experiment highlights the need for further investigations into the underlying mechanisms of optoelectronic nanodevices.
Review
Chemistry, Physical
Johanna Meier, Gerd Bacher
Summary: This review discusses the progress in device processing and analysis of LED devices based on three-dimensional core-shell microrods, emphasizing the potential of the 3D device architecture from an applications point of view.
Article
Nanoscience & Nanotechnology
A. Cros, A. Garcia Cristobal, K. Hestroffer, B. Daudin, J. Wang, F. Demangeot, R. Pechou
Summary: Analysis of electron-phonon coupling in GaN/AlN core-shell nanowires using Raman scattering excited at various UV wavelengths revealed different vibration modes of phonons under different excitations. The thickness of the AlN shell can be adjusted to tune the energy and character of the electronic bands in these nanowires.
Article
Materials Science, Multidisciplinary
Akanksha Kapoor, Vincent Grenier, Eric Robin, Catherine Bougerol, Gwenole Jacopin, Bruno Gayral, Maria Tchernycheva, Joel Eymery, Christophe Durand
Summary: A dual-color emission is achieved by combining two monolithic sets of core-shell multiple quantum wells (MQWs) grown on GaN microwires, showing blue and green emissions. Advanced structural characterization reveals the growth of two sets of MQWs and their color emission sources on m-plane sidewall surfaces. LED based on these core-shell MQWs can be fabricated with multiple color emission possibilities.
ADVANCED PHOTONICS RESEARCH
(2021)
Article
Physics, Multidisciplinary
Yingzhi Zhao, Lingyun Xie, Hedong Chen, Xingyu Wang, Yongjie Chen, Guofu Zhou, Richard Notzel
Summary: The novel n-InGaN/p-Cu2O nanowire photoanode, obtained through heterostructuring and doping concepts, significantly enhances the photocurrent for solar water splitting. The optimized core-shell structure, self-stabilized at positive voltage, combined with a NiOOH co-catalyst, boosts the photocurrent into a competitive range.
FRONTIERS IN PHYSICS
(2021)
Article
Chemistry, Physical
Aadil Waseem, Muhammad Ali Johar, Mostafa Afifi Hassan, Indrajit Bagal, Jun-Seok Ha, June Key Lee, Sang-Wan Ryu
Summary: Flexible and stable piezoelectric energy harvesters were successfully fabricated using polydimethylsiloxane-embedded m-axis GaN/Al2O3 core-shell nanowires transferred to indium-deposited flexible substrates. Optimizing the piezoelectric performance by controlling the Al2O3 shell thickness showed that a 6 nm thickness exhibited the maximum performance, with performance decreasing when the thickness was increased or decreased. The PEHs were effective in harvesting mechanical energy, even from static strain, and also demonstrated energy supply capabilities for operating a light emitting diode.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Applied
Vincent Grenier, Sylvain Finot, Lucie Valera, Joel Eymery, Gwenole Jacopin, Christophe Durand
Summary: A single wire UV-LED device was fabricated by integrating core-shell GaN/AlGaN multiple quantum wells (MQWs) in a p-n junction on the upper part of GaN microwires grown by silane-assisted metal organic vapor phase epitaxy. Rectifying diode-like behavior was demonstrated for both GaN and GaN/AlGaN p-n junctions without a MQW active region, with a weak leakage current attributed to an additional conduction path along wire sidewalls in the GaN/AlGaN core-shell heterostructure. Electroluminescence at 340 nm in UV-A was achieved by embedding a GaN (2.6 nm)/Al0.3Ga0.7N (3 nm) heterostructure in a GaN/Al0.3Ga0.7N p-n junction, and further reducing the well thickness to 0.9 nm and increasing the Al-content of barriers to 60% resulted in a decreased emission wavelength to 310 nm. UV-B emission based on single wire core-shell UV-LEDs was demonstrated in this work.
APPLIED PHYSICS LETTERS
(2022)
Article
Chemistry, Physical
Qingyuan Luo, Ronghuo Yuan, Yan-Ling Hu, Defa Wang
Summary: InxGa1-xN nanowires with core/shell structure grown on n-type Si substrate by Ni-assisted CVD method were studied for their photocatalytic properties. Thicker GaN shell was found to reduce photoactivity, and a strategy to improve performance was proposed.
APPLIED SURFACE SCIENCE
(2021)
Article
Physics, Multidisciplinary
Junchao Li, Huanqing Chen, Guo Yu, Menglai Lei, Shunkun Li, Xiaodong Hu
Summary: Room-temperature exciton-polariton is observed in GaN/InGaN core-shell microrods grown by metal-organic vapor phase epitaxy. A large Rabi splitting over 265 meV is demonstrated in the core-shell microrod structure. Room-temperature lasing in core-shell microrods is confirmed by power-dependent photoluminescence spectra. The lasing in the shell layer results to a modulated lasing wavelength and takes one step further to more stable polariton lasing in MQW core-shell microrods.
Article
Nanoscience & Nanotechnology
H. Zhang, V Piazza, V Neplokh, N. Guan, F. Bayle, S. Collin, L. Largeau, A. Babichev, F. H. Julien, M. Tchernycheva
Summary: The study investigated the origin of electrical inhomogeneities in an array of core-shell InGaN/GaN nanowires and proposed a solution by changing the contact architecture, which led to a significant increase in the yield of emitting nanowires. The impact of a potential barrier at the interface between the nanowire core and the radially grown n-doped layer on the performance of the array was analyzed using multiple scanning techniques.
Article
Chemistry, Multidisciplinary
Xingchen Pan, Hao Hong, Rongli Deng, Mingrui Luo, Richard Notzel
Summary: We studied the desorption of In during the growth of InGaN nanowires on Si, which resulted in a unique light emitter. As the growth temperature increased, uniform In-rich InGaN nanowires evolved into intermediate core-shell structures before transforming into pure GaN nanowires. Various characterization techniques were used to study the different InGaN nanowire structures. A growth model was developed to understand the growth regimes influenced by anisotropic In surface diffusion and desorption. The self-formed core-shell InGaN nanowires were identified as the active region of the red light-emitting diode.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Energy & Fuels
Chuanxiao Xiao, Chun-Sheng Jiang, John Moseley, John Simon, Kevin Schulte, Aaron J. Ptak, Steve Johnston, Brian Gorman, Mowafak Al-Jassim, Nancy M. Haegel, Helio Moutinho
Article
Energy & Fuels
Nancy M. Haegel, Chi-Wen Ke, Hesham Taha, Harvey Guthrey, Christopher M. Fetzer, Richard R. King
IEEE JOURNAL OF PHOTOVOLTAICS
(2017)
Article
Chemistry, Multidisciplinary
A. T. M. Golam Sarwar, Benjamin Leung, George T. Wang, Roberto C. Myers
CRYSTAL GROWTH & DESIGN
(2018)
Review
Optics
Yuji Zhao, Houqiang Fu, George T. Wang, Shuji Nakamura
ADVANCES IN OPTICS AND PHOTONICS
(2018)
Article
Nanoscience & Nanotechnology
Deborah L. McGott, Michael D. Kempe, Stephen Glynn, Nick Bosco, Teresa M. Barnes, Nancy M. Haegel, Colin A. Wolden, Matthew O. Reese
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Physics, Applied
G. Hao, A. Mosey, X. Jiang, A. J. Yost, K. R. Sapkota, G. T. Wang, X. Zhang, J. Zhang, A. T. N'Diaye, R. Cheng, X. Xu, P. A. Dowben
APPLIED PHYSICS LETTERS
(2019)
Article
Chemistry, Multidisciplinary
Sheng Liu, Aleksandr Vaskin, Sadhvikas Addamane, Benjamin Leung, Miao-Chan Tsai, Yuanmu Yang, Polina P. Vabishchevich, Gordon A. Keeler, George Wang, Xiaowei He, Younghee Kim, Nicolai F. Hartmann, Han Htoon, Stephen K. Doorn, Matthias Zilk, Thomas Pertsch, Ganesh Balakrishnan, Michael B. Sinclair, Isabelle Staude, Igal Brener
Article
Energy & Fuels
Matthew O. Reese, Stephen Glynn, Michael D. Kempe, Deborah L. McGott, Matthew S. Dabney, Teresa M. Barnes, Samuel Booth, David Feldman, Nancy M. Haegel
Editorial Material
Multidisciplinary Sciences
Nancy M. Haegel, Harry Atwater, Teresa Barnes, Christian Breyer, Anthony Burrell, Yet-Ming Chiang, Stefaan De Wolf, Bernhard Dimmler, David Feldman, Stefan Glunz, Jan Christoph Goldschmidt, David Hochschild, Ruben Inzunza, Izumi Kaizuka, Ben Kroposki, Sarah Kurtz, Sylvere Leu, Robert Margolis, Koji Matsubara, Axel Metz, Wyatt K. Metzger, Mahesh Morjaria, Shigeru Niki, Stefan Nowak, Ian Marius Peters, Simon Philipps, Thomas Reindl, Andre Richter, Doug Rose, Keiichiro Sakurai, Rutger Schlatmann, Masahiro Shikano, Wim Sinke, Ron Sinton, B. J. Stanbery, Marko Topic, William Tumas, Yuzuru Ueda, Jao van de lagemaat, Pierre Verlinden, Matthias Vetter, Emily Warren, Mary Werner, Masafumi Yamaguchi, Andreas W. Bett
Article
Materials Science, Multidisciplinary
Chuanxiao Xiao, Chun-Sheng Jiang, Jun Liu, Andrew Norman, John Moseley, Kevin Schulte, Aaron J. Ptak, Brian Gorman, Mowafak Al-Jassim, Nancy M. Haegel, Helio Moutinho
MICROSCOPY AND MICROANALYSIS
(2019)
Editorial Material
Materials Science, Multidisciplinary
Sarah R. Kurtz, Ashling (Mehdi) Leilaeioun, Richard R. King, Ian Marius Peters, Michael J. Heben, Wyatt K. Metzger, Nancy M. Haegel
Article
Chemistry, Multidisciplinary
Chuanxiao Xiao, Chun-Sheng Jiang, Kevin Blaine, Mahisha Amarasinghe, Eric Colegrove, Wyatt K. Metzger, Mowafak M. Al-Jassim, Nancy M. Haegel, Helio Moutinho
CELL REPORTS PHYSICAL SCIENCE
(2020)
Article
Electrochemistry
Trent R. Northen, Nancy Haegel, Daniel Sinars, Johney Green, Dawn Wellman, Daniel T. Schwartz
ELECTROCHEMICAL SOCIETY INTERFACE
(2019)
Article
Chemistry, Multidisciplinary
Prashun Gorai, Robert W. McKinney, Nancy M. Haegel, Andriy Zakutayev, Vladan Stevanovic
ENERGY & ENVIRONMENTAL SCIENCE
(2019)
Meeting Abstract
Chemistry, Multidisciplinary
George Wang
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2018)