Noble Metals in Polyoxometalates

Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

(2012) Maxim N. Sokolov et al.   CHEMICAL COMMUNICATIONS

3 d Metal Ions in Highly Unusual Eight-Coordination: The Phosphate-Capped Dodecapalladate(II) Nanocube

(2012) Maria Barsukova-Stuckart et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stabilization of High-Valence Ruthenium with Silicotungstate Ligands: Preparation, Structural Characterization, and Redox Studies of Ruthenium(III)-Substituted α-Keggin-Type Silicotungstates with Pyridine Ligands, [SiW11O39RuIII(Py)]5−

(2012) Masahiro Sadakane et al.   Chemistry-An Asian Journal

{AsW9O33}–{Mo3S4} based polyoxometalates including a metal–metal bond with Pd or Ni. Synthesis, structure and studies in solution

(2012) Sylvain Duval et al.   DALTON TRANSACTIONS

Synthesis and characterization of open and sandwich-type polyoxometalates reveals visible-light-driven water oxidation via POM-photosensitizer complexes

(2012) Pierre-Emmanuel Car et al.   GREEN CHEMISTRY

Cation-Induced Synthesis of New Polyoxopalladates

(2012) Zheng-Guo Lin et al.   INORGANIC CHEMISTRY

Bis[tetraruthenium(IV)]-Containing Polyoxometalates: [{RuIV4O6(H2O)9}2Sb2W20O68(OH)2]4– and [{RuIV4O6(H2O)9}2{Fe(H2O)2}2{β-TeW9O33}2H]−

(2012) Irina V. Kalinina et al.   INORGANIC CHEMISTRY

Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The “Oxo Wall” Stands

(2012) Kevin P. O’Halloran et al.   INORGANIC CHEMISTRY

Terminal Gold-Oxo Complexes

(2012) Rui Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand

(2012) Travis M. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Retraction

(2012) T. M. Anderson et al.   SCIENCE

Anhydrous pentaguanidinium dihydrogen nonavanado(IV)platinate(IV)

(2011) Hea-Chung Joo et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Synthesis and Characterization of the Dicopper(II)-Containing 22-Palladate(II)[CuII2PdII22PV12O60(OH)8]20−

(2011) Maria Barsukova-Stuckart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diamond-Shaped [Ag4]4+ Cluster Encapsulated by Silicotungstate Ligands: Synthesis and Catalysis of Hydrolytic Oxidation of Silanes

(2011) Yuji Kikukawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and characterization of [PW11O39Ir(H2O)]4−: successful incorporation of Ir into polyoxometalate framework and study of the substitutional lability at the Ir(iii) site

(2011) Maxim N. Sokolov et al.   CHEMICAL COMMUNICATIONS

Oxygenic polyoxometalates: a new class of molecular propellers

(2011) Andrea Sartorel et al.   CHEMICAL COMMUNICATIONS

Connecting ruthenium substituted Keggin-type tungstophosphates by oxotungstic bridges: Evidence for the steric effect of {RuL3}2+ (L3=η6-arene, (DMSO)3) fragments

(2011) Danielle Laurencin et al.   COMPTES RENDUS CHIMIE

Quantum chemical characterization of the generation of high-valent oxoruthenium species of Keggin type polyoxometalates: electronic structure and bonding features

(2011) Chun-Guang Liu et al.   DALTON TRANSACTIONS

Addition of N-Heterocyclic Carbenes to a Ruthenium(VI) Nitrido Polyoxometalate: a New Route to Cyclic Guanidines

(2011) Claire Besson et al.   INORGANIC CHEMISTRY

Noble Metals in Polyoxometalate Chemistry: Palladium-Containing Derivatives of the Monolacunary Keggin and Wells–Dawson Tungstophosphates

(2011) Natalya V. Izarova et al.   INORGANIC CHEMISTRY

A Cagelike Polyanion with a Ag+Enwrapped, [AgAs2Mo15O54]11−

(2011) Yanping Zhang et al.   INORGANIC CHEMISTRY

A Keggin-type polyoxotungstate-coordinated diplatinum(II) complex: Synthesis, characterization, and stability of the cis-platinum(II) moieties in dimethylsulfoxide and water

(2011) Masao Kato et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−

(2011) Feng Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Mechanism of Water Oxidation with Single-Site Ruthenium–Heteropolytungstate Complexes

(2011) Masato Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A first principles study of water oxidation catalyzed by a tetraruthenium-oxo core embedded in polyoxometalate ligands

(2011) Simone Piccinin et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The role of the heteroatom (X = SiIV, PV, and SVI) on the reactivity of {γ-[(H2O)RuIII(μ-OH)2RuIII(H2O)][X n+W10O36]}(8−n)− with the O2 molecule

(2011) Aleksey E. Kuznetsov et al.   THEORETICAL CHEMISTRY ACCOUNTS

Preparation and StructuralCharacterization of RuII-DMSO and RuIII-DMSO-substituted α-Keggin-type Phosphotungstates, [PW11O39RuIIDMSO]5- and [PW11O39RuIIIDMSO]4-, and Catalytic Activity for Water Oxidation

(2011) Masahiro Sadakane et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Redetermination of heptapotassium nonahydrogen bis[α-hexamolybdoplatinate(IV)] undecahydrate

(2010) Uk Lee et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Monopotassium monosodium hexahydrogen α-hexamolybdoplatinate(IV) undecahydrate

(2010) Uk Lee et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Polyoxometalates Made of Gold: The Polyoxoaurate [AuIII4AsV4O20]8−

(2010) Natalya V. Izarova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Noble-Metalate Bowl: The Polyoxo-6-vanado(V)-7-palladate(II) [Pd7V6O24(OH)2]6−

(2010) Natalya V. Izarova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

(2010) Claire Besson et al.   CHEMICAL COMMUNICATIONS

Photo-induced water oxidation with tetra-nuclear ruthenium sensitizer and catalyst: A unique 4 × 4 ruthenium interplay triggering high efficiency with low-energy visible light

(2010) Fausto Puntoriero et al.   CHEMICAL COMMUNICATIONS

Ruthenium polyoxometalate water splitting catalyst: very fast hole scavenging from photogenerated oxidants

(2010) Michele Orlandi et al.   CHEMICAL COMMUNICATIONS

Polyoxopalladates Encapsulating Yttrium and Lanthanide Ions, [XIIIPdII12(AsPh)8O32]5− (X=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)

(2010) Maria Barsukova et al.   CHEMISTRY-A EUROPEAN JOURNAL

A novel heptatungstovanadate fragment stabilized by organo-ruthenium group: [HVW7O28Ru(dmso)3]6−

(2010) Li-Hua Bi et al.   CRYSTENGCOMM

Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state

(2010) Massimiliano Delferro et al.   DALTON TRANSACTIONS

Preparation and electrocatalytic application of composites containing gold nanoparticles protected with rhodium-substituted polyoxometalates

(2010) Kamila M. Wiaderek et al.   ELECTROCHIMICA ACTA

Bonding Interactions between Nitrous Oxide (N2O) and Mono-Ruthenium Substituted Keggin-Type Polyoxometalates: Electronic Structures of Ruthenium/N2O Adducts

(2010) Chun-Guang Liu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

An thin film of the di-decatungstosilicate with a tetra-ruthenium(IV)-oxo core and its electrochemical properties

(2010) Huiyuan Ma et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Rugged water-oxidation anodes

(2010) Antoni Llobet   Nature Chemistry

Efficient water oxidation at carbon nanotube–polyoxometalate electrocatalytic interfaces

(2010) Francesca M. Toma et al.   Nature Chemistry

Synthesis and characterisation of novel ruthenium multi-substituted polyoxometalates: α,β-[SiW9O37Ru4(H2O)3Cl3]7−

(2010) J.A.F. Gamelas et al.   POLYHEDRON

Synthesis and Crystal Structure of the Palladium(IV) Polyoxomolybdate, K0.75Na3.75[PdMo6O24H3.5]·17H2O

(2010) Sarah Angus-Dunne et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Inorganic Cryptand: Size-Selective Strong Metallic Cation Encapsulation by a Disilicoicosatungstate (Si2W20) Polyoxometalate

(2009) Akihiro Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

What Does it Really Take to Stabilize Complexes of Late Transition Metals with Terminal Oxo Ligands?

(2009) Christian Limberg   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Are Particulate Noble-Metal Catalysts Metals, Metal Oxides, or Something In-Between?

(2009) James C. Goloboy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NMR Spectra of Terminal Oxo Gold and Platinum Complexes: Relativistic DFT Predictions

(2009) Alessandro Bagno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vicinal Dinitridoruthenium-Substituted Polyoxometalates γ-[XW10O38{RuN}2]6−(X=Si or Ge)

(2009) Claire Besson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photochemical Reduction of Carbon Dioxide Catalyzed by a Ruthenium-Substituted Polyoxometalate

(2009) Alexander M. Khenkin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical studies on nitrido ruthenium (VI) porphyrin and high valent ruthenium nitrido derivatives of Keggin typical polyoxometalate ([PW11O39{RuVIN}]4−): electronic structures and bonding features

(2009) Chun-Guang Liu et al.   DALTON TRANSACTIONS

Transition metal-substituted Dawson anions as chemo- and regio-selective oxygen transfer catalysts for H2O2 in the epoxidation of allylic alcohols

(2009) Andrew J. Stapleton et al.   DALTON TRANSACTIONS

Self-assembly of star-shaped heteropoly-15-palladate(II)

(2009) Natalya V. Izarova et al.   DALTON TRANSACTIONS

NMR Chemical Shifts of Metal Centres in Polyoxometalates: Relativistic DFT Predictions

(2009) Nina Vankova et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Solid State Structures of the Hydrogen-Bonded Hexamolybdoplatinate(IV) Tetramer [(PtMo6O24)4H23]9–and the Hexamolybdoplatinate(IV) Trimers [(PtMo6O24)3H16]8–and [(PtMo6O24)3H14]10–

(2009) Victor W. Day et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Electron Paramagnetic Resonance Investigation of Some 11-Tungstoruthenate(III) Polyoxoanions

(2009) Charles C. Rong et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity

(2009) Rui Cao et al.   INORGANIC CHEMISTRY

Reinvestigation of a Ru2-Incorporated Polyoxometalate Dioxygenase Precatalyst, “[WZnRu2III(H2O)(OH)(ZnW9O34)2]11−”: Evidence For Marginal, ≤0.2 Equivalents of Ru Incorporation Plus Faster Catalysis by Physical Mixtures of [RuII(DMSO)4Cl2] and the Parent Polyoxometalate [WZn3(H2O)2(ZnW9O34)2]12−

(2009) Aimee M. Morris et al.   INORGANIC CHEMISTRY

Nitrogen-Atom Transfer from [PW11O39RuVIN]4−to PPh3

(2009) Claire Besson et al.   INORGANIC CHEMISTRY

Heteropoly-13-Palladates(II) [PdII13(AsVPh)8O32]6−and [PdII13SeIV8O32]6−

(2009) Natalya V. Izarova et al.   INORGANIC CHEMISTRY

A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

(2009) Claire Besson et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Undecatungstophospho(aqua)ruthenate(II): One pot synthesis, characterization and non-solvent liquid phase aerobic oxidation of alkenes

(2009) Pragati Shringarpure et al.   INORGANICA CHIMICA ACTA

Large polytungstobismuthate aggregate linked by unusual silver–tungsten–bismuth cluster

(2009) Ling Zeng et al.   JOURNAL OF MOLECULAR STRUCTURE

Computational Studies of the Geometry and Electronic Structure of an All-Inorganic and Homogeneous Tetra-Ru-Polyoxotungstate Catalyst for Water Oxidation and Its Four Subsequent One-Electron Oxidized Forms

(2009) David Quiñonero et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Synthesis and crystal structure of RuIII-supported tungstoantimonate [Sb2W20RuIII2(H2O)2(dmso)6O68]4−

(2009) Li-Hua Bi et al.   JOURNAL OF SOLID STATE CHEMISTRY

Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates

(2009) Andrea Sartorel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen and Water Activation Processes on Multi-Ru-Substituted Polyoxometalates: Comparison with the “Blue-Dimer” Water Oxidation Catalyst

(2009) Aleksey E. Kuznetsov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural, Physicochemical, and Reactivity Properties of an All-Inorganic, Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation

(2009) Yurii V. Geletii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands

(2009) Yurii V. Geletii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarbon oxidation with an oxygen-hydrogen mixture: Catalytic systems based on the interaction of platinum or palladium with a heteropoly compound

(2009) N. I. Kuznetsova et al.   KINETICS AND CATALYSIS

Water Oxidation: A Robust All-Inorganic Catalyst

(2008) Georg Süss-Fink   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-Containing Polyoxometalates

(2008) Rui Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-Containing Polyoxometalates

(2008) Ulrich Kortz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8−

(2008) Elena V. Chubarova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An All-Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation

(2008) Yurii V. Geletii et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A γ-Keggin-type Dimeric Silicotungstate Sandwiching an Adamantanoid Tetra-nuclear Ruthenium–Oxygen Cluster Core

(2008) Syuhei Yamaguchi et al.   CHEMISTRY LETTERS

Selective Inclusion of Cu+ and Ag+ Electron-Rich Metallic Cations within Supramolecular Polyoxometalates Based on {AsW9O33}{Mo3S4} Combinations

(2008) Sylvain Duval et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbonyl–ruthenium substituted α-Keggin-tungstosilicate, [α-SiW11O39RuII(CO)]6−: synthesis, structure, redox studies and reactivity

(2008) Masahiro Sadakane et al.   DALTON TRANSACTIONS

Influence of polyoxometalate ligands on the nature of high-valent transition metal nitrido species. A theoretical analysis of experimentally known and unprecedented compounds

(2008) Susanna Romo et al.   DALTON TRANSACTIONS

Hydrothermal Synthesis and Structural Characterization of the High-Valent Ruthenium-Containing Polyoxoanion [{PW11O39}2{(HO)RuIV–O–RuIV(OH)}]10–

(2008) Su-Wen Chen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Palladium(II) Phosphotungstate Derivatives: Synthesis and Characterization of the [Pdx{WO(H2O)}3-x{A,α-PW9O34}2](6+2x)- Anions

(2008) Richard Villanneau et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Quantum Chemical Studies on High-Valent Metal Nitrido Derivatives of Keggin-Type Polyoxometalates ([PW11O39{MVIN}]4−(M = Ru, Os, Re)): MVI−N Bonding and Electronic Structures

(2008) Chun-Guang Liu et al.   INORGANIC CHEMISTRY

Mixed-Valence 24-Vanadophosphate Decorated with Six RuII(dmso)3 Groups: [{RuII 3(dmso)9PVV 11VIVRuIIIO37(OH)3}2]8−

(2008) Li-Hua Bi et al.   JOURNAL OF CLUSTER SCIENCE

Synthesis, characterization and crystal structure of a novel Os(II)-supported tungstoarsenate [HAsW7O28Os(dmso)3]6−

(2008) Li-Hua Bi et al.   JOURNAL OF SOLID STATE CHEMISTRY

Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst

(2008) Andrea Sartorel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic palladium(II) and iron(III), titanium(IV), vanadium(V), cobalt(II), and copper(II) complexes with the [As2W19O67(H2O)]14− heteropolyanion

(2008) L. G. Detusheva et al.   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Facile Incorporation of Platinum(IV) into Polyoxometalate Frameworks: Preparation of [H2PtIVV9O28]5− and Characterization by195Pt NMR Spectroscopy

(2007) Uk Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleation Process in the Cavity of a 48-Tungstophosphate Wheel Resulting in a 16-Metal-Centre Iron Oxide Nanocluster

(2007) Sib Sankar Mal et al.   CHEMISTRY-A EUROPEAN JOURNAL