Reinvestigation of a Ru2-Incorporated Polyoxometalate Dioxygenase Precatalyst, “[WZnRu2III(H2O)(OH)(ZnW9O34)2]11−”: Evidence For Marginal, ≤0.2 Equivalents of Ru Incorporation Plus Faster Catalysis by Physical Mixtures of [RuII(DMSO)4Cl2] and the Parent Polyoxometalate [WZn3(H2O)2(ZnW9O34)2]12−

Title

Reinvestigation of a Ru2-Incorporated Polyoxometalate Dioxygenase Precatalyst, “[WZnRu2III(H2O)(OH)(ZnW9O34)2]11−”: Evidence For Marginal, ≤0.2 Equivalents of Ru Incorporation Plus Faster Catalysis by Physical Mixtures of [RuII(DMSO)4Cl2] and the Parent Polyoxometalate [WZn3(H2O)2(ZnW9O34)2]12−

Authors

Keywords

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Journal

INORGANIC CHEMISTRY

Volume 48, Issue 10, Pages 4411-4420

Publisher

American Chemical Society (ACS)

Online

2009-04-07

DOI

10.1021/ic9000363