Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes

Dibridgehead Diphosphines that Turn Themselves Inside Out

(2011) Michael Stollenz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Monodentate Oxaphospholane Ligands: Utility in Highly Efficient and Enantioselective 1,4-Diboration of 1,3-Dienes

(2011) Christopher H. Schuster et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts

(2011) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis

(2011) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis

(2011) Serafino Gladiali et al.   CHEMICAL SOCIETY REVIEWS

An Enantioselective, Intermolecular α-Arylation of Ester Enolates To Form Tertiary Stereocenters

(2011) Zhiyan Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis

(2011) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd/Josiphos-Catalyzed Enantioselective α-Arylation of Silyl Ketene Acetals and Mechanistic Studies on Transmetalation and Enantioselection

(2011) Kenya Kobayashi et al.   ORGANOMETALLICS

Rhodium-Catalyzed Asymmetric Hydroformylation of N-Allylamides: Highly Enantioselective Approach to β2-Amino Aldehydes

(2010) Xiaowei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and enantioselective catalytic asymmetric hydroboration of α-substituted styrenyl derivatives

(2010) Clément Mazet et al.   CHEMICAL COMMUNICATIONS

Improved Catalysts for the Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis

(2010) Luca Mantilli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Catalytic α-Alkylation of Aldehydes via an SN1 Pathway

(2010) Adam R. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Role of Reversible Oxidative Addition in Selective Palladium(0)-Catalyzed Intramolecular Cross-Couplings of Polyhalogenated Substrates: Synthesis of Brominated Indoles

(2010) Stephen G. Newman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis

(2010) Hui-Wen Shih et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origin of Pressure Effects on Regioselectivity and Enantioselectivity in the Rhodium-Catalyzed Hydroformylation of Styrene with (S,S,S)-BisDiazaphos

(2010) Avery L. Watkins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Hydroformylation ofN-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands

(2010) Richard I. McDonald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of a Chiral Scaffolding Ligand in Catalytic Enantioselective Hydroformylation

(2010) Amanda D. Worthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Rhodium-Catalyzed Hydroformylation of 1,3-Dienes to Highly Enantioenriched β,γ-Unsaturated Aldehyes with Diazaphospholane Ligands

(2010) Avery L. Watkins et al.   ORGANIC LETTERS

Light in Aminocatalysis: The Asymmetric Intermolecular α-Alkylation of Aldehydes

(2009) Paolo Melchiorre   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols

(2009) Luca Mantilli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanded scope for the iridium-catalyzed asymmetric isomerization of primary allylic alcohols using readily accessible second-generation catalysts

(2009) Luca Mantilli et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Organocatalysis—after the gold rush

(2009) Søren Bertelsen et al.   CHEMICAL SOCIETY REVIEWS

Rh-Catalyzed Asymmetric Hydroformylation of Heterocyclic Olefins Using Chiral Diphosphite Ligands. Scope and Limitations

(2009) Javier Mazuela et al.   JOURNAL OF ORGANIC CHEMISTRY

An Efficient Process for Pd-Catalyzed C−N Cross-Coupling Reactions of Aryl Iodides: Insight Into Controlling Factors

(2009) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective α-Arylation of Carbonyl Compounds

(2009) Antonio Burtoloso   SYNLETT

Iridium-catalyzed isomerization of primary allylic alcohols under mild reaction conditions

(2009) Luca Mantilli et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos

(2008) Giang D. Vo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Palladium-Catalyzed Intramolecular α-Arylation of Aldehydes

(2008) Jorge García-Fortanet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proline-Catalyzed Asymmetric Formal α-Alkylation of Aldehydes via Vinylogous Iminium Ion Intermediates Generated from Arylsulfonyl Indoles

(2008) Rafik R. Shaikh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Domino Reactions: A Cascade Consisting of a Michael Addition and an Aldehyde α-Alkylation

(2008) Dieter Enders et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Aminocatalysis-Gold Rush in Organic Chemistry

(2008) Paolo Melchiorre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE

An Improved Protocol for the Pd-Catalyzed α-Arylation of Aldehydes with Aryl Halides

(2008) Rubén Martín et al.   ORGANIC LETTERS

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

(2008) D. A. Nicewicz et al.   SCIENCE

Development of a new class of C1-symmetric bisphosphine ligands for rhodium-catalyzed asymmetric hydrogenation

(2008) Qian Dai et al.   TETRAHEDRON