Gold-Catalyzed Functionalization of Unactivated C(sp3)H Bonds by Hydride Transfer Facilitated by Alkynylspirocyclopropanes

Sequential C sp 3H Arylation and Olefination: Total Synthesis of the Proposed Structure of Pipercyclobutanamide A

(2012) Will R. Gutekunst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Oxidative Cyclizations ofcis-3-En-1-ynes To Form Cyclopentenone Derivatives

(2012) Sabyasachi Bhunia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc(II)-Catalyzed Redox Cross-Dehydrogenative Coupling of Propargylic Amines and Terminal Alkynes for Synthesis of N-Tethered 1,6-Enynes

(2012) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes

(2012) Ryan J. Felix et al.   Nature Chemistry

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Gold-Catalyzed Rearrangements: Reaction Pathways Using 1-Alkenyl-2-alkynylcyclopropane Substrates

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclization by Catalytic Ruthenium Carbene Insertion into C sp 3H Bonds

(2011) Fermín Cambeiro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fused Indolines by Palladium-Catalyzed Asymmetric CC Coupling Involving an Unactivated Methylene Group

(2011) Masafumi Nakanishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Strained small rings in gold-catalyzed rapid chemical transformations

(2011) Bei-Li Lu et al.   CHEMICAL SOCIETY REVIEWS

Alkynylcyclopropanes from Terminal Alkynes through Consecutive Coupling to Fischer Carbene Complexes and Selective Propargylene Transfer

(2011) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expeditious Construction of a Carbobicyclic Skeleton via sp3-C−H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process

(2011) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity

(2011) Benoit Bolte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes

(2011) César R. Solorio-Alvarado et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Challenge and progress: palladium-catalyzed sp3 C–H activation

(2011) Hu Li et al.   Catalysis Science & Technology

Gold-Catalyzed Oxidative Ring Expansions and Ring Cleavages of Alkynylcyclopropanes by Intermolecular Reactions Oxidized by Diphenylsulfoxide

(2010) Chia-Wen Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-catalyzed cycloisomerization of 1,4-enynes via activation of a sp3-hybridized C–H bond

(2010) Dhananjayan Vasu et al.   CHEMICAL COMMUNICATIONS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence

(2010) Igor Dias Jurberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides

(2010) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes

(2010) Benoit Bolte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed C−C Bond Formation at α-Position of Aliphatic Amines via C−H Bond Activation through 1,5-Hydrogen Transfer

(2010) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Carbonylation of C(sp3)−H Bonds: A New Entry to 1,4-Dicarbonyl Compounds

(2010) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Annulation/Fragmentation: Formation of Free Gold Carbenes by Retro-Cyclopropanation

(2010) César R. Solorio-Alvarado et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Ring Expansions of Unactivated Alkynylcyclopropanes to (E)-2-Alkylidenecyclobutanamines in the Presence of Sulfonamides

(2010) Siyu Ye et al.   ORGANIC LETTERS

Platinum(II)-Catalyzed Intramolecular Cyclization ofo-Substituted Aryl Alkynes through sp3CH Activation

(2009) Shangdong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum and Ruthenium Chloride-Catalyzed Cycloisomerization of 1-Alkyl-2-ethynylbenzenes: Interception of π-Activated Alkynes with a Benzylic C−H Bond

(2009) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Au(I)-Catalyzed Cycloisomerizations Terminated by sp3C−H Bond Insertion

(2009) Yoshikazu Horino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (−)-PNU-286607 by Asymmetric Cyclization of Alkylidene Barbiturates

(2009) J. Craig Ruble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3C−H Bonds Catalyzed by Platinum Tetraiodide

(2009) Paul A. Vadola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins

(2009) Daisuke Shikanai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[1,5]-Hydride Transfer/Cyclizations on Alkynyl Fischer Carbene Complexes: Synthesis of 1,2-Dihydroquinolinyl Carbene Complexes and Cascade Reactions

(2008) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Gold- and Silver-Catalyzed Tandem Amination/Ring Expansion of Cyclopropyl Methanols with Sulfonamides as an Expedient Route to Pyrrolidines

(2008) Weidong Rao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed 1,3-Addition of a sp3-Hybridized C−H Bond to Alkenylcarbenoid Intermediate

(2008) Sabyasachi Bhunia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction

(2008) Paul Ha-Yeon Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Highly Enantioselective Synthesis of Axially Chiral Allenes

(2008) Vanessa Kar-Yan Lo et al.   ORGANIC LETTERS

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals

(2007) Chen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY