4.8 Article

Tunable near-Infrared Luminescence of PbSe Quantum Dots for Multigas Analysis

Journal

ANALYTICAL CHEMISTRY
Volume 86, Issue 22, Pages 11312-11318

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ac5030478

Keywords

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Funding

  1. National 863 Program [2011AA050509]
  2. National Natural Science Foundation of China [61106039, 51272084, 61306078, 61225018]
  3. National Postdoctoral Foundation [2011049015]
  4. Jilin Province Key Fund [20140204079GX]
  5. Shandong Natural Science Foundation [ZR2012FZ007]
  6. Hong Kong Scholar Program [XJ2012022]
  7. State Key Laboratory on Integrated Optoelectronics [IOSKL2012ZZ12]
  8. NSF [CHE-1338346]
  9. 3M Faculty Award
  10. Division Of Chemistry
  11. Direct For Mathematical & Physical Scien [1338346] Funding Source: National Science Foundation

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Multigas sensing is highly demanded in the fields of environmental monitoring, industrial production, and coal mine security. Three near-infrared emission wavelengths from PbSe quantum dots (QDs) were used to analyze the concentration of three gases simultaneously through direct absorption spectroscopy, including acetylene (C2H2), methane (CH4), and ammonia (NH3). The corresponding lower detection limits for the three gases were 20, 100, and 20 ppm, respectively, with an accuracy of 2%. This study demonstrates that QDs with tunable emissions have great potential for simultaneous and uninterfered multiplex gas analysis and detection due to the advantages of the easy tunability of multiplex emitting wavelengths from QDs.

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