Article
Chemistry, Physical
Felipe de Jesus Anaya-Castro, Diana G. Aguilar-Garcia, Rodolfo Gomez-Balderas, Emir A. Galvan-Garcia, Valentin Miranda-Soto, Antonio Tirado-Guizar, Adrian Ochoa Teran, Georgina E. Pina Luis
Summary: This study evaluated the binding capacity between four functional monomers (APTES, APTMS, AEAPTES, AEAPTMS) and tetracycline (TC) to form noncovalent pre-polymerization complexes using a density functional theory (DFT) based methodology. The results showed the formation of stable TC-monomer complexes through electrostatic interactions and intermolecular hydrogen bonds. APTES and APTMS monomers exhibited the most stable complexes. UV-Vis, fluorescence, and 1HNMR spectroscopy confirmed the TC-APTES pre- polymerization complex. Synthesized molecularly imprinted polymers (MIPs) based on APTES and AEAPTMS demonstrated high adsorption capacity, with excellent agreement between DFT calculations and experimental results.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Biochemical Research Methods
Noman Nawaz, Nor Kartini Abu Bakar, Habibun Nabi Muhammad Ekramul Mahmud, Nazzatush Shimar Jamaludin
Summary: Molecularly imprinted polymers (MIPs) are promising materials for biological sensing, with advantages such as ease of synthesis, low cost, high recognition ability, and long-term durability. They can be employed in drug delivery, biosensor technology, and nanotechnology, and offer potential for improved recognition of biomacromolecules.
ANALYTICAL BIOCHEMISTRY
(2021)
Review
Chemistry, Analytical
Simonas Ramanavicius, Inga Morkvenaite-Vilkonciene, Urte Samukaite-Bubniene, Vilma Ratautaite, Ieva Plikusiene, Roman Viter, Arunas Ramanavicius
Summary: This review focuses on the development of molecularly imprinted polymers (MIPs) and their application in sensor design. MIP-based conducting polymers, such as polypyrrole, are frequently used in sensor design due to their unique properties. The review also provides an overview of other materials that can be molecularly imprinted and discusses methods for designing MIP-based sensing structures and transducing analytical signals. Furthermore, it explores expected new trends and horizons in the application of MIP-based structures.
Review
Polymer Science
Aliya Nur Hasanah, Ike Susanti
Summary: The safety of medicinal products is determined by their pharmacological and toxicological profiles, which depend on both the active substance's toxicological properties and the impurities it contains. Many studies have been conducted on the separation and purification of active pharmaceutical ingredients (APIs) and the detection of impurities in APIs and drug products. Molecularly imprinted polymers (MIPs) have been applied in these studies to separate impurities and serve as adsorbents in sample preparation. The surface-imprinting polymerization method has shown advantages over the bulk polymerization method in terms of higher adsorption capacity and faster adsorption kinetics of MIPs. However, MIPs are currently only used for organic compounds in the analysis of APIs and drug products, and there is a need to develop MIPs for other impurities, including multi-template MIPs for simultaneous separation of multiple impurities.
Review
Engineering, Environmental
Hui Yang, Hong -Bo Liu, Zhi-Shu Tang, Zhi-Dong Qiu, Hua-Xu Zhu, Zhong-Xing Song, Ai-Ling Jia
Summary: Molecularly imprinted membranes combine membrane separation technology and molecular imprinting technologies to achieve molecular memory and recognition on template molecules, making them widely applicable in various fields such as sensor development and drug delivery. They have been studied for over 60 years and continue to be a major research focus due to their compatibility with emerging technologies.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Review
Polymer Science
Simonas Ramanavicius, Arunas Jagminas, Arunas Ramanavicius
Summary: This review outlines the important directions and applications of polymer-based semiconducting materials in affinity sensors, focusing on the bioanalytical application of conducting polymers such as polypyrrole and polyaniline. It also discusses advancements in polymerization techniques and analytical signal transduction methods applied in affinity sensors. Additionally, the review highlights the development and application of molecularly imprinted polymer-based structures as potential replacements for expensive affinity reagents.
Review
Polymer Science
Semra Akgonullu, Seckin Kilic, Cem Esen, Adil Denizli
Summary: The accurate detection of biological substances such as proteins has always been a hot topic in scientific research. Biomimetic sensors seek to imitate sensitive and selective mechanisms of biological systems and integrate these traits into applicable sensing platforms. Molecular imprinting technology has been extensively practiced in many domains, producing molecular recognition materials with specific capabilities. Molecularly imprinted polymers (MIPs), also known as plastic antibodies, are artificial receptors with high-affinity binding sites for a particular molecule or compound. MIPs for protein recognition are expected to have high affinity through interactions between polymer matrices and functional groups of the target protein. This critical review discusses recent advances in the synthesis, characterization, and application of MIP-based sensor platforms for protein detection.
Review
Chemistry, Analytical
Yahan Cui, Lan Ding, Jie Ding
Summary: Magnetic imprinted polymers (MMIPs) are synthetic polymeric materials that have wide-ranging applications in sample processing. By combining magnetic separation technology, MMIPs not only have high selectivity for adsorbing target analytes, but also provide convenience for rapid separation and processing of large sample volumes. This review summarizes recent advanced preparation strategies of MMIPs and highlights their applications in complex samples.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2022)
Review
Polymer Science
Xiaoyue Zhao, Yong Wang, Pan Zhang, Zhemiao Lu, Yin Xiao
Summary: This review summarizes recent advances in the application of cyclodextrin-based molecular imprinting polymers (MIPs) in sample preparation, detection, sensing, and drug delivery over the past five years. It also discusses the specific roles of cyclodextrins in MIPs and elaborates on the challenges and future prospects in the application of cyclodextrins in MIPs.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Nanoscience & Nanotechnology
Alessandra Maria Bossi, Alessio Bucciarelli, Devid Maniglio
Summary: Nanosized biomimetics prepared by molecular imprinting are showing potential as plastic antibodies in medicine for cell imaging and targeted therapies. Utilizing natural polymer silk fibroin to synthesize biocompatible MIP SF-NPs demonstrates high affinity recognition sites and biocompatibility.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Roghayeh Mantashloo, Soleiman Bahar
Summary: In this study, modified magnetic graphene quantum dots with molecularly imprinted polymer coating (Fe3O4@GQDs/MIP), which serve as a low-cost green adsorbent for easy evaluation of quercetin medicinal compound, were synthesized. The optimal conditions for measuring quercetin were investigated, and quercetin in real samples of green tea, cumin, and thyme was successfully measured and detected. The synthesized adsorbent showed high selectivity, sensitivity, and efficiency.
MICROCHEMICAL JOURNAL
(2023)
Review
Polymer Science
Andreea E. Bodoki, Bogdan-C. Iacob, Elena Dinte, Oliviu Vostinaru, Ovidiu Samoila, Ede Bodoki
Summary: The human eye presents challenges for drug administration due to anatomical and physiological barriers, but molecular imprinting technology shows promise in addressing these issues, especially in ocular therapy. Molecularly imprinted polymers have the potential to improve drug delivery systems for treating eye diseases.
Article
Chemistry, Analytical
Vilma Ratautaite, Ernestas Brazys, Almira Ramanaviciene, Arunas Ramanavicius
Summary: The aim of this study was to compare the application of two different conducting polymers, polypyrrole and polyaniline, in the design of molecularly imprinted polymers (MIPs). The results showed that polypyrrole had a higher affinity for L-tryptophan and was more suitable for the design of MIP-based sensors for the detection of L-tryptophan.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Review
Chemistry, Physical
Simonas Ramanavicius, Arunas Ramanavicius
Summary: Achievements in polymer chemistry have enabled the design of artificial phase boundaries through the modification of selected molecules and larger structures. These structures have proven to be useful for the development of new materials suitable for affinity chromatography and sensors. This review provides an overview of the synthesis of molecularly imprinted polymers (MIPs) and their applicability in the design of affinity sensors. The use of conducting polymers, such as polypyrrole, polyaniline, and polythiophene, shows promising capabilities for molecular imprinting. The review also discusses methods for the synthesis of conducting polymer-based MIPs and the challenges and trends in MIP technology.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2022)
Article
Polymer Science
Li Zhang, Hongbo Mo, Chuan Wang, Xiaofeng Li, Shuai Jiang, Weigang Fan, Yagang Zhang
Summary: Novel core-shell magnetic molecularly imprinted polymers (MMIPs) were synthesized for the adsorption of cefixime (CFX). The MMIPs showed high adsorption capacity and selective adsorption ability for CFX, and exhibited excellent reusable performance.
Article
Chemistry, Physical
Rola Mostafa, Eric Bremond, Carlo Adamo, Ilaria Ciofini, Christophe Morell, Henry Chermette
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Walid Lamine, Salima Boughdiri, Lorraine Christ, Christophe Morell, Henry Chermette
JOURNAL OF COMPUTATIONAL CHEMISTRY
(2019)
Article
Biochemical Research Methods
Marwa Chaabene, Bouzid Gassoumi, Pierre Mignon, Rafik Ben Chaabane, Abdul-Rahman Allouche
JOURNAL OF MOLECULAR GRAPHICS & MODELLING
(2019)
Article
Chemistry, Multidisciplinary
Pierre Mignon, Javier Navarro-Ruiz, Albert Rimola, Mariona Sodupe
ACS EARTH AND SPACE CHEMISTRY
(2019)
Article
Chemistry, Physical
Marwa Manachou, Christophe Morell, Henry Chermette, Salima Boughdiri
CHEMICAL PHYSICS LETTERS
(2019)
Article
Chemistry, Multidisciplinary
Juan Andres, Paul W. Ayers, Roberto A. Boto, Ramon Carbo-Dorca, Henry Chermette, Jerzy Cioslowski, Julia Contreras-Garcia, David L. Cooper, Gernot Frenking, Carlo Gatti, Farnaz Heidar-Zadeh, Laurent Joubert, Angel Martin Pendas, Eduard Matito, Istvan Mayer, Alston J. Misquitta, Yirong Mo, Julien Pilme, Paul L. A. Popelier, Martin Rahm, Eloy RamosCordoba, Pedro Salvador, W. H. Eugen Schwarz, Shant Shahbazian, Bernard Silvi, Miquel Sola, Krzysztof Szalewicz, Vincent Tognetti, Frank Weinhold, Emilie-Laure Zins
JOURNAL OF COMPUTATIONAL CHEMISTRY
(2019)
Article
Chemistry, Physical
Maryam Rahimi, Henry Chermette, Saeed Jamehbozorgi, Reza Ghiasi, Mahboubeh Poor Kalhor
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
(2019)
Article
Chemistry, Physical
Pierre Mignon, Gwenaelle Corbin, Sebastien Le Crom, Virginie Marry, Jihua Hao, Isabelle Daniel
APPLIED CLAY SCIENCE
(2020)
Article
Chemistry, Physical
Guillaume Thiam, Florence Charlieux, Pierre Mignon, Franck Rabilloud, Hassan Abdoul-Carime
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Geochemistry & Geophysics
Gwenaelle Corbin, Emmanuelle Vulliet, Bruno Lanson, Albert Rimola, Pierre Mignon
Summary: The study found that the adsorption of carbamazepine and paracetamol onto expandable clay minerals is low, with neither compound entering the interlayer space of the clay. The adsorption mainly occurs through van der Waals interactions on the clay surface.
Article
Chemistry, Multidisciplinary
Anna Levy, Manuel De Anda Villa, Gaetan Laurens, Valerie Blanchet, John Bozek, Jerome Gaudin, Emily Lamour, Stephane Mace, Pierre Mignon, Aleksandar R. Milosavljevic, Christophe Nicolas, Minna Patanen, Christophe Prigent, Emmanuel Robert, Sebastien Steydli, Martino Trassinelli, Dominique Vernhet, Onni Vetelainen, David Amans
Summary: Pulsed laser ablation in liquid (PLAL) is a powerful method for producing nanoparticle colloids with long-term stability, and the stability is influenced by the reactivities and chemical equilibria at the nanoparticle/solvent interface. X-ray photoelectron spectroscopy can be used to evaluate the degree of nanoparticle surface oxidation and composition.
Article
Chemistry, Multidisciplinary
Rania Mechichi, Taha Chabbah, Saber Chatti, Ibtissem Jlalia, Corinne Sanglar, Herve Casabianca, Emmanuelle Vulliet, Catherine Marestin, Regis Mercier, Steffen M. Weidner, Abdelhamid Errachid, Mohamed Hammami, Nicole Jaffrezic-Renault, Houyem Abderrazak
Summary: In the development of green analytical chemistry, a study was conducted on a silica gel coated with a partially biosourced poly(ethersulfone) semi-penetrating network for the greener extraction of aromatic organic pollutants. The optimized composition of the semi-penetrating network led to total adsorption of the pollutants, regardless of their hydrophilicity. The adsorption characteristics, kinetics, and isotherms of the SG-semi-INP LP80/XP20 were studied for p-hydroxybenzoic acid and toluic acid.
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY
(2022)
Proceedings Paper
Computer Science, Interdisciplinary Applications
Stefano Pantaleone, Albert Rimola, Javier Navarro-Ruiz, Pierre Mignon, Mariona Sodupe, Piero Ugliengo, Nadia Balucani
COMPUTATIONAL SCIENCE AND ITS APPLICATIONS - ICCSA 2020, PT VII
(2020)
Article
Nanoscience & Nanotechnology
Franck Bertorelle, Srestha Basu, Hussein Fakhouri, Martina Peric Bakulic, Pierre Mignon, Isabelle Russier-Antoine, Pierre-Francois Brevet, Sabu Thomas, Nandakumar Kalarikkal, Rodolphe Antoine
Article
Chemistry, Multidisciplinary
Douniazed Hannachi, Mohamed Fahim Haroun, Ahiem Khireddine, Henry Chermette
NEW JOURNAL OF CHEMISTRY
(2019)