Journal
ANALYTICAL CHEMISTRY
Volume 81, Issue 3, Pages 1089-1094Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ac802188c
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Funding
- National Science Foundation [CHE-0449312, CHE-0750377]
- Robert A-Welch Foundation [A-1482]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0750377] Funding Source: National Science Foundation
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Silver nanoparticles (NPs) of similar to 5 nm diameter deposited in a single layer on glycine were examined with cluster secondary ion mass spectrometry (SIMS) in the event-by-event bombardment-detection mode. The projectiles used were Au-3(+), C-60(+), and Au-400(4+) with impact energies of 34, 26, and 136 keV, respectively. ne highest secondary ion yields were obtained with Au-400(4+). The method presented can test single or multilayer organization and determine surface coverage. NPs are identified one-by-one for chemical composition. Chemical and physical information in a nonimaging mode was resolved at similar to 10 nm. Grazing vs direct impacts on NPs were identified and quantified. NP fragmentation from direct impacts with Au-400(4+) and C-60(+) was observed for the first time.
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