Recent Progress in the Radical Chemistry of Alkylborates and Alkylboronates

Dual Photoredox/Nickel-Catalyzed Regioselective Cross-Coupling of 2-Arylaziridines and Potassium Benzyltrifluoroborates: Synthesis of β-Substitued Amines

(2018) Xiao-Ye Yu et al.   ORGANIC LETTERS

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C–H Functionalization

(2017) Jennifer K. Matsui et al.   ORGANIC LETTERS

Manganese-Mediated C−H Alkylation of Unbiased Arenes Using Alkylboronic Acids

(2016) Susana Castro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Alkenylation, Allylation, and Cyanation of Potassium Alkyltrifluoroborates with Organic Photoredox Catalysts

(2016) Drew R. Heitz et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic, Enantioselective Addition of Alkyl Radicals to Alkenes via Visible-Light-Activated Photoredox Catalysis with a Chiral Rhodium Complex

(2016) Haohua Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Electron Transmetalation: Photoredox/Nickel Dual Catalytic Cross-Coupling of Secondary Alkyl β-Trifluoroboratoketones and -esters with Aryl Bromides

(2016) John C. Tellis et al.   ORGANIC LETTERS

Unprotected Amino Acids as Stable Radical Precursors for Heterocycle C–H Functionalization

(2016) Duy N. Mai et al.   ORGANIC LETTERS

Synthesis of 2-Aryl- and 2-Vinylpyrrolidines via Copper-Catalyzed Coupling of Styrenes and Dienes with Potassium β-Aminoethyl Trifluoroborates

(2016) Chanchamnan Um et al.   ORGANIC LETTERS

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

(2016) Javad Amani et al.   ORGANIC LETTERS

Single-Electron-Transfer Oxidation of Trifluoroborates and Silicates with Organic Reagents: A Comparative Study

(2016) Jean-Philippe Goddard et al.   SYNLETT

Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine

(2016) Guo-Xing Li et al.   Chemical Science

Copper-Catalyzed Boron-Selective C(sp2)–C(sp3) Oxidative Cross-Coupling of Arylboronic Acids and Alkyltrifluoroborates Involving a Single-Electron Transmetalation Process

(2016) Siyi Ding et al.   ACS Catalysis

Photoredox/Brønsted Acid Co-Catalysis Enabling Decarboxylative Coupling of Amino Acid and Peptide Redox-Active Esters with N-Heteroarenes

(2016) Wan-Min Cheng et al.   ACS Catalysis

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

(2015) Mirna El Khatib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress on All Ends for Carbon-Carbon Bond Formation through Photoredox Catalysis

(2015) Miguel Peña-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Electron Transmetalation: Synthesis of 1,1-Diaryl-2,2,2-trifluoroethanes by Photoredox/Nickel Dual Catalytic Cross-Coupling

(2015) DaWeon Ryu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

(2015) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers

(2015) Idris Karakaya et al.   ORGANIC LETTERS

Protecting group-free, selective cross-coupling of alkyltrifluoroborates with borylated aryl bromides via photoredox/nickel dual catalysis

(2015) Yohei Yamashita et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis

(2015) Yanjie Li et al.   Organic Chemistry Frontiers

Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis

(2014) Kazuki Miyazawa et al.   ADVANCED SYNTHESIS & CATALYSIS

Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis

(2014) Hanchu Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Induced Chemoselective Deboronative Alkynylation under Biomolecule-Compatible Conditions

(2014) Hanchu Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Radical Fluorination of Alkylboronates in Aqueous Solution

(2014) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

(2013) Kazuki Miyazawa et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Synthetic applications of photoredox catalysis with visible light

(2013) Yumeng Xi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Oxidative Heck Reactions between Alkyltrifluoroborates and Vinyl Arenes

(2013) Timothy W. Liwosz et al.   ORGANIC LETTERS

Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3

(2013) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry

(2013) Takashi Koike et al.   SYNLETT

Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

(2012) Yusuke Yasu et al.   ADVANCED SYNTHESIS & CATALYSIS

Modular Synthesis of Phenanthridine Derivatives by Oxidative Cyclization of 2-Isocyanobiphenyls with Organoboron Reagents

(2012) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

(2011) Akira Suzuki   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Practical C−H Functionalization of Quinones with Boronic Acids

(2011) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Radical Cyclizations with Arylboronic Acids and Trifluoroborates

(2011) Jonathan W. Lockner et al.   ORGANIC LETTERS

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Oxidation of Alkyl Trifluoroborates: An Opportunity for Tin-Free Radical Chemistry

(2010) Geoffroy Sorin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Oxidation of Catecholboron Enolates with TEMPO

(2009) Martin Pouliot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo-allylation and photo-benzylation of carbonyl compounds using organotrifluoroborate reagents

(2009) Yutaka Nishigaichi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

(2009) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Transfer Photoredox Catalysis: Intramolecular Radical Addition to Indoles and Pyrroles

(2009) Joseph W. Tucker et al.   ORGANIC LETTERS

Ritter-type amidation of alkylboron derivatives with nitriles

(2009) Clément Cazorla et al.   TETRAHEDRON LETTERS

Oxidative Homocoupling of Aryl, Alkenyl, and Alkynyl Grignard Reagents with TEMPO and Dioxygen

(2008) Modhu Sudan Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN