Transition Metal-Mediated Direct CH Arylation of Heteroarenes Involving Aryl Radicals

Palladium-Catalyzed Direct Denitrogenative C-3-Arylation of 1H-Indoles with Arylhydrazines using Air as the Oxidant

(2013) Yongxin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild and Rapid Pd-Catalyzed Cross-Coupling with Hydrazine in Continuous Flow: Application to the Synthesis of Functionalized Heterocycles

(2013) Andrew DeAngelis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mild, One-Pot Stadler-Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous-Flow

(2013) Xiao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

sp2 C–H bond activation in water and catalytic cross-coupling reactions

(2013) Bin Li et al.   CHEMICAL SOCIETY REVIEWS

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Visible Light-mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst

(2013) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Twofold Carbon-Carbon Bond Formation by Intra- and Intermolecular Radical Reactions of Aryl Diazonium Salts

(2013) Hannelore Jasch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chelation-Assisted Cross-Coupling of Anilines through In Situ Activation as Diazonium Salts with Boronic Acids under Ligand-, Base-, and Salt-Free Conditions

(2013) Roxan Joncour et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Formation of 1,3,4-Oxadiazol-2(3H)-ones and Dibenzo[c,e]azepines by Concomitant Cathodic Reduction of Diazonium Salts and Phenanthrenequinones

(2013) Belen Batanero et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H Arylation of Benzoquinone in Water through Aniline Activation: Synergistic Effect of Graphite-Supported Copper Oxide Nanoparticles

(2013) Aurélien Honraedt et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-catalyzed Cross-Coupling of Electron-Deficient Heterocycles and Quinone with Organoboron Species via Innate C–H Functionalization: Application in Total Synthesis of Pyrazine Alkaloid Botryllazine A

(2013) Parvinder Pal Singh et al.   JOURNAL OF ORGANIC CHEMISTRY

Uncovering the Mechanism of the Ag(I)/Persulfate-Catalyzed Cross-Coupling Reaction of Arylboronic Acids and Heteroarenes

(2013) Niki R. Patel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability

(2013) Fionn O’Hara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic surface patterning of cellulose using diazonium salts and visible light

(2013) Peter Schroll et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-metal-catalyzed additions of C–H bonds to C–X (X = N, O) multiple bonds via C–H bond activation

(2013) Guobing Yan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent applications of arene diazonium salts in organic synthesis

(2013) Fanyang Mo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Visible-Light Photoredox in Homolytic Aromatic Substitution: Direct Arylation of Arenes with Aryl Halides

(2013) Yannan Cheng et al.   ORGANIC LETTERS

Room-Temperature Arylation of Arenes and Heteroarenes with Diaryl­iodonium Salts by Photoredox Catalysis

(2013) Dong Xue et al.   SYNLETT

Recent advances in transition-metal-free direct C–C and C–heteroatom bond forming reactions

(2013) Vaibhav P. Mehta et al.   RSC Advances

Iodo-Bodipys as visible-light-absorbing dual-functional photoredox catalysts for preparation of highly functionalized organic compounds by formation of C–C bonds via reductive and oxidative quenching catalytic mechanisms

(2013) Ling Huang et al.   RSC Advances

Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed CH Arylation with Diaryliodonium Salts

(2012) Sharon R. Neufeldt et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed cyclization of β-bromo-α,β-unsaturated ketones with arylhydrazines leading to 3-substituted 1-aryl-1 H-pyrazoles

(2012) Hye Kyung Lee et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

(2012) Jian Wang et al.   CHEMICAL COMMUNICATIONS

The Gomberg-Bachmann Reaction for the Arylation of Anilines with Aryl Diazotates

(2012) Gerald Pratsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sustainable Heck-Matsuda Reaction with Catalytic Amounts of Diazonium Salts: An Experimental and Theoretical Study

(2012) Nicolas Susperregui et al.   CHEMISTRY-A EUROPEAN JOURNAL

CH Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

(2012) David Y.-K. Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Radical Arylation of Anilines with Arylhydrazines

(2012) Hannelore Jasch et al.   JOURNAL OF ORGANIC CHEMISTRY

Continuous-Flow Synthesis of Monoarylated Acetaldehydes Using Aryldiazonium Salts

(2012) Natalia Chernyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts

(2012) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H arylation of unactivated heteroaromatics with aryl halides by cobalt porphyrin

(2012) Ying Ying Qian et al.   TETRAHEDRON LETTERS

Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium Salts

(2012) Peter Schroll et al.   ChemistryOpen

Aryl Diazonium versus Iodonium Salts: Preparation, Applications and Mechanisms for the Suzuki-Miyaura Cross-Coupling Reaction

(2011) Hélène Bonin et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalysis and CH Activation Meet Radical- and Electron-Transfer Reactions

(2011) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series

(2011) Cécile Verrier et al.   Beilstein Journal of Organic Chemistry

Potassium tert-butoxide mediated Heck-type cyclization/isomerization–benzofurans from organocatalytic radical cross-coupling reactions

(2011) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

(2011) Nanase Uchiyama et al.   CHEMICAL COMMUNICATIONS

A Mild Oxidative Aryl Radical Addition into Alkenes by Aerobic Oxidation of Arylhydrazines

(2011) Tsuyoshi Taniguchi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evolution and Synthetic Applications of the Heck-Matsuda Reaction: The Return of Arenediazonium Salts to Prominence

(2011) Jason G. Taylor et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Arylation of Arene and N-Heteroarenes with Diaryliodonium Salts without the Use of Transition Metal Catalyst

(2011) Jun Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical C−H Functionalization of Quinones with Boronic Acids

(2011) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C–C Bond Formation of Arylhydrazines with Olefins via Carbon–Nitrogen Bond Cleavage

(2011) Ming-Kui Zhu et al.   ORGANIC LETTERS

Unprecedented Substoichiometric Use of Hazardous Aryl Diazonium Salts in the Heck-Matsuda Reaction via a Double Catalytic Cycle

(2011) François Le Callonnec et al.   ORGANIC LETTERS

Practical Radical Cyclizations with Arylboronic Acids and Trifluoroborates

(2011) Jonathan W. Lockner et al.   ORGANIC LETTERS

Metal-Free Direct Arylations of Indoles and Pyrroles with Diaryliodonium Salts

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Silver-Catalyzed 2-Pyridyl Arylation of Pyridine N-Oxides with Arylboronic Acids at Room Temperature

(2011) Wenpeng Mai et al.   SYNLETT

Recent advances in the Heck–Matsuda reaction in heterocyclic chemistry

(2011) François-Xavier Felpin et al.   TETRAHEDRON

A microwave-assisted, propylphosphonic anhydride (T3P®) mediated one-pot Fischer indole synthesis

(2011) Matthieu Desroses et al.   TETRAHEDRON LETTERS

Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process

(2010) Toshifumi Dohi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Synthesis of heterocycles on the basis of arylation products of unsaturated compounds. 19.* Arylation of 2-acetylthio- phene and the synthesis of 2-(5-aryl-2-thien- yl)-4-quinolinecarboxylic acids

(2010) V. S. Matiychuk et al.   Chemistry of Heterocyclic Compounds

Synthesis of heterocycles on the basis of products of arylation of unsaturated compounds 22.* 3-Aryl-2-chloropropanal in the synthesis of N-Aryl-5-(R-benzyl)-1,3-thiazole-2-amines

(2010) V. S. Matiychuk et al.   Chemistry of Heterocyclic Compounds

Dichloro-Bis(aminophosphine) Complexes of Palladium: Highly Convenient, Reliable and Extremely Active Suzuki-Miyaura Catalysts with Excellent Functional Group Tolerance

(2010) Jeanne L. Bolliger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radical Arylation of Phenols, Phenyl Ethers, and Furans

(2010) Alexander Wetzel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Direct C-H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes

(2010) Samir Messaoudi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway

(2010) Frédéric Vallée et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modification of Carbon Substrates by Aryl and Alkynyl Iodonium Salt Reduction

(2010) Martin Weissmann et al.   LANGMUIR

Photoinitiated Polymerization: Advances, Challenges, and Opportunities

(2010) Yusuf Yagci et al.   MACROMOLECULES

Radical Addition of Arylboronic Acids to Various Olefins under Oxidative Conditions

(2010) Arne Dickschat et al.   ORGANIC LETTERS

Palladium-Catalyzed C−H Arylation of 2,5-Substituted Pyrroles

(2010) Anna M. Wagner et al.   ORGANIC LETTERS

Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids

(2010) Sankar Guchhait et al.   SYNTHESIS-STUTTGART

C–H arylation of unactivated arenes with aryl halides catalyzed by cobalt porphyrin

(2010) Ching Tat To et al.   TETRAHEDRON LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaryliodonium Salts: A Journey from Obscurity to Fame

(2009) Eleanor���A. Merritt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Meerwein arylation with 3-fluorobutenone

(2009) Timothy B. Patrick et al.   JOURNAL OF FLUORINE CHEMISTRY

General Approach for Monolayer Formation of Covalently Attached Aryl Groups Through Electrografting of Arylhydrazines

(2009) Kristoffer Malmos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cp2Ni-KOt-Bu-BEt3(or PPh3) Catalyst System for Direct C−H Arylation of Benzene, Naphthalene, and Pyridine

(2009) Osamu Kobayashi et al.   ORGANIC LETTERS

Role of triplet states of aryldiazonium cations in the Meerwein reaction

(2009) B. F. Minaev et al.   RUSSIAN JOURNAL OF APPLIED CHEMISTRY

Mechanism of Meerwein arylation of furan derivatives

(2009) N. D. Obushak et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of heterocycles from arylation products of unsaturated compounds: XVIII. 5-Arylfuran-2-carboxylic acids and their application in the synthesis of 1,2,4-thiadiazole, 1,3,4-oxadiazole, and [1,2,4]triazolo[3,4-b][1,3,4]thiadiazole derivatives

(2009) Yu. I. Gorak et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation

(2009) Ayhan S. Demir et al.   TETRAHEDRON

Gold(I)-catalyzed direct C–H arylation of pyrazine and pyridine with aryl bromides

(2009) Ming Li et al.   TETRAHEDRON LETTERS

Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions

(2008) Sebastian Würtz et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis and reactions of 5-aryl-2-thiophenecarbaldehydes

(2008) M. D. Obushak et al.   Chemistry of Heterocyclic Compounds

Intermolecular Olefin Functionalisation Involving Aryl Radicals Generated from Arenediazonium Salts

(2008) Markus R. Heinrich   CHEMISTRY-A EUROPEAN JOURNAL

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

(2008) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

Direct Arylation of Oxazoles at C2. A Concise Approach to Consecutively Linked Oxazoles

(2008) Emmanuel Ferrer Flegeau et al.   ORGANIC LETTERS

Synthesis of heterocycles based on arylation products of unsaturated compounds: XVII. Arylation of 2-acetylfuran and synthesis of 3-R-6-(5-aryl-2-furyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazines

(2008) N. D. Obushak et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Potassium permanganate/carboxylic acid/organic solvent: a powerful reagent for enone oxidation and aryl coupling reactions

(2008) Ayhan S. Demir et al.   TETRAHEDRON

Radical fluoroarylation in radiochemical synthesis

(2008) Christina Hultsch et al.   TETRAHEDRON LETTERS