Iron-Catalyzed Generation of α-Amino Nitriles from Tertiary Amines

Chiral Iron Catalysts for Asymmetric Synthesis

(2013) Kovuru Gopalaiah   CHEMICAL REVIEWS

A Robust Palladium(II)-Porphyrin Complex as Catalyst for Visible Light Induced Oxidative CH Functionalization

(2013) Wai-Pong To et al.   CHEMISTRY-A EUROPEAN JOURNAL

Manganese Dioxide–Methanesulfonic Acid Promoted Direct Dehydrogenative Alkylation of sp3 C–H Bonds Adjacent to a Heteroatom

(2013) Xigong Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Simple and Sustainable Iron-Catalyzed Aerobic C–H Functionalization of N,N-Dialkylanilines

(2013) Maxim O. Ratnikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation of Oxidative Mannich Reaction with tert-Butyl Hydroperoxide. The Role of Transition Metal Salt

(2013) Maxim O. Ratnikov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic applications of photoredox catalysis with visible light

(2013) Yumeng Xi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Versatile C–H Functionalization of Tetrahydroisoquinolines Catalyzed by Iodine at Aerobic Conditions†

(2013) Jayaraman Dhineshkumar et al.   ORGANIC LETTERS

Magnetically Recoverable CuFe2O4 Nanoparticles as Highly Active Catalysts for Csp3-Csp and Csp3-Csp3 Oxidative Cross-Dehydrogenative Coupling

(2013) Chao-Jun Li et al.   SYNLETT

Cobalt-Catalyzed Oxidative α-Cyanation of Tertiary Aromatic Amines with Trimethylsilyl Cyanide and tert-Butyl Hydroperoxide

(2013) Norio Sakai et al.   SYNLETT

Photoinduced Direct Cyanation of C(sp3)-H Bonds

(2013) Masayuki Inoue et al.   SYNTHESIS-STUTTGART

Fast, solvent-free asymmetric alkynylation of prochiral sp3 C–H bonds in a ball mill for the preparation of optically active tetrahydroisoquinoline derivatives

(2013) Jingbo Yu et al.   TETRAHEDRON LETTERS

The Copper-Catalyzed C-3-Formylation of Indole CH Bonds using Tertiary Amines and Molecular Oxygen

(2012) Jianbin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

A Scalable, Efficient Gold-Catalyzed Oxidative Phosphonation of sp3 CH Bonds using Air as Sustainable Oxidant

(2012) Jin Xie et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Oxidative Cross-Dehydrogenative Coupling of Tertiary Amines to Aldehydes

(2012) Junmin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Cyanation of Tertiary Amines with Ethyl Cyanoformate over a Niobia-Supported Iron-Exchanged Molybdophosphoric Acid Catalyst

(2012) Kasanneni Tirumala Venkateswara Rao et al.   ChemCatChem

Cu(ii)-catalyzed C–H (SP3) oxidation and C–N cleavage: base-switched methylenation and formylation using tetramethylethylenediamine as a carbon source

(2012) Lei Zhang et al.   CHEMICAL COMMUNICATIONS

Photoredox functionalization of C–H bonds adjacent to a nitrogen atom

(2012) Lei Shi et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Iron-Catalyzed Oxidative Amidation of Tertiary Amines with Aldehydes

(2012) Yuanming Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct α-Functionalization of Saturated Cyclic Amines

(2012) Emily A. Mitchell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aerobic Oxidation of a Tertiary Aliphatic Amine Under Visible-Light Photocatalysis: Facile Synthesis of Methylene-Bridged Bis-1,3-dicarbonyl Compounds

(2012) Woo-Jin Yoo et al.   Chemistry-An Asian Journal

Gold-Catalyzed Direct Indolation of Tetrahydroisoquinolines

(2012) Yan Zhang et al.   CHINESE JOURNAL OF CHEMISTRY

Iron-Catalyzed N-Alkylation of Azoles via Cleavage of an sp3 C–H Bond Adjacent to a Nitrogen Atom

(2012) Qinqin Xia et al.   JOURNAL OF ORGANIC CHEMISTRY

Shining Light on Photoredox Catalysis: Theory and Synthetic Applications

(2012) Joseph W. Tucker et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Metal/Organo-Catalyzed Aerobic Oxidative sp3C–H Olefination of Tertiary Amines Using Molecular Oxygen as the Sole Oxidant

(2012) Gen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral α-Cyanation of Amines

(2012) Longle Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Comparative Mechanistic Study of Cu-Catalyzed Oxidative Coupling Reactions with N-Phenyltetrahydroisoquinoline

(2012) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Graphene-Supported RuO2 Nanoparticles for Efficient Aerobic Cross-Dehydrogenative Coupling Reaction in Water

(2012) Qing-Yuan Meng et al.   ORGANIC LETTERS

Azobisisobutyronitrile Initiated Aerobic Oxidative Transformation of Amines: Coupling of Primary Amines and Cyanation of Tertiary Amines

(2012) Lianghui Liu et al.   ORGANIC LETTERS

C-1 Alkynylation of N-Methyltetrahydroisoquinolines through CDC: A Direct Access to Phenethylisoquinoline Alkaloids

(2012) Kamal Singh et al.   SYNLETT

Hydrophobically Assisted Separation-Friendly Mitsunobu Reaction

(2012) Xin-Shan Ye et al.   SYNLETT

Molybdenum trioxide catalyzed oxidative cross-dehydrogenative coupling of benzylic sp3 C–H bonds: synthesis of α-aminophosphonates under aerobic conditions

(2012) Kaliyamoorthy Alagiri et al.   TETRAHEDRON LETTERS

Recyclable Ru/C catalyzed oxidative cyanation of tertiary amines with TBHP

(2012) K. Harsha Vardhan Reddy et al.   RSC Advances

A Highly Efficient Gold-Catalyzed Oxidative CC Coupling from CH Bonds Using Air as Oxidant

(2011) Jin Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acetone Cyanohydrin: A Convenient Alternative of Toxic Sodium Cyanide/Acetic Acid for Oxidative Cyanation of Tertiary Amines

(2011) Sanny Verma et al.   CATALYSIS LETTERS

Starch Immobilized Ruthenium Trichloride Catalyzed Oxidative Cyanation of Tertiary Amines with Hydrogen Peroxide.

(2011) Sanny Verma et al.   ChemCatChem

Visible-light photoredox catalyzed oxidative Strecker reaction

(2011) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines

(2011) Kaliyamoorthy Alagiri et al.   CHEMICAL COMMUNICATIONS

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Oxidative Direct Cyclization ofN-Methylanilines with Electron-Deficient Alkenes Using Molecular Oxygen

(2011) Mayuko Nishino et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrochemical Synthesis and Chemistry of Chiral 1-Cyanotetrahydroisoquinolines. An Approach to the Asymmetric Syntheses of the Alkaloid (−)-Crispine A and Its Natural (+)-Antipode

(2011) Fadila Louafi et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Oxidative Cross-Coupling ofN,N-Dimethylanilines with Heteroarenes under Molecular Oxygen

(2011) Lehao Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Functionalization of (Un)protected Tetrahydroisoquinoline and Isochroman under Iron and Copper Catalysis: Two Metals, Two Mechanisms

(2011) Michael Ghobrial et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies on a Cu-Catalyzed Aerobic Oxidative Coupling Reaction withN-Phenyl Tetrahydroisoquinoline: Structure of Intermediates and the Role of Methanol As a Solvent

(2011) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tropylium Ion Mediated α-Cyanation of Amines

(2011) Julia M. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H functionalization of tertiary amines by cross dehydrogenative coupling reactions: solvent-free synthesis of α-aminonitriles and β-nitroamines under aerobic condition

(2011) Kaliyamoorthy Alagiri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron-Catalyzed Oxidation of Tertiary Amines: Synthesis of β-1,3-Dicarbonyl Aldehydes by Three-Component C–C Couplings

(2011) Weiping Liu et al.   ORGANIC LETTERS

Photochemically Induced Radical Transformation of C(sp3)–H Bonds to C(sp3)–CN Bonds

(2011) Shin Kamijo et al.   ORGANIC LETTERS

Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts

(2011) Shun-Ichi MURAHASHI   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

Copper-catalyzed oxidative trifluoromethylation of benzylic sp3 C–H bond adjacent to nitrogen in amines

(2011) Hiromasa Mitsudera et al.   TETRAHEDRON LETTERS

Iron oligopyridine complexes as efficient catalysts for practical oxidation of arenes, alkanes, tertiary amines and N-acyl cyclic amines with Oxone

(2011) Peng Liu et al.   Chemical Science

Iron-Catalyzed Oxidative Mono- and Bis-Phosphonation of N,N-Dialkylanilines

(2010) Wei Han et al.   ADVANCED SYNTHESIS & CATALYSIS

Heterogeneously Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide/Hydrogen Peroxide using Polymer-Supported Iron(II) Phthalocyanines as Catalyst

(2010) Sweety Singhal et al.   ADVANCED SYNTHESIS & CATALYSIS

α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

(2010) Irina Jovel et al.   CHEMICAL COMMUNICATIONS

Highly efficient oxidative carbon–carbon coupling with SBA-15-support iron terpyridine catalyst

(2010) Peng Liu et al.   CHEMICAL COMMUNICATIONS

Gold-complexes catalyzed oxidative α-cyanation of tertiary amines

(2010) Yan Zhang et al.   CHEMICAL COMMUNICATIONS

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Recent Uses of Iron Catalysts in Organic Reactions

(2010) Liu et al.   CURRENT ORGANIC CHEMISTRY

FeCl3-Catalyzed Oxidative Allylation of sp2and sp3C−H Bond Adjacent to a Nitrogen Atom: Easy Access to Homoallyl Tertiary Amines

(2010) Gullapalli Kumaraswamy et al.   JOURNAL OF ORGANIC CHEMISTRY

Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants

(2010) D. Bradley G. Williams et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Tetrahydroisoquinoline Alkaloids via Anodic Cyanation as the Key Step

(2010) Fadila Louafi et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron opens up to high activity

(2010) Sason Shaik   Nature Chemistry

Copper-Catalyzed Synthesis of α-Amino Imides from Tertiary Amines: Ugi-Type Three-Component Assemblies Involving Direct Functionalization of sp3C−Hs Adjacent to Nitrogen Atoms

(2010) Xin Ye et al.   ORGANIC LETTERS

Catalytic Oxidative Coupling Reactions for the Formation of Carbon-Carbon Bonds without Carbon-Metal Intermediates

(2010) Martin Klussmann et al.   SYNTHESIS-STUTTGART

From Oblivion into the Limelight: Iron (Domino) Catalysis

(2009) Alois Fürstner   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis

(2009) Chun-Xiao Song et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed dehydrogenative phosphonation of N,N-dimethylanilines

(2009) Wei Han et al.   CHEMICAL COMMUNICATIONS

Iron catalyzed oxidative cyanation of tertiary amines

(2009) Wei Han et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed aerobic phosphonation of sp3 C–H bonds

(2009) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

(2009) Sweety Singhal et al.   CHEMICAL COMMUNICATIONS

P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations

(2009) Sason Shaik et al.   CHEMICAL REVIEWS

Iron(iii) chloride in oxidative C–C coupling reactions

(2009) Abdelwareth A. O. Sarhan et al.   CHEMICAL SOCIETY REVIEWS

Oxidation of Tertiary Amines by Cytochrome P450-Kinetic Isotope Effect as a Spin-State Reactivity Probe

(2009) Chunsen Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fe-Catalyzed Oxidative Coupling of Heteroarenes and Methylamines

(2009) Masaki Ohta et al.   Chemistry-An Asian Journal

Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions

(2009) Waldemar Maximilian Czaplik et al.   ChemSusChem

CuBr-Catalyzed Reaction ofN,N-Dimethylanilines and Silyl Enol Ethers: An Alternative Route to β-Arylamino Ketones

(2009) Lehao Huang et al.   ORGANIC LETTERS

Chemoselective C−H Bond Activation: Ligand and Solvent Free Iron-Catalyzed Oxidative C−C Cross-Coupling of Tertiary Amines with Terminal Alkynes. Reaction Scope and Mechanism

(2009) Chandra M. Rao Volla et al.   ORGANIC LETTERS

Iron-Catalyzed Selective Oxidation ofN-Methyl Amines: Highly Efficient Synthesis of Methylene-Bridged bis-1,3-Dicarbonyl Compounds

(2009) Haijun Li et al.   ORGANIC LETTERS

CuBr-Catalyzed Oxidative Difluoromethylation of Tertiary Amines with Difluoroenol Silyl Ethers

(2009) Lingling Chu et al.   ORGANIC LETTERS

Copper/Diethyl Azodicarboxylate Mediated Regioselective Alkynylation of Unactivated Aliphatic Tertiary Methylamine with Terminal Alkyne

(2009) Xiaoliang Xu et al.   ORGANIC LETTERS

The Promise and Challenge of Iron-Catalyzed Cross Coupling

(2008) Benjamin D. Sherry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?

(2008) Stephan Enthaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450

(2008) Shun-Ichi Murahashi et al.   CHEMICAL SOCIETY REVIEWS

Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

(2008) Arkaitz Correa et al.   CHEMICAL SOCIETY REVIEWS

Recent Advances in Iron Catalysis in Organic Synthesis

(2008) Eike Bauer   CURRENT ORGANIC CHEMISTRY

Synthesis of Alkaloids ofGalipea officinalisby Alkylation of an α-Amino Nitrile

(2008) Saurabh Shahane et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Coupling of Tertiary Aliphatic Amines with Terminal Alkynes to Propargylamines via C−H Activation

(2008) Mingyu Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3C−H Bond Activation and Carbon−Carbon Bond Formation

(2008) Shun-Ichi Murahashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Oxidative Cyanation Based on the Concept of Site Isolation

(2008) Toshiki Tajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct electrochemical α-cyanation of N-protected cyclic amines

(2008) Samuel Shikuku Libendi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Oxidative sp3C−H Bond Arylation with Aryl Boronic Acids

(2008) Olivier Baslé et al.   ORGANIC LETTERS