Article
Thermodynamics
Alireza Hassanjani Roushan, Abdollah Omrani
Summary: The successful synthesis of NaX nanocrystals using an organic, additive-free hydrothermal approach was reported in this paper. The NaX nanocrystals were found to act as an effective nucleating agent in the crystallization of PVA, enhancing the crystallinity degree of the nanocomposite. The effective energy barrier for the PVA/NaX nanocrystals system was shown to be smaller than that of neat PVA using the Friedman isoconversional method.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Engineering, Chemical
Wenyao Zhang, Huilong Yan, Qiuwang Wang, Cunlu Zhao
Summary: The study proposes an extended TMS theory applicable to cases with both salinity and temperature gradients, showing good quantitative agreement with experimental data. Results suggest that membrane potential can be enhanced when salinity and temperature gradients are in opposite directions, and can be enhanced or reduced depending on the extent of the TP effect when gradients are in the same direction.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Chemistry, Physical
Wenhan Jia, Isamu Kusaka
Summary: Using a version of dynamical density functional theory, a microscopic structure of hard-sphere fluids in the presence of a temperature gradient was explored. The assumption of local equilibrium was found to predict density profiles accurately even under a large temperature gradient. Oscillatory density profiles indicating particle layering were observed in bulk and in confinement, with theoretical predictions exaggerating the amplitude of oscillation in cases with sharp temperature changes over small distances.
Article
Engineering, Chemical
Mathijs H. B. Born, Niels De Witte, Joeri F. M. Denayer, Tom R. C. Van Assche
Summary: This study used a laboratory-scale experiment to mimic large-scale non-isothermal behavior and found that the efficiency of a polyurethane insulating column was approximately 20% lower than a regular steel column due to adiabatic effects. The difference between isothermal, non-isothermal, and adiabatic limit behavior was demonstrated through experiments and simulations.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Multidisciplinary Sciences
Mohsen Mohammadniaei, Ming Zhang, Jon Ashley, Ulf Bech Christensen, Lennart Jan Friis-Hansen, Rasmus Gregersen, Jan Gorm Lisby, Thomas Lars Benfield, Finn Erland Nielsen, Jens Henning Rasmussen, Ellen Botker Pedersen, Anne Christine Rye Olinger, Laerke Torring Kolding, Maryam Naseri, Tao Zheng, Wentao Wang, Jan Gorodkin, Yi Sun
Summary: The study introduces a novel non-enzymatic isothermal amplification method for rapid detection of SARS-CoV-2 RNA, without the need for reverse transcription, with high specificity and sensitivity. The method is simple, fast, cost-effective, stable, and suitable for a wide range of testing needs.
NATURE COMMUNICATIONS
(2021)
Article
Optics
Yang Shu, Wenchen Zhou, Zhixiong Zhou, Allen Y. Yi
Summary: In this study, a rapid non-isothermal imprinting process for Fresnel lens arrays was proposed, which can be carried out at room temperature to greatly reduce thermal cycle time and energy consumption. The process allows for production of high-quality microlenses with a high precision surface finish.
Article
Engineering, Chemical
Robin Peeters, Vincent Verbruggen, Jan Ronge, Johan A. Martens
Summary: This paper developed a non-isothermal kinetic model to study the production of fresh water from atmospheric water vapor using desiccant pellets in a day-night cycle. The study found that factors like bed thickness and water vapor diffusion have impacts on the absorption efficiency.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Nanoscience & Nanotechnology
Shupeng Chang, Kehuan Wang, Bin Wang, Mateusz Kopec, Zhe Li, Liliang Wang, Gang Liu
Summary: This study investigated the effects of heating parameters on the non-equilibrium microstructure evolution of Ti-6Al-4V alloy. It was found that higher heating rates and lower temperatures resulted in lower β phase volume fraction and finer β grains. When the alloy was heated to 1000℃ at a rate of 50℃/s and then quenched immediately, the tensile strength was improved by 19.5% and the elongation only decreased from 13.6% to 9.6%.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Chemistry, Physical
M. Petryk, I. Boyko, J. Fraissard, N. Lebovka
Summary: This paper theoretically considers the non-isothermal adsorption/desorption of gas in a cylindrical column filled with adsorbent particles. The model is based on Langmuir theory for equilibrium adsorption. Using the Heaviside operational method, analytical solutions for the kinetics of changes in the concentration of adsorbate in the inter- and intra-particle spaces were obtained. Numerical calculations were conducted for gas adsorption at different temperatures of the gas flow, followed by desorption by the flow of inert gas through the column. The results revealed complex interrelations between the spatial-temporal dependencies in the distribution of concentrations of adsorbed gas inside the adsorption column and the temperatures of the inlet gas.
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
(2023)
Article
Engineering, Environmental
Dian Celante, Lisiane O. Diehl, Leoni N. Brondani, Cezar A. Bizzi, Fernanda de Castilhos
Summary: This study investigated the esterification of DEHT catalyzed by TTIP, evaluated the influence of various reaction conditions, proposed a kinetic model, and reached conclusions consistent with the experimental data.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Food Science & Technology
Marlen Petersen, Luyao Ma, Xiaonan Lu
Summary: In this study, a method combining LAMP and PMA treatment was developed for detecting VBNC C. jejuni in agri-foods. The method demonstrated high specificity and quantitative capacity, allowing for rapid and sensitive determination of the pathogenic bacteria in contaminated agricultural products, reducing the risk to public health.
INTERNATIONAL JOURNAL OF FOOD MICROBIOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Shireen Zafar, Sadia Perveen, Shamsul Qamar
Summary: This paper presents a multi-component lumped kinetic model of non-isothermal and non-linear reactive liquid chromatography and demonstrates the thermal effects on reaction kinetics, adsorption equilibria, and conversion-separation studies. A numerical method called total variation bounded (TVB) Runge-Kutta local-projection discontinuous Galerkin finite element method (DG-FEM) is proposed for solving the model equations. The results from numerical simulations verify the accuracy of the DG-FEM method and provide insights into the sensitivity of the conversion-separation process in non-equilibrium and non-isothermal liquid chromatographic reactors.
KOREAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Analytical
Kelly Garnick, Anthony E. Wetherby, Brian Sweeney, Thomas A. Scott, Cong Wei
Summary: A rapid analytical method for quantifying Sr-90 in infant formula prior to secular equilibrium was presented, with data obtained at activity concentrations ranging from 6 Bq/kg to 160 Bq/kg. The method showed high precision and a limit of quantification of 0.5 Bq/kg using 250 g sample portions.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2021)
Article
Microbiology
Lei Wang, Huansen Yang, Kun Wang, Haitao Yang, Mengdi Zhao, Yuping Shang, Fang Wang, Jingquan Dong, Weiguo Zhao, Li Li, Wei Liang, Yan Wang
Summary: A specific, rapid, and sensitive detection method for Bacillus cereus in dairy products has been developed, which can detect the bacteria within 20 minutes at 37°C with no cross-reactivity with other foodborne pathogens. This method is effective for distinguishing emetic from non-emetic strains in dairy products.
FRONTIERS IN MICROBIOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Sukeharu Nomoto, Masahito Segawa, Makoto Watanabe
Summary: In this study, a non-equilibrium multi-phase field method (MPFM) coupled with the Calculation of Phase Diagram (CALPHAD) database was developed for a multicomponent Ni alloy to investigate solidification microstructure in powder-based additive manufacturing. Results showed good agreement between the non- and quasi-equilibrium methods at lower cooling rates, but differences became more pronounced at higher cooling rates. The non-equilibrium MPFM demonstrated its ability to accurately simulate solidification microstructure at high cooling rates in powder bed fusion additive manufacturing.
Article
Engineering, Chemical
Rama Rao Vemula, Mayuresh V. Kothare, Shivaji Sircar
Article
Engineering, Chemical
Rama Rao Vemula, Mayuresh V. Kothare, Shivaji Sircar
Article
Chemistry, Multidisciplinary
V. Rama Rao, C. W. Wu, M. V. Kothare, S. Sircar
SEPARATION SCIENCE AND TECHNOLOGY
(2015)
Article
Engineering, Chemical
Chin-Wen Wu, Rama Rao Vemula, Mayuresh V. Kothare, Shivaji Sircar
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2016)
Article
Chemistry, Multidisciplinary
Rama Rao Vemula, Mayuresh V. Kothare, Shivaji Sircar
SEPARATION SCIENCE AND TECHNOLOGY
(2017)
Article
Chemistry, Physical
Vemula Rama Rao, Mayuresh V. Kothare, Shivaji Sircar
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
(2014)
Article
Engineering, Chemical
V. Rama Rao, S. Farooq, W. B. Krantz
Article
Engineering, Chemical
Vemula Rama Rao, Mayuresh V. Kothare, Shivaji Sircar
Article
Engineering, Chemical
Shreenath Krishnamurthy, Vemula Rama Rao, Sathishkumar Guntuka, Paul Sharratt, Reza Haghpanah, Arvind Rajendran, Mohammad Amanullah, Iftekhar A. Karimi, Shamsuzzaman Farooq
Article
Engineering, Chemical
Vemula Rama Rao, Shamsuzzaman Farooq
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2014)
Article
Engineering, Chemical
Rama Rao Vemula, Shivaji Sircar