Article
Materials Science, Ceramics
Qiang Jing, Fan Zhang, Liwen Lei, Jinyong Zhang
Summary: 3Y-TZP ceramics were prepared using the solid state method and surface carburization process. The effect of surface carburization on low temperature degradation was investigated. It was found that the surface carburized samples exhibited much longer failure time and lower nuclear growth rate compared to the conventionally sintered samples. Carbon dissolved in the zirconia lattice in the form of electrically neutral atoms without disrupting the original charge balance. The precipitation rate of Y3+ from the zirconia lattice was identified as the key factor in determining the low-temperature phase transition. The surface carburization treatment significantly improved the low-temperature degradation performance of 3Y-TZP ceramics, making them suitable for application in low-temperature and humid environments.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Yung-Shin Cheng, Yu-Xin Chen, Wei-Hsing Tuan, Jin-Ren Chen, Po-Liang Lai
Summary: The S-N curve of a composite consisting of ceria-stabilized zirconia (Ce-TZP) and alumina (Al2O3) was measured in this study. The initial bending strength of the Ce-TZP/Al2O3 composite was determined, followed by applying stress above 70% of the initial bending strength for up to 1,000,000 cycles. Transformation bands were formed on the tensile surface, and fatigue failure occurred at the band with the largest width. Post-fatigue heating treatment was effective in removing the transformation bands and enhancing the strength of the material.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Dentistry, Oral Surgery & Medicine
Jasna Cotic, Andraz Kocjan, Sanja Panchevska, Tomaz Kosmac, Peter Jevnikar
Summary: The study assessed the effects of rapid sintering and reduced alumina content on the ageing of 3Y-TZP ceramics in the oral environment. Results showed that materials prepared with rapid sintering aged 1.6 times faster than those with conventional sintering. Discs with polished surfaces exhibited clear signs of ageing after 48 months.
Article
Materials Science, Ceramics
Anna-Lena Merk, Frank Kern
Summary: Two 3Gd-TZP materials with a combination of high toughness and moderate strength were manufactured from intense mixing and milling of unstabilized zirconia starting powders and gadolinia stabilizer oxide, followed by hot pressing at 1250 degrees C - 1400 degrees C. Depending on the starting powder, the materials showed distinct differences in transformation characteristics, sintering temperature dependence of mechanical properties, and the tendency to develop R-curve related deformation features.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Review
Materials Science, Multidisciplinary
R. Shahmiri, O. C. Standard, J. N. Hart, G. Bahmanrokh, Y. Yin, A. Samiee, N. Gharagozlu, C. C. Sorrell
Summary: The grain size of 3Y-TZP is critical for maintaining its tetragonal structure during aging in the oral cavity. However, current fabrication protocols often do not meet this size requirement. This study aims to provide a suitable experimental method for examining grain growth in 3Y-TZP without thermal etching and to investigate the effects of different thermal conditions on grain growth in dental restorations.
JOURNAL OF MATERIALS SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Koji Matsui, Kazuto Nakamura, Mitsuhiro Saito, Akihide Kuwabara, Hidehiro Yoshida, Yuichi Ikuhara
Summary: In this study, the microstructure of 3 mol% Y2O3-stabilized tetragonal ZrO2 polycrystals (Y-TZP) during the early stage of low-temperature degradation (LTD) was analyzed using STEM-nanoprobe and EDS techniques. The effects of grain size and Y3+ concentration within the grains on the LTD behavior were investigated. The results showed that the decrease in Y3+ concentration within the grains accelerated the tetragonal-to-monoclinic phase transformation, while the grain size had minimal effect on the transformation rate.
Article
Engineering, Biomedical
Li Wang, Yang Jiao, Lian Yao, Yang Sheng, Zongdong Hao, Weizhe Tang, Rui Dou
Summary: Dental ceramic materials with excellent mechanical properties and high resistance to low temperature degradation (LTD) can be obtained through the combination of stereolithography (SLA) and microwave sintering (MWS).
JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS
(2023)
Article
Engineering, Multidisciplinary
Tomohiro Harai, Masayoshi Mizutani, Shunichi Shishido, Keisuke Nakamura, Hitoshi Ohmori, Toyohiko J. Konno, Tsunemoto Kuriyagawa
Summary: Low-temperature degradation (LTD) is a problem for the integrity of zirconia implants. This study investigated the LTD properties of zirconia with surface treatment using nanosecond and picosecond pulsed lasers. The results showed that laser treatments deteriorated the LTD resistance of the materials and additional annealing hindered LTD propagation.
PRECISION ENGINEERING-JOURNAL OF THE INTERNATIONAL SOCIETIES FOR PRECISION ENGINEERING AND NANOTECHNOLOGY
(2023)
Article
Chemistry, Physical
Ki-Won Jeong, Jung-Suk Han, Gi-Uk Yang, Dae-Joon Kim
Summary: A study was conducted to investigate the biaxial strength of yttria-stabilized zirconia specimens aged at different temperatures, revealing an increase in strength with higher preaging temperatures due to phase transformations and residual stress effects.
Article
Materials Science, Ceramics
Clara G. Soubelet, Maria P. Albano
Summary: The study investigated the effects of adding different contents of refractory bioglass on Y-TZP and Al2O3-doped Y-TZP bioceramics, with distinct findings between YZ and AYZ. With increasing glass content, fracture toughness slightly increased for YZ but decreased for AYZ.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Suchada Kongkiatkamon, Chaimongkon Peampring
Summary: This study evaluated the effects of regular and speed sintering on the surface structure, translucency, and flexural strength of zirconia. The results showed that speed sintering resulted in smaller grain sizes and slightly lower translucency compared to regular sintering. However, speed sintering exhibited higher flexural strength. Therefore, speed sintering can be considered a suitable method for sintering zirconia.
Article
Dentistry, Oral Surgery & Medicine
Andraz Kocjan, Jasna Cotic, Tomaz Kosmac, Peter Jevnikar
Summary: The study evaluated in vivo aging of biomedical grade 3Y-TZP ceramics in the oral environment and compared it with artificially accelerated in vitro hydrothermal aging at 37 degrees C. The results showed that there were no significant differences in aging between finer and coarser-grained specimens in vivo, but aging rates varied depending on surface treatments, exhibiting different kinetics processes.
Article
Materials Science, Ceramics
Shafique Ahmed, Lifong Zou, Haixue Yan
Summary: This study investigates the low-temperature degradation (LTD) of commercial TZ-3Y-E powder before sintering. The results show that LTD was not observed in the powder after hydrothermal ageing treatment.
ADVANCES IN APPLIED CERAMICS
(2022)
Article
Materials Science, Multidisciplinary
Afiqa Mohamad, Bowen Gong, Tiankai Yao, Adrian R. Wagner, Michael T. Benson, Jie Lian
Summary: This work reports an innovative approach to develop advanced U3Si2 fuels with state-of-the-art materials properties by synergizing multiple effects of microstructure control, oxide protection, and phase transformation-induced mechanically toughening. The incorporation of 3Y-TZP additives enhances fracture toughness and oxidation resistance of U3Si2 fuel, representing a major step towards realizing the potential of high density U3Si2 as the leading fuel concept for nuclear energy systems.
JOURNAL OF NUCLEAR MATERIALS
(2021)
Article
Materials Science, Ceramics
O. Yu. Zadorozhnaya, T. A. Khabas, K. S. Kamyshnaya, V. A. Kutugin, S. E. Malykhin
Summary: The study found that two-step sintering is more effective in controlling the microstructure and achieving good mechanical properties compared to single-step sintering for Al2O3-ZrO2 composites. The composites sintered in two-stage conditions exhibited better resistance to hydrothermal degradation under water vapor pressure, with the highest flexural strength achieved at specific temperature and time parameters.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Anatomy & Morphology
Christoph Lauer, Tobias B. Grun, Isabel Zutterkirch, Raouf Jemmali, James H. Nebelsick, Klaus G. Nickel
Article
Anthropology
Patrick Schmidt, Gerald Buck, Christoph Berthold, Christoph Lauer, Klaus G. Nickel
ARCHAEOLOGICAL AND ANTHROPOLOGICAL SCIENCES
(2019)
Article
Geochemistry & Geophysics
Katja Eder, Laura M. Otter, Limei Yang, Dorrit E. Jacob, Julie M. Cairney
GEOSTANDARDS AND GEOANALYTICAL RESEARCH
(2019)
Article
Multidisciplinary Sciences
Patrick Schmidt, Matthias Blessing, Maxime Rageot, Radu Iovita, Johannes Pfleging, Klaus G. Nickel, Ludovic Righetti, Claudio Tennie
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2019)
Article
Materials Science, Multidisciplinary
Christoph Lauer, Sebastian Haussmann, Patrick Schmidt, Carolin Fischer, Doreen Rapp, Christoph Berthold, Klaus G. Nickel
ADVANCED ENGINEERING MATERIALS
(2020)
Review
Materials Science, Multidisciplinary
Enhui Wang, Xinmei Hou, Yafeng Chen, Zhi Fang, Junhong Chen, Tongxiang Liang, Kuo-chih Chou, Klaus G. Nickel
Summary: With the advancement of science and technology, non-oxide ceramics (NOCs) play a crucial role in various fields at high temperatures. However, they are prone to complex gas-solid interface reactions under harsh conditions, emphasizing the importance of understanding these reactions for material performance improvement. Different approaches, including theoretical, experimental, and simulative methods, are used to efficiently study the reaction behavior and mechanisms of NOCs at the gas-solid interface.
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES
(2021)
Article
Humanities, Multidisciplinary
Patrick Schmidt, Matthias A. Blessing, Tabea J. Koch, Klaus G. Nickel
Summary: The study found that birch tar made with different techniques exhibited varying adhesive performance, suggesting that the simple and low-investment open-air condensation method might have been the preferred production method in the Palaeolithic era.
Article
Multidisciplinary Sciences
Abay Namen, Radu Iovita, Klaus G. Nickel, Aristeidis Varis, Zhaken Taimagambetov, Patrick Schmidt
Summary: This study examines the mechanical properties of lithic raw materials such as chert, porphyry, and shale from Kazakhstan and finds that materials like porphyry possess fracture toughness values comparable to chert, challenging previous assumptions about their quality.
Article
Archaeology
Patrick Schmidt, Tabea J. Koch, Christoph Berthold, Frieder Lauxmann, Klaus G. Nickel
Summary: Birch tar, the first adhesive produced by humans, has implications for human evolution and craftsmanship development. Our study reveals the evolution of tar's mechanical properties during cooking, providing insights for adhesive production.
Article
Multidisciplinary Sciences
Klaus G. Nickel, Patrick Schmidt
Summary: We propose a quantitative framework for understanding the force required for stone tool knapping using different raw materials. Our model explains the process of crack formation and continued stressing during knapping, leading to flake detachment. Our findings allow for understanding the differences in knapping quality between raw materials.
Article
Engineering, Multidisciplinary
Katharina Klang, Klaus G. Nickel
Summary: The spine of the lance sea urchin is a unique lightweight construction with porous features that can be used for producing ceramics. This structure has unique mechanical properties and energy consumption performance, allowing it to exhibit adaptable behavior under compression overload.
Article
Chemistry, Multidisciplinary
Xin Cui, Kaiwen Sun, Jialiang Huang, Jae S. Yun, Chang-Yeh Lee, Chang Yan, Heng Sun, Yuanfang Zhang, Chaowei Xue, Katja Eder, Limei Yang, Julie M. Cairney, Jan Seidel, N. J. Ekins-Daukes, Martin Green, Bram Hoex, Xiaojing Hao
ENERGY & ENVIRONMENTAL SCIENCE
(2019)
Article
Engineering, Multidisciplinary
Christoph Lauer, Kilian Sillmann, Sebastian Haussmann, Klaus G. Nickel
BIOINSPIRATION & BIOMIMETICS
(2019)
Article
Materials Science, Ceramics
S. Kaessner, N. Wichtner, F. Hueller, C. Berthold, K. G. Nickel
JOURNAL OF CERAMIC SCIENCE AND TECHNOLOGY
(2018)
Article
Archaeology
Sabrina Stempfle, Joerg Linstaedter, Klaus G. Nickel, Abdeslam Mikdad, Patrick Schmidt
JOURNAL OF ARCHAEOLOGICAL SCIENCE-REPORTS
(2018)