Journal
MOLECULAR CATALYSIS
Volume 453, Issue -, Pages 132-138Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mcat.2018.04.023
Keywords
Pd-contained perovskite; Intelligent catalyst; Hydrothermal synthesis; Aerobic alcohol oxidation
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Funding
- JSPS KAKENHI [15K06565]
- JSPS Bilateral Joint Research Project
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We successfully prepared Pd-containing perovskite strontium titanate (Pd-STO) by a relatively low-temperature hydrothermal method (i.e., 373 K) without posterior calcination. The particle size and porosity of the STO perovskite could be tuned by changing the molar ratio of H2O/NH3 (e.g., 5.0, 12.5 and 25.0) during the preparation of the amorphous titania sources. The mesoporous contained Pd-STO(12.5) showed superior catalytic performance compared to that of the other Pd-STO(x) (x = H2O/NH3) perovskites for alcohol oxidation with molecular oxygen. Both the refluxing of the non-polar solvents and addition of molecular sieves enhanced the reaction yield significantly. The Pd-incorporated perovskite (Pd-STO) showed better recyclability compared with that of the impregnated perovskite (imp-Pd/STO).
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