Article
Materials Science, Multidisciplinary
Hyunki Kim, Seokjin Hong, Hedam Kim, Yeji Jun, Soo Young Kim, Sang Hyun Ahn
Summary: This review discusses the importance and application prospects of ammonia oxidation reaction (AOR), and highlights the recent progress and strategies in electrical ammonia oxidation electrodes based on the AOR mechanism. Although the AOR mechanism remains unclear, most studies have focused on Pt catalysts.
APPLIED MATERIALS TODAY
(2022)
Article
Chemistry, Multidisciplinary
Katsutoshi Sato, Shuhei Zaitsu, Godai Kitayama, Sho Yagi, Yuto Kayada, Yoshihide Nishida, Yuichiro Wada, Katsutoshi Nagaoka
Summary: Hydrogen is a promising clean energy source, but the presence of carbon monoxide in the reformate is a major issue. Ru-based catalysts are commonly used for removal of carbon monoxide in polymer electrolyte fuel cell systems. However, their durability against nitrogen impurities such as ammonia is a concern. This study investigated the deactivation of an Ru-based PROX catalyst by ammonia and the mechanism of suppression of this deactivation by adding Pt.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Applied
Spencer W. Wallace, Ian T. McCrum, Michael J. Janik
Summary: The catalytic electrochemical oxidation of ammonia on Pt(100) facet is structurally sensitive, with faster nitrogen gas formation due to the stability of NH2* intermediate and the formation of N2H4* from NH2* dimerization at high coverage. Density functional theory calculations can help understand the elementary reaction thermodynamics and kinetics of ammonia oxidation on Pt(100).
Review
Environmental Sciences
Nian Liu, Zhen Sun, Huan Zhang, Lasse Hyldgaard Klausen, Ryu Moonhee, Shifei Kang
Summary: Bacterial and photocatalysis techniques are widely used for the remediation of ammonia nitrogen wastewater. While traditional microbial methods are proven useful, there is a need for more efficient and controllable treatment methods to address the diverse cases of ammonia nitrogen pollution. Bacterial treatment relies on ammonia nitrogen oxidation-reduction by nitrifying and denitrifying bacteria, but these reactions are slow and uncontrolled. Photocatalysis, on the other hand, has advantages such as low temperature reaction and long life, but cannot perform multiple complex biochemical reactions. This review highlights recent achievements, key problems, and future directions for remediation of high-ammonia-nitrogen wastewater using bacterial treatment and photocatalysis techniques, including the potential of combining bacterial-photocatalysis techniques.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Chemistry, Physical
Mengdi Liu, Sai Zhang, Min Chen, Shuxue Zhou, Limin Wu
Summary: In this study, an isolated bimetallic Fe-Ru single atom catalyst was synthesized via anchoring the metal single atoms on nitrogen-doped carbon nanorod spheres. The catalyst exhibits an optimized faradaic efficiency of 29.3% along with an NH3 yield rate of 43.9 & mu;g h(-1) mg(-1) for the NRR under -0.2 V vs. RHE. Control experiments and isotopic labelling test confirm that the generated NH3 originates from the nitrogen (N-2) feeding gas. Computational analysis indicates that Fe acts as the active sites for nitrogen reduction. Impressively, an obvious synergistic effect exists between spatially isolated single atoms, which could be overlooked previously. The electronic structure of Fe sites is effectively influenced by Ru atoms, which results in the d-band center shift and stronger N-2 adsorption, further improving NRR performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Kai Peng, Weiqi Zhang, Narayanamoorthy Bhuvanendran, Qiang Ma, Qian Xu, Lei Xing, Lindiwe Khotseng, Huaneng Su
Summary: In this study, a facile trace Ir-doping strategy was utilized to fabricate Ir-PtZn and IrPtCu alloy NDs catalysts, significantly improving the electrocatalytic activity and durability for methanol oxidation reaction (MOR). The Ir-PtZn/Cu NDs catalysts exhibited enhanced mass activities compared to undoped PtZn and PtCu, as well as Pt/C, in acid medium. The long-term durability test showed that the Ir-doped NDs retained a high percentage of their initial mass activities, highlighting the potential of Ir-doping in developing advanced electrocatalysts for direct methanol fuel cell applications.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Agricultural Engineering
Helga Cristina Fuhrmann Dinnebier, Alexandre Matthiensen, William Michelon, Deisi Cristina Tapparo, Tauani Gabriela Fonseca, Rafael Favretto, Ricardo Luis Radis Steinmetz, Helen Treichel, Fabiane Goldschmidt Antes, Airton Kunz
Summary: This study found that the strain Chlorella sorokiniana (LBA#39) was able to tolerate high concentrations of ammonia nitrogen at neutral pH, showing good biomass productivity and nutrient removal capabilities, providing a sustainable approach for integrating raw materials into agricultural industrial facilities and improving biogas production.
BIORESOURCE TECHNOLOGY
(2021)
Article
Environmental Sciences
Congqi Tian, Ping Yuan, Weili Huang, Feiyu Song, Wenyan Zhao
Summary: Microbial fuel cell-electro-Fenton system (MEF) has gained attention for its ability to remove refractory organic pollutants through in-situ production of H2O2 without external energy supply. A viable strategy to enhance H2O2 production and activation is the development of a bifunctional catalytic cathode. In this study, alpha-FeOOH/MoS2 nanocomposites were fabricated using a novel hydrothermal method. The obtained alpha-FeOOH/1 wt%MoS2 cathode exhibited a high power density and significantly improved electrocatalytic activity and in-situ H2O2 generation. The MEF with alpha-FeOOH/1 wt%MoS2 cathode showed excellent degradation and mineralization performance for various pollutants, making it a promising catalyst for efficient wastewater treatment.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Physical
Kexin Liu, Shilong Yang, Yi Chen, Wenlei Zhang, Pu Liu, Xiucheng Zheng
Summary: In this study, a series of nano hexagonal boron nitride (h-BN) supported CuNi bimetallic catalysts were prepared, and the effects of different ratios and loadings on the hydrolysis reaction of ammonia borane were investigated. The optimal catalyst exhibited outstanding catalytic activity and durability, with high hydrogen generation rate and turnover frequency.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Environmental Sciences
Khyle Glainmer N. Quiton, Ming-Chun Lu, Yao-Hui Huang
Summary: This study investigates the application of bimetallic catalysts in water and wastewater treatment, finding that Fe-based bimetallic catalysts are one of the most efficient heterogeneous catalysts for the treatment of organic and inorganic contamination. The roles and performances of bimetallic catalysts in the removal of environmental contaminants vary.
Article
Chemistry, Multidisciplinary
Dao-Jun Guo, Shu-Kun Cui
Summary: High-performance Pt-WO3/MWCNTao catalysts for methanol electro-oxidation were successfully synthesized in this study, with significantly improved mass activity and a lower CO oxidized potential. The combination of high hydrophilic MWCNTs and the synergistic effect of WO3 were proposed to contribute to the superior performance, making the nano-composites a powerful strategy for obtaining anodic catalysts with super activity in direct methanol fuel cells.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Engineering, Environmental
Gwangtaek Lee, DongYeon Kim, Jong-In Han
Summary: A novel electrochemical approach using a gas diffusion electrode (GDE) was developed to recover NH4+ from livestock wastewater (LW) efficiently. With a current density of 10 mA/cm(2), the GDE-based system showed potential competitiveness in terms of energy consumption compared to traditional stripping methods. Further development of smart operational methods could improve the cost-effectiveness of GDE-based NH4+ recovery from LW.
Article
Energy & Fuels
Vi Thuy Thi Phan, Toan Minh Pham, Hau Quoc Pham, Tai Thien Huynh, Thi Hong Tham Nguyen, Van Thi Thanh Ho
Summary: This study focuses on the synthesis and application of a high-performance Pt3Co1/Ti0.9Ir0.1O2 catalyst for direct methanol fuel cells. By depositing Pt3Co1 alloy nanoparticles on a robust Ti0.9Ir0.1O2 support, the catalyst exhibits improved activity and poisoning tolerance, as well as lower cost and better stability compared to commercial Pt/C catalyst. The success of this work provides a foundation for further development of TiO2-based bimetallic catalysts in the electrochemical catalysis field.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Environmental Sciences
Shiguang Zhuang, Baitao Li, Xiujun Wang
Summary: In this study, a high-performance cathode catalyst Fe3Co1-700 was successfully synthesized and demonstrated comparable or even better catalytic activity and stability in microbial fuel cells (MFCs) compared to commercial Pt/C catalyst. This work provides an effective strategy for regulating the surface electronic state in bimetallic electro-catalysts.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Kathryn Ralphs, Gillian Collins, Haresh Manyar, Stuart L. James, Christopher Hardacre
Summary: The catalysts prepared by mechanochemical method exhibited better selectivity in the selective hydrogenation reaction. The Pt/TiO2 catalyst achieved 100% selectivity to stearyl alcohol.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Physical
Haojie Li, Bingke Yang, Zhen Yao, Xuetao Wang, Kaiming Shen, Mengjie Liu
Summary: This study systematically investigates the influence of metal and nonmetal element doping on the photochemical properties of g-C3N4 for efficient catalytic AB hydrogen production. It provides a design method for high performance bifunctional catalysts of photocatalysis and metal catalysis. The results show that both non-metals (B, P) and metals (Ru, Ni) have efficient regulatory effects on the band structure of g-C3N4, resulting in a reduced band gap and improved hydrogen production. The study offers a theoretical method for the coupling of metal catalysis/photocatalysis ammonia borane to produce hydrogen.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Shrouq Mujahed, Davide Gandolfo, Luigi Vaccaro, Evgueni Kirillov, Dmitri Gelman
Summary: In this study, a high-valent Ru(IV) bifunctional catalyst was successfully applied for the hydrosilylation of various functional groups. The high-valent hydride complexes showed high chemoselectivity and affinity towards reducing polar bonds. The scope, limitations, and plausible mechanism of the reaction were described.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Yongzhen Peng, Kongchen Xia, Qi Wu
Summary: In this study, we report an engineered cyclohexanone monooxygenase that can be used for the asymmetric synthesis of chiral alpha-deuterated carbonyl compounds via enantioselective reductive dehalogenation. The engineered enzyme exhibits good chemoselectivity, stereoselectivity, and d-incorporation, making it a promising method for the synthesis of deuterated drugs.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Qi Yang, Ruixuan Xu, Hongqi Nie, Qilong Yan, Jun Liu, Jiuyu Chen, Yunlan Sun
Summary: The adsorption and decomposition processes of ammonium perchlorate (AP) on pure-Al and Al2O3/Al surfaces were investigated using density functional theory. The results showed that the pure-Al surface is more conducive to the decomposition of AP and the activation of NH3, while the Al2O3/Al surface promotes the disengagement of H and NH3 decomposition.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Yudong Hu, Guochao Xu, Ye Ni
Summary: This study identified a novel phenylalanine dehydrogenase (QtPDH) with high catalytic efficiency and thermal stability, making it a promising biocatalyst for industrial production of bulky aromatic primary amines. QtPDH exhibited a broader substrate specificity and significantly longer half-life compared to BbPDH.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Weiling Zhao, Zhiling Huang, Hui Shen, Xianglong Li, Shaofen Zhao, Bo Xie, Shengjie Xia
Summary: This study investigated the effects of metal doping and crystal plane selection on the CO2 adsorption properties of MgO using density functional theory (DFT) methods. The results showed that the appropriate crystal plane and metal doping can improve the adsorption properties of MgO on CO2. The influence of different crystal planes and metal dopants on CO2 adsorption properties varied significantly. The research provides some references for experimental studies on CO2 adsorption by MgO by combining the dual modification of crystal plane and doped metal.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Jie Zhang, Jinwei Chen, Zongbo Shi, Junyu Zhao, Runsheng Zhuo, Ruilin Wang
Summary: In this study, a double-layered silicalite-1 support with high specific surface area was synthesized, and a magnesium modification strategy was adopted to improve the catalytic activity and stability of the zinc-based catalyst. The modified catalyst showed enhanced propylene selectivity and anti-coking property.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Pei-Sen Gao, Chang-Wang Pan, Cheng Liu, Wen -Tong Chen
Summary: Asymmetric electrocatalysis offers a unique approach to obtain enantioenriched molecules that are difficult to obtain through conventional methods. This study developed a novel bifunctional electrocatalyst, enabling the oxidative kinetic resolution of chiral 1,4-diols and gamma-lactones. The work demonstrates the potential of bifunctional electrocatalysis for asymmetric synthetic methods and its importance in the development of novel electrocatalytic methods.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Qinzhe Lin, Xuanjin Lv, Xianming Zeng, Mengning Zhong, Qiyun Wu, Huilin Ren, Shenpeng Xu, Wentian Chen, Wenting Du, Jun Li
Summary: The catalytic efficiency of engineered IRED M5 was found to be relatively low when tasked with a bulky amine substrate. Rational design led to the mutants M203V and F260A, with F260A exhibiting a substantial improvement in conversion and stereoselectivity. The study revealed the potential molecular mechanisms underlying the effect of F260A and M203V on catalytic performance.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Zhishuai Wang, Fengyun Su, Hailong Cao, Mengzhen Tian, Xiang Li, Haiquan Xie, Xiaoli Jin, Zhengdao Li, Xin Ying Kong
Summary: In this study, the efficiency of photocatalytic CO2 reduction was significantly enhanced by incorporating nickel oxide onto niobium pentoxide. The resulting catalyst showed remarkable methane and carbon monoxide production improvements.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
A. Yu. Sidorenko, Yu. M. Kurban, T. V. Khalimonyuk, I. V. Il'ina, N. S. Li-Zhulanov, O. S. Patrusheva, V. V. Goltsova, M. P. Bei, Zh. V. Ihnatovich, J. Warna, K. P. Volcho, N. F. Salakhutdinov, D. Yu. Murzin, V. E. Agabekov
Summary: This study provides a comprehensive investigation into the catalytic condensation of renewable 3-carene with formaldehyde for the one-step preparation of terpenoid trans-4-hydroxymethyl-2-carene. Various acids and alumino-silicates were found to catalyze the reaction, but the selectivity to the desired product was limited. Phosphoric acid showed the highest selectivity, and an excess of formaldehyde or catalyst loading significantly increased the yield of the target product. Water presence also led to increased selectivity. Additionally, a detailed mechanism for the 3-carene condensation with formaldehyde was proposed and confirmed through kinetic modeling.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Meng-Yu Rong, Jing Nie, Shen Li, Jun-An Ma
Summary: We synthesized a new class of chiral quaternary ammonium salts and used them as catalysts in phase-transfer catalytic asymmetric alkylation. By employing these catalysts, we obtained a series of chiral fluorinated aromatic alpha-amino acid derivatives with high yields and enantioselectivities.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Zhaozhou Wei, Guangtao Wei, Huixian Che, Deyuan Xiong, Linye Zhang, Ruihua Xue, Yalin Tang, Xuanli Lu
Summary: This study demonstrates that small-sized graphite crystallite and highly defective carbon-based catalysts can increase the -SO3H density of the catalysts and modulate their surface electronic properties, leading to improved efficiency in the alpha-pinene hydration reaction. The reduction of graphite crystallite size is considered a critical step in enhancing the selectivity of alpha-terpineol.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Kempanna S. Kanakikodi, Nagendra Kulal, K. S. Subramanya, M. S. Puneethkumar, Bhavana B. Kulkarni, Ganapati Shanbhag, Sanjeev P. Maradur
Summary: An effective and highly selective protocol for synthesizing asymmetric organic carbonates using dimethyl carbonate (DMC) as a reactant and solvent has been developed. The performance of CeO2 nanostructures with different morphologies in the carbonate interchange reaction (CIR) of alcohols was investigated, and the CeO2 nano-catalyst with rod morphology exhibited the highest oxygen vacancy and remarkable enhancement in conversion. The CeO2 characterization data revealed that the exposed active sites, defect density, coordination state of surface atoms, and reducibility of the catalytic materials are the contributing factors to its high catalytic activity. CeO2 can be easily recovered and reused for multiple cycles.
MOLECULAR CATALYSIS
(2024)
Article
Chemistry, Physical
Yanzhao Gao, Xianglei Meng, Shiqi Huang, Hui Wu, Liantao Jiang, Yu Zhou, Yuting Song, Yanyan Diao
Summary: Gamma alumina modified with alkaline earth metal shows improved catalytic performance for hydrogenation reactions. Pd catalysts supported by Al2O3 and Mg-modified Al2O3 were synthesized and their structure, composition, and surface acidity were investigated. The results showed that Pd/MgO-Al2O3-2 catalyst exhibited the best catalytic performance due to its metallic state palladium and weak acid sites.
MOLECULAR CATALYSIS
(2024)