4.7 Article

Uniformly Dispersed and Re-Agglomerated Graphene Oxide-Based Cement Pastes: A Comparison of Rheological Properties, Mechanical Properties and Microstructure

Journal

NANOMATERIALS
Volume 8, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/nano8010031

Keywords

graphene oxide (GO); uniform dispersion; re-agglomeration; rheological properties; hydration products; cement paste

Funding

  1. National Natural Science Foundation of China [51778368, 51578341]

Ask authors/readers for more resources

The properties of graphene oxide (GO)-based cement paste can be significantly affected by the state of GO dispersion. In this study, the effects of uniformly dispersed and re-agglomerated GO on the rheological, mechanical properties and microstructure of cement paste were systematically investigated. Two distinct dispersion states can be achieved by altering the mixing sequence: Polycarboxylate-ether (PCE) mixed with GO-cement or cement mixed with GO-PCE. The experimental results showed that the yield stress and plastic viscosity increased with the uniformly dispersed GO when compared to those of re-agglomerated GO cement paste. Moreover, the 3-day compressive and flexural strengths of uniformly dispersed GO paste were 8% and 27%, respectively, higher than those of re-agglomerated GO pastes. The results of X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy analyses demonstrated that uniformly dispersed GO more effectively promotes the formation of hydration products in hardened cement paste. Furthermore, a porosity analysis using mercury intrusion porosimetry revealed that the homogeneous dispersion of GO can better inhibit the formation of large-size pores and optimize the pore size distribution at 3 and 7 days than the re-agglomerated GO.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Review Chemistry, Physical

The synthetic strategies, photoluminescence mechanisms and promising applications of carbon dots: Current state and future perspective

Chuang He, Peng Xu, Xuanhan Zhang, Wujian Long

Summary: Carbon dots, as a rising star in carbon nanomaterials, have attracted enormous attention for their excellent optical properties, biocompatibility, catalytic performance, small size, low toxicity, and environmental friendliness. Researchers have extensively studied and summarized the synthetic strategies, photoluminescence mechanisms, and promising applications of carbon dots, as well as discussed the prospects and challenges for further research in this field.

CARBON (2022)

Article Construction & Building Technology

Prediction of optimal ranges of mix ratio of self-compacting mortars (SCMs) based on response surface method (RSM)

Lixiao Li, Yuejia Wan, Shangxin Chen, Weiwei Tian, Wujian Long, Jian Song

Summary: The study systematically investigated the effects of constituents on the rheological and mechanical properties of self-compacting mortars, with a focus on factors such as fly ash and sand-to-binder ratio. It was found that an optimal range of FA, SF, s/b, w/b between 10-20%, 6-10%, 1.1-1.2, 0.35-0.36 respectively resulted in better workability and greater compressive strength of SCMs.

CONSTRUCTION AND BUILDING MATERIALS (2022)

Article Construction & Building Technology

Statistical analysis of chloride concentration distribution in concrete by a meso-scale model considering irregular shape aggregates

Zhi-Lu Jiang, Zhi-Wei Qian, Xiang-Lin Gu, Ji-Hua Zhu, Wu-Jian Long, Feng Xing

Summary: This study investigates the probabilistic characteristics of chloride concentration distribution in concrete with irregular aggregates through numerical simulation, which shows that chloride diffusivity is related to the shape of aggregate particles. The results suggest that using more spherical and isotropic aggregates can reduce chloride concentration deviation and improve concrete durability. Therefore, spatial variability of aggregate distribution should be considered in concrete design to ensure structural durability and corrosion resistance.

CONSTRUCTION AND BUILDING MATERIALS (2022)

Article Green & Sustainable Science & Technology

Dynamical properties of environmental high-performance composites with calcined clay

Jingjie Wei, Wu-Jian Long, Kamal H. Khayat, Biqin Dong, Liu Mei, Feng Xing

Summary: This study investigates the dynamic properties of high-performance composite materials HPC-LC3 and proposes a method to enhance the dynamic properties of structures by improving the vibration absorption ability of cement-matrix materials. The results show that incorporating LC3 into traditional HPC can improve its dynamic properties and reduce energy consumption, CO2 emissions, and costs.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Green & Sustainable Science & Technology

Design, dynamic performance and ecological efficiency of fiber-reinforced mortars with different binder systems: Ordinary Portland cement, limestone calcined clay cement and alkali-activated slag

Wu-Jian Long, Zhuorui Wu, Kamal H. Khayat, Jingjie Wei, Biqin Dong, Feng Xing, Jinrui Zhang

Summary: This study compared the dynamic mechanical properties, ecological and economic efficiency of fiber-reinforced mortars (FRMs) made with different binder systems. The results showed that FRMs made with limestone calcined clay cement (LC3) exhibited higher loss factors, appropriate pore size distributions, and good fiber-matrix interfacial properties. Additionally, FRMs made with LC3 showed lower energy consumption and cost compared to other types of mortars.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Construction & Building Technology

Binding Mechanism of CSA Cement on Premixed Cl- and Its Governing Parameters

Yaocheng Wang, Xuelei Jiang, Zhenhao Zhong, Zhicheng Liu, Weiwen Li, Wujian Long, Feng Xing

Summary: Experimental work on calcium sulfoaluminate (CSA) mixes has shown that the binding capacity of CSA cement on external chloride ions is influenced by the water/powder ratio and the presence of gypsum. The study also found that a substance called CAH(10) contributes to the binding of premixed chloride ions. The presence of premixed chloride ions in CSA cement affects the mineralogy and physical properties of the cement, leading to a more densified microstructure.

JOURNAL OF MATERIALS IN CIVIL ENGINEERING (2022)

Article Construction & Building Technology

Accelerating effect of calcined hydrotalcite-Na2SO4 binary system on hydration of high volume fly ash cement

Wujian Long, Jing Xie, Xuanhan Zhang, Shicong Kou, Feng Xing, Chuang He

Summary: This work proposes a new method to overcome the slow setting and low early strength of cement-based composites with high-volume fly ash (HVFA). The effects of a binary system containing calcined hydrotalcite (CHT) and Na2SO4 (NS) on the early strength, hydration process, pore structure, and microstructural morphology of HVFA composites were investigated. Results showed that the CHT and NS co-doped system exhibited better performance in improving the mechanical properties and porosity of HVFA cement than the CHT or NS single system, due to the accelerated hydration process, increased hydration product content, and refined pore structure. These findings provide guidance for enhancing the early strength of HVFA concrete in practical engineering.

CONSTRUCTION AND BUILDING MATERIALS (2022)

Article Construction & Building Technology

Recycling of waste cathode ray tube glass through fly ash-slag geopolymer mortar

Wu-Jian Long, Xuanhan Zhang, Jing Xie, Shicong Kou, Qiling Luo, Jingjie Wei, Can Lin, Gan-Lin Feng

Summary: An effective method for recycling waste CRT glass is to use fly ash-slag geopolymer composite as fine aggregate. The silica modulus and alkali dosage have significant effects on the performance of the geopolymer. The optimal alkali dosage and silica modulus for recycling CRT glass with geopolymer are determined to be 6% and 1.5, respectively.

CONSTRUCTION AND BUILDING MATERIALS (2022)

Article Chemistry, Physical

Hydration Behavior of Magnesium Potassium Phosphate Cement: Experimental Study and Thermodynamic Modeling

Jinrui Zhang, Wenjun Niu, Zhen Liu, Youzhi Yang, Wujian Long, Yuanyuan Zhang, Biqin Dong

Summary: The hydration behavior of MKPC was investigated through various material characterization methods and thermodynamic modeling. The results showed that K-struvite is the main hydration product of MKPC, and the structure became denser with the increase in curing age. Additionally, thermodynamic modeling was effective in analyzing the hydration behavior of MKPC.

MATERIALS (2022)

Article Materials Science, Multidisciplinary

Synergistic Effect of HEDP.4Na and Different Induced Pouring Angles on Mechanical Properties of Fiber-Reinforced Alkali-Activated Slag Composites

Jingjie Wei, Jianwei Liu, Kamal H. Khayat, Wu-Jian Long

Summary: This study aimed to improve the flexural and damping properties of fiber-reinforced alkali-activated slag composites (FR-AASC) by using organic phosphonates (HEDP.4Na) and different pouring methods. The results showed that using 0.3% HEDP.4Na combined with a 150 degrees-induced pouring angle significantly enhanced the mechanical properties of FR-AASC compared to the reference group. The compressive and flexural strength, damping energy consumption, and storage modulus of the FR-AASC sample cast using 0.3% HEDP.4Na and the 150 degrees-induced pouring angle increased by 20%, 60%, 78%, and 30%, respectively.

FIBERS (2023)

Article Construction & Building Technology

Ai-guided proportioning and evaluating of self-compacting concrete based on rheological approach

Boyuan Cheng, Liu Mei, Wu-Jian Long, Shicong Kou, Lixiao Li, Songyuan Geng

Summary: This study introduces a novel approach by utilizing a random forest algorithm to predict the rheology, workability, and mechanical properties of Self-Compacting Concrete (SCC). The models exhibit high accuracy and provide valuable insights for designing SCC mixtures tailored to specific requirements. The findings contribute to the advancement of SCC technology and have significant implications for the construction industry.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Construction & Building Technology

Interpretable auto-tune machine learning prediction of strength and flow properties for self-compacting concrete

Wujian Long, Boyuan Cheng, Shengyu Luo, Lixiao Li, Liu Mei

Summary: The purpose of this study is to establish highly nonlinear relationships between SCC mix proportions and properties using machine learning techniques and providing interpretable models to guide SCC design. The proposed models exhibit high accuracy in predicting the key properties of SCC through careful feature engineering, model training, and hyper-parameter optimization. Experimental verification shows that the proposed models can accurately predict the properties of C45, C50, and C55 SCC.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Construction & Building Technology

Three-dimensional pore structure characterization of cement paste by X-ray computed tomography (XCT) and focused ion beam/scanning electron microscopy (FIB/SEM)

Zhilu Jiang, Yingjie Pan, Chuanqing Fu, Weiwen Li, Yaocheng Wang, Wu-Jian Long

Summary: This paper aims to investigate the 3-D pore structure of cement paste at different scales using XCT and FIB/SEM. The results show that pore structures measured by FIB/SEM are more heterogeneous than those measured by XCT. Additionally, the pore connectivity decreases with decreasing water-cement ratio, increasing curing age, and the addition of fly ash/slag. The reduction in connectivity due to fly ash is more significant based on the observations by XCT compared to FIB/SEM. The transport-related tortuosity differs from geometric tortuosity, and the diffusional tortuosity exhibits a larger discrepancy from hydraulic tortuosity at lower porosity.

CONSTRUCTION AND BUILDING MATERIALS (2023)

Article Green & Sustainable Science & Technology

AI-guided design of low-carbon high-packing-density self-compacting concrete

Boyuan Cheng, Liu Mei, Wu-Jian Long, Shicong Kou, Qiling Luo, Yanjin Feng

Summary: Self-compacting concrete (SCC) has gained popularity in modern engineering, but traditional design methods face challenges such as high material and labor costs, as well as elevated carbon emissions and energy consumption. To address these issues, this study proposes a novel approach that combines the compressible packing model with machine learning, enabling the intelligent design of low-carbon, high-packing-density SCC.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Chemistry, Physical

Mechanical Properties and Hydration Degree of Magnesium Potassium Phosphate Cement Modified by Sintered Silt Ash

Hongguang Zhang, Wenya Yang, Qiling Luo, Wu-Jian Long

Summary: This study systematically analyzed the influence of sintered silt ash (SSA) on magnesium potassium phosphate cement (MKPC). The results showed that blending SSA into MKPC can improve its compressive strength. Additionally, SSA can delay the hydration reaction of MKPC and increase its hydration degree.

MATERIALS (2023)

No Data Available