Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 32, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc02266f
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Funding
- Federal Agency for Scientific Organizations (FASO Russia) [AAAA-A18-118020290146-2]
- Russian Foundation for Basic Research [16-33-60122]
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A series of novel (S)-amino acid derivatives bearing planar-chiral (3-acylamino-1,2-dicarba-closo-dodecaboran-1-yl)acetyl substituents was synthesized. Carboranyl amino esters were obtained in a diastereomerically pure form (according to chiral HPLC). Single crystals of individual diastereomers were studied by optical microscopy, X-ray diffraction analysis and piezoresponse force microscopy. The piezoelectric activity of some compounds was shown to exceed that of most known organic piezoelectrics.
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