Self-standing and shape-memorable UV-curing epoxy polymers for three-dimensional (3D) continuous-filament printing

In the development of three-dimensional printable materials for high-speed and high-resolution printing, UV-curing polymers can guarantee fast and precise printing of high performance load-bearing structures, but the injected drops of the monomers tend to spread over the substrates due to their low viscosity. In this study, we imposed the self-standing and shape-memorable capability of an epoxy acrylate (EA) monomer to ensure continuous filamentary 3D printing while maintaining its low viscosity nature. Using octadecanamide (ODA) with EA, strong hydrogen-bond networks (-N-H center dot center dot center dot O=C-N-C=O center dot center dot center dot H-O-, -N-H center dot center dot center dot N-) were additionally achieved in the material system and the developed material distinctively exhibited rheological duality at different processing stages: a low-viscosity liquid-like behavior (viscosity of B50 Pa) while passing through the nozzle and a self-standing solid-like behavior (static yield stress of B364 Pa) right after being printed. This reversible liquid-to-solid transitional capability was quantified by viscoelastic complex moduli provided a dynamic yield stress (ty, G) of 210 Pa corresponding to the upright stacking up to B3.2 cm (3 wt% of ODA). The time (ty, G) required for conformational rearrangement was evaluated to be as fast as B10 similar to 2 s. After UV curing, the 3D printed layers exhibited no air pockets or weld lines at the stacked interfaces, which could guarantee excellent mechanical performance and structural integrity.