4.6 Article

Alternative to visbreaking or delayed coking of heavy crude oil through a short contact time, solid transported bed cracking process

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 8, Issue 2, Pages 540-550

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy01281k

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Funding

  1. ECOPETROL SA
  2. Spanish Government-MINECO through the program Severo Ochoa [SEV 2016-0683]
  3. MINECO/FEDER [CTQ2015-70126-R]
  4. Generalitat Valenciana through the Prometeo program [PROMETEOII/2013/011]

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An extra-heavy crude oil was treated at a short contact time in the 510-580 degrees C temperature range in a FCC-like process, first thermally and then in the presence of a solid with low catalytic activity. The treatment greatly improved the properties of the crude oil, reducing the density and viscosity to values that make the oil transportable without dilution in a pipeline. In addition, the upgraded oil was substantially free of contaminants such as metals and heptane insolubles. The use of the solid allowed upgrading all properties with a minimum coke penalty. The residual fraction of the upgraded oil had to be eliminated to obtain a syncrude stable in asphaltene proof, which could be obtained by recycling to extinction in a cracking reactor.

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