Mechanistic insights into the SN2-type reactivity of aryl-Co(iii) masked-carbenes for C–C bond forming transformations

Cobalt(II)-based Metalloradical Activation of 2-(Diazomethyl)pyridines for Radical Transannulation and Cyclopropanation

(2018) Satyajit Roy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Amido Esters and Amido Phosphonates through Carbonylation of Diazo Compounds Followed by Nucleophilic Addition Reaction

(2017) Kankanala Ramakrishna et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of Cp*CoIII/RhIII-Catalyzed Directed C–H Functionalization with Diazo Compounds

(2017) Shuanglin Qu et al.   JOURNAL OF ORGANIC CHEMISTRY

Carboxylate-Assisted Formation of Aryl-Co(III) Masked-Carbenes in Cobalt-Catalyzed C–H Functionalization with Diazo Esters

(2017) Oriol Planas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

(2017) Yong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Access to Cobaltacycles via C–H Activation: N-Chloroamide-Enabled Room-Temperature Synthesis of Heterocycles

(2017) Xiaolong Yu et al.   ORGANIC LETTERS

Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII–Carbene radical and o-quinodimethane intermediates

(2017) Colet te Grotenhuis et al.   Chemical Science

Cooperative Lewis Acid/Cp*CoIIICatalyzed C−H Bond Activation for the Synthesis of Isoquinolin-3-ones

(2016) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of Key Organometallic Aryl-Co(III) Intermediates in Cobalt-Catalyzed C(sp2)–H Functionalizations and New Insights into Alkyne Annulation Reaction Mechanisms

(2016) Oriol Planas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CoIII–Carbene Radical Approach to Substituted 1H-Indenes

(2016) Braja Gopal Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic Cyanoalkylation through Double C–H Activation Mediated by Ni(III)

(2016) Wen Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-catalyzed C−H Activation

(2016) Miaoshen Su et al.   JOURNAL OF THE CHINESE CHEMICAL SOCIETY

Amidines for Versatile Cobalt(III)-Catalyzed Synthesis of Isoquinolines through C–H Functionalization with Diazo Compounds

(2016) Jie Li et al.   ORGANIC LETTERS

Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins

(2016) Soham Maity et al.   ACS Catalysis

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Manganese Catalyzed C–H Halogenation

(2015) Wei Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

(2015) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H bond functionalization based on metal carbene migratory insertion

(2015) Fangdong Hu et al.   CHEMICAL COMMUNICATIONS

Recent Advances in First-Row-Transition-Metal-Catalyzed Dehydrogenative Cou­pling of C(sp3)-H Bonds

(2015) Jinmin Miao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Aromatic Methoxylation and Hydroxylation by Organometallic High-Valent Nickel Complexes

(2015) Wen Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Carbonylative Cyclization of Pyridinyl Diazoacetates for the Synthesis of Pyridoisoquinolinones

(2015) Yonghyeon Baek et al.   ORGANIC LETTERS

Cp ∗ Co(III)-catalyzed direct functionalization of aromatic C–H bonds with α-diazomalonates

(2015) Xu-Ge Liu et al.   TETRAHEDRON LETTERS

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)H Bond Alkenylation by Alkynes

(2014) Liene Grigorjeva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group

(2014) Ayana Yokota et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct observation of two-electron Ag(I)/Ag(III) redox cycles in coupling catalysis

(2014) Marc Font et al.   Nature Communications

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-catalyzed ortho-C–H halogenations of benzamides

(2013) Lianhui Wang et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Palladium-catalysed hydroxylation and alkoxylation

(2011) Stephan Enthaler et al.   CHEMICAL SOCIETY REVIEWS

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIIICatalytic Cycle

(2011) Alicia Casitas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions

(2010) Alicia Casitas et al.   Chemical Science

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Nitrogen-Containing Heterocycles by CH Bond Functionalization

(2009) Praew Thansandote et al.   CHEMISTRY-A EUROPEAN JOURNAL