Article
Materials Science, Composites
Feng Gao, Renbo Wei, Lingyun Zhou, Wei Luo, Zhiqiang Li, Lingyun Pang, Shuang Li, Xiufu Hua, Lingling Wang
Summary: This study synthesized SPEN@CCTO/PEN nanocomposites by modifying hydroxylated CCTO with SPEN and integrating it into the PEN matrix. The nanomaterials effectively prevented agglomeration of CCTO and improved interfacial adhesion, resulting in superior dielectric characteristics and energy storage density. Furthermore, the excellent mechanical properties make SPEN@CCTO/PEN a promising flexible dielectric material for future applications.
POLYMER COMPOSITES
(2023)
Article
Chemistry, Physical
Diao Yuan, Yajun Qin, Songsong Li, Shenghua Du, Yaoyao Xu, Qiang Weng, Pei Chen, Xinbing Chen, Zhongwei An
Summary: A novel monomer DFTMTE was synthesized and utilized to prepare densely sulfonated copolymer membranes with high ion exchange capacity and conductivity, exhibiting significantly improved performance compared to commercially available membranes, attributed to excellent microphase separation and quinoxaline-based crosslinking.
JOURNAL OF POWER SOURCES
(2021)
Article
Polymer Science
Zahra Esmaeilzadeh, Mohammad Karimi, Ahmad Mousavi Shoushtari, Mehran Javanbakht
Summary: This study successfully fabricated and characterized the SPEEK nanocomposite of polydopamine coated multi-walled carbon nanotube (P@MWCNT), showing improved dimensional stability and enhanced proton conductivity. Through innovative approach based on interfacial energies, it was found that increasing the interfacial energy between P@MWCNTs and polymer chains contributes to the transfer of protons along the interface region of nanofiller and matrix.
Review
Chemistry, Physical
Minghan Xu, Hao Xue, Qingfu Wang, Lichao Jia
Summary: Proton exchange membrane fuel cells (PEMFCs) are potential clean energy sources attracting attention, with a focus on developing high-performance, low-cost PEMs to replace benchmark Nafion membranes. Sulfonated poly(arylene ether ketone)s (SPAEKs) and sulfonated poly(arylene ether sulfone)s (SPAESs) are promising candidates due to their performance and cost advantages. Efforts are classified and introduced in developing SPAEK and SPAES membranes for promising research directions in the field.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Polymer Science
Prem P. Sharma, Vo Dinh Cong Tinh, Dukjoon Kim
Summary: Enhancement in ion cluster size of sulfonated poly (arylene ether sulfone) (SPAES)-based membranes was successfully achieved by encapsulating basic pendent branches as side groups, leading to improved proton conductivity and excellent chemical stability. The synthesized hybrid membrane demonstrated potential application in electrochemical and proton exchange membrane fuel cell applications with stable performance.
Article
Biochemistry & Molecular Biology
Zhoulin Ye, Nanjie Chen, Zigui Zheng, Lei Xiong, Dongyang Chen
Summary: In this study, the introduction of nano-sized SiO2 particles in sulfonated poly(arylene ether) proton exchange membranes (PEMs) was shown to improve mechanical strength and thermal stability, decrease ion exchange capacity, water uptake, and swelling ratio, as well as reduce proton and vanadium ion permeability. As a result, the H+/VO2+ selectivity of the composite PEMs was significantly enhanced, providing a cost-effective solution for potential vanadium redox flow battery (VRFB) applications.
Article
Chemistry, Physical
Zhuoyu Yin, Haobo Geng, Pengfei Yang, Benbing Shi, Chunyang Fan, Quan Peng, Hong Wu, Zhongyi Jiang
Summary: A sulfonated covalent organic framework nanosheets (TpPa-SO3H) were synthesized and incorporated into SPEEK matrix to prepare proton exchange membranes with increased ion exchange capacity and reduced swelling ratio. The SPEEK/TpPa-SO3H-5 membrane exhibited significantly improved proton conductivity and mechanical strength, leading to favorable performance in a single H-2/O-2 fuel cell.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Lingxin Meng, Mengchi Ju, Jingmei Xu, Xuan Chen, Pengyun Zhao, Jinxuan Lei, Tian Lan, Fenglong Chen, Ziyi Hu, Zhe Wang
Summary: In this study, fluorenyl-containing sulfonated poly(arylene ether ketone sulfone)s were synthesized and hybrid membranes with high proton conductivity and low swelling ratio were successfully prepared. By adding specific fillers, the proton conductivity and water absorption of the membranes were improved. The obtained hybrid membranes showed promising potential for application in proton exchange membrane fuel cells.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Polymer Science
Xulin Yang, Ying Li, Wenwu Lei, Xidi Liu, Qian Zeng, Qiancheng Liu, Wei Feng, Kui Li, Pan Wang
Summary: This study investigates the thermal pyrolysis behavior of diphenolic acid-based Poly (arylene ether nitrile) under a non-oxidizing gaseous environment, revealing a third-order degradation mechanism and providing insights for understanding the identification, structural determination, and thermal resistance of PAEN materials.
POLYMER DEGRADATION AND STABILITY
(2021)
Article
Polymer Science
Riddhi Kamble, Arijit Ghorai, Bholanath Ghanti, Debabrata Pradhan, Susanta Banerjee
Summary: A series of polymer-metal-organic frameworks (MOF) hybrid composite membranes were prepared and their properties were analyzed and compared. The results showed that incorporating MOF into the polymer matrix can significantly improve proton conductivity, water uptake, and swelling without affecting oxidative stability.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Polymer Science
Yang Yu, Zheng Zeng, Xuesong Gao, Chunyong Xiong, Huamei Zhu, Hongyu Cen, Xuan Zheng, Qingting Liu, Tao Hu, Chonggang Wu
Summary: To enhance proton conductivity, sulfonated poly(ether ether ketone) (SPEEK) was covalently grafted with segments containing multiple propanesulfonic acid groups (MS-SPEEK-102). The resulting MS-SPEEK-102 exhibited higher proton conductivity and power density compared to SPEEK, attributed to the increased number of sulfonic acid groups and construction of uninterrupted proton-conducting channels through the movement of flexible side-chain segments. This study presents a potential approach for obtaining a proton exchange membrane with improved proton conductivity based on SPEEK.
MACROMOLECULAR RAPID COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Vo Dinh Cong Tinh, Vu Dong Thuc, Dukjoon Kim
Summary: To facilitate the commercialization of proton exchange membrane fuel cells, the decomposition of the polymer electrolyte membrane needs to be addressed. A functional sulfonic acid group grafted onto poly(arylene ether sulfone) by sulfide linkages was synthesized to prevent degradation. Additionally, cerium oxide nanoparticles were prepared for radical scavenging. The layer-by-layer membrane containing cerium oxide showed lower voltage loss rate and maintained proton conductivity.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Polymer Science
Yanhui Wang, Pei Chen, Qiang Weng, Xinbing Chen, Zhongwei An
Summary: Semi-interpenetrating polymer network (sIPN) proton exchange membranes prepared from sulfonated polyimides and cross-linkable sulfonated poly(arylene ether)s showed significantly higher performance due to the interlocked structures. The sIPN membrane sIPN-SPAEK(2/1)-SPI exhibited good mechanical properties, high stability, reasonably high proton conductivity, and low methanol permeability.
Article
Chemistry, Physical
Merve G. Seden, Emre Basturk, Tulay Y. Inan, Nilhan K. Apohan, Atilla Gungor
Summary: In this study, molecular weight-controlled and fluorine-containing polyarylethers (MWCPAEs) were synthesized and blend membranes with excellent properties were prepared through sulfonation and blending. The chemical, mechanical, thermal, and hydrolytic properties of the blend membranes are comparable to or better than Nafion.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Nanoscience & Nanotechnology
Yunji Xie, Di Liu, Anna Ringuette, Patrick Theato
Summary: Branched sulfonated polymers with ultradensely sulfonated branched centers, called B-x-SPAEKS, show reduced water affinity compared to analogous polymers with sulfonated branched arms, resulting in lower swelling and proton conductivity. However, further analysis reveals that B-x-SPAEKS exhibit significantly better proton conduction due to the formation of larger hydrophilic clusters that promote efficient proton transportation.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Polymer Science
Xiaohong He, Hongguo Shou, Xiaobo Liu, Kun Jia
Summary: In this study, silver nanoparticles were synthesized and successfully modified the crystallization behavior of PET-PEG elastomers, enhancing their mechanical properties. The results demonstrate the potential application of silver nanoparticles in the preparation of multifunctional polyester elastomers.
Article
Polymer Science
Pan Wang, Xidi Liu, Hai Liu, Xiaohong He, Dawei Zhang, Jiaqi Chen, Ying Li, Wei Feng, Kun Jia, Jing Lin, Kui Li, Xulin Yang
Summary: Polyarylene ether-based polymer with photoluminescence was further functionalized to be a thermal resistant, tough, and flexible optical material. The end-capped polymers exhibited strong aggregation-induced emission with high quantum yield of fluorescence. The molecular weights and processing methods significantly impacted the fluorescence properties of the polymers, showing potential applications in various optical fields.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Chemistry, Physical
Shuning Liu, Ling Tu, Chenchen Liu, Lifen Tong, Zhongxiang Bai, Guo Lin, Kun Jia, Xiaobo Liu
Summary: This study focuses on preparing high-temperature resistant composites by introducing nitrile-functionalized agents on the surface of multiwalled carbon nanotubes. The resulting composites exhibit excellent mechanical, thermal, and dielectric properties, making them suitable for energy storage applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Polymer Science
Penglun Zheng, Rui Wang, Xiaoliang Peng, Jichang Sun, Huaiyin Liu, Junwei Li, Chuanbang Liu, Lan Jiang, Quanyi Liu, Yu Zhang
Summary: In this study, a multiple cross-linking reaction was carried out in epoxy resin (EPs) by introducing nitrile groups and the benzoxazine ring, followed by a simple heat treatment. The resulting halogen/phosphorus-free and environmentally friendly network not only suppresses the migration of the functional flame retardants from the substrate, but also shows significantly enhanced flame-retardant properties.
HIGH PERFORMANCE POLYMERS
(2022)
Article
Materials Science, Multidisciplinary
Tian Liu, Mingzhen Xu, Zhongxiang Bai, Xiaoqian Xu, Dengxun Ren, Wenjin Chen, Xiaobo Liu
Summary: A strategy for toughening phthalonitrile-based resin containing benzoxazine (BA-Ph) with poly (aryl ether nitrile) (PP-PEN) was proposed. The influence mechanism of PP-PEN with different molecular weight on the polymerization process and cross-linking structure of BA-Ph was explored. Glass fiber reinforced composite laminates (BA-Ph/PP-PEN/GF) were fabricated and the effect of PP-PEN molecular weight on the mechanical and thermal properties was investigated.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Rui Wang, Penglun Zheng, Junwei Li, Jichang Sun, Huaiyin Liu, Xue Li, Quanyi Liu
Summary: By synthesizing a new flame retardant and incorporating it into epoxy resins, the flame retardancy of the epoxy resins can be significantly improved, achieving a UL-94 V-0 rating. This simple and effective method has potential for development in engineering applications.
Review
Chemistry, Multidisciplinary
Jichang Sun, Chuanbang Liu, Huaiyin Liu, Junwei Li, Penglun Zheng, Yun Zheng, Zhihong Liu
Summary: This review summarizes the recent advances in organic-inorganic composite solid electrolytes (CSE) with ordered architectures for solid-state lithium batteries. The study highlights the significant improvement in ionic conductivities achieved through the incorporation of ordered inorganic fillers in CSE. The review provides researchers with valuable insights for achieving ordered structures in CSE to enhance the performance of advanced solid-state lithium batteries.
Article
Polymer Science
Huaiyin Liu, Junwei Li, Jichang Sun, Haihan Zhao, Jing Wu, Yun Zheng, Penglun Zheng
Summary: An organic-inorganic composite flame retardant (HKDC) containing multi-element P/N/Si was successfully synthesized to improve the flame retardant properties of epoxy resins (EP). This flame retardant utilizes the synergistic effect of multiple elements to achieve excellent flame retardant effect with low addition amount in EP. It not only reduces the migration of molecules through the structure of inorganic substances, but also increases the compactness with the EP matrix.
HIGH PERFORMANCE POLYMERS
(2023)
Article
Polymer Science
Huaiyin Liu, Penglun Zheng, Junwei Li, Jichang Sun, Rui Wang, Haihan Zhao, Jing Wu, Yun Zheng, Quanyi Liu
Summary: An active P/N/Si flame retardant containing a double bond was synthesized to enhance the flame retardancy properties of epoxy resins. The addition of the flame retardant reduced pHRR and TSR by 51.7% and 29.8%, respectively, while inhibiting the release of toxic fuels and smoke.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Polymer Science
Haihan Zhao, Junwei Li, Rui Wang, Huaiyin Liu, Jichang Sun, Jing Wu, Penglun Zheng
Summary: This study synthesized a novel interpenetrating polymer network structure by introducing double bonds into flame retardants based on crosslinking strategy, aiming to improve the flame retardancy of epoxy resins. The increased crosslink density improved the mechanical properties and fire retardancy of the EP thermosets.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Junwei Li, Penglun Zheng, Huaiyin Liu, Jichang Sun, Yawei Meng, Haihan Zhao, Jing Wu, Yun Zheng, Quanyi Liu
Summary: Flame retardant epoxy resin with improved fire resistance and microstructure has been developed by using Cu2+ and DOPO system, which effectively enhances the flame retardancy and tightness of the resin. The addition of flame retardant leads to well-defined fire resistance and improved physical properties of the resin.
Article
Polymer Science
Junwei Li, Quanyi Liu, Yumei Zhou, Yuming Cai, Kaikai Shi, Haihan Zhao, Yawei Meng, Penglun Zheng
Summary: A multicomponent flame retardant (Sp-ACDH) containing P/N/S was synthesized and applied to epoxy resin, which enhanced the flame retardancy of the resin. With the addition of 10 wt% Sp-ACDH, the epoxy composite achieved UL-94 V-0 rating and had an LOI of 32.7%. Moreover, Sp-ACDH effectively reduced the heat release rate of the epoxy resin. Characterization results using SEM, Raman spectroscopy, and TG-FTIR spectra confirmed the flame-retardant properties of Sp-ACDH in both gas and condensed phases.
HIGH PERFORMANCE POLYMERS
(2023)
Article
Polymer Science
Junwei Li, Qiuju Ma, Quanyi Liu, Penglun Zheng
Summary: A phosphorus-nitrogen synergistic flame retardant was synthesized, which enhanced the flame retardancy of epoxy composites through the cross-linking effect of nitrile groups and the introduction of flexible chain segments. The study also found that the addition of DPVHD improved the flexural properties of the epoxy resin matrix.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Polymer Science
Mingzhen Xu, Bo Li, Xiongyao Li, Zexu Fan, Dengxun Ren
Summary: This study systematically investigates the curing behaviors of self-polymerization epoxy/phthalonitrile (APPEN) pre-polymers. The key factors affecting the co-polymerization of APPEN are defined, and appropriate pre-polymerization conditions are analyzed. The thermomechanical and mechanical properties of glass-fiber-reinforced APPEN laminates are analyzed, revealing their outstanding performance. The findings contribute to the application of epoxy-matrix-based composites in high-performance polymer composites.
Review
Chemistry, Multidisciplinary
Junwei Li, Haihan Zhao, Huaiyin Liu, Jichang Sun, Jing Wu, Quanyi Liu, Yun Zheng, Penglun Zheng
Summary: The use of polymer materials is closely related to our manufacturing life, but their combustibility and toxic fumes limit their usage. Metal-based flame retardants can enhance the flame-retardant properties and smoke suppression performance of polymers. This study systematically presents the research progress and flame-retardant mechanism of flame-retardant polymers using flame retardants from different groups of metals.