Lithium Enolates: ‘Capricious’ Structures - Reliable Reagents for Synthesis

(S)-(-)-2-ALLYLCYCLOHEXANONE

(2014)   ORGANIC SYNTHESES

PREPARATION OF (S)-2-ALLYL-2-METHYLCYCLOHEXANONE

(2014)   ORGANIC SYNTHESES

Method of Continuous Variations: Applications of Job Plots to the Study of Molecular Associations in Organometallic Chemistry

(2013) Joseph S. Renny et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model

(2013) Yun Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mixed Aggregates of an Alkyl Lithium Reagent and a Chiral Lithium Amide Derived from N-Ethyl-O-triisopropylsilyl Valinol

(2013) Chicheung Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of 2,3-Disubstituted Indanones via Pd-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Ketones

(2013) Xiao-Hui Li et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Allylic Substitution Reactions: Stereoselective Construction of α- and β-Substituted Carbonyl Compounds

(2013) P. Evans et al.   SYNTHESIS-STUTTGART

The Diaryl(oxy)methyl Group: More than an Innocent Bystander in Chiral Auxiliaries, Catalysts, and Dopants

(2012) Manfred Braun   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly stereoselective modifications of peptides via Pd-catalyzed allylic alkylation of internal peptide amide enolates

(2012) Swarup Datta et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

How Does Palladium Coordination Affect the Electrophilicities of Allyl Cations? Development of a Robust Kinetic Method for Following Reactions of [(η3-Diarylallyl)Pd(PPh3)2]+ with Nucleophiles

(2012) Konstantin Troshin et al.   ORGANOMETALLICS

Enantioselective rhodium-catalyzed allylic alkylation of acyclic α-alkoxy substituted ketones using a chiral monodentate phosphite ligand

(2012) P. Andrew Evans et al.   Chemical Science

Palladium-Catalyzed Allylic Alkylation of Doubly Deprotonated Carboxylic Acids

(2011) Manfred Braun et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Allylic Alkylation of Carboxylic Acid Derivatives: N-Acyloxazolinones as Ester Enolate Equivalents

(2011) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reply to T. W. Bentley: Limitations of the s(E+N) and Related Equations

(2011) Herbert Mayr   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Farewell to the HSAB Treatment of Ambident Reactivity

(2011) Herbert Mayr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Mechanistic Studies of the Lithium Enolate of 4-Fluoroacetophenone: Rapid-Injection NMR Study of Enolate Formation, Dynamics, and Aldol Reactivity

(2011) Kristopher J. Kolonko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure and Dynamics of α-Aryl Amide and Ketone Enolates: THF, PMDTA, TMTAN, HMPA, and Crypt-Solvated Lithium Enolates, and Comparison with Phosphazenium Analogues

(2010) Kristopher J. Kolonko et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Acylimidazoles as Ester Enolate Equivalents

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

(2010) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

(2010) Jan Streuff et al.   Nature Chemistry

Stereoselective palladium-catalyzed allylic alkylations of peptideamide enolates

(2010) Swarup Datta et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Intermolecular Michael Reactions: A Computational Investigation

(2010) Eugene E. Kwan et al.   ORGANIC LETTERS

Synthesis of macrocyclic precursors of lankacidins using Stille reactions of 4-(2-iodo-alkenyl)azetidinones and related compounds for ring closure

(2010) Christopher T. Brain et al.   TETRAHEDRON

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Perspectives on Computational Organic Chemistry

(2009) Andrew Streitwieser   JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation

(2009) Bai-Lin Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solution Structures of Lithium Enolates of Cyclopentanone, Cyclohexanone, Acetophenones, and Benzyl Ketones. Triple Ions and Higher Lithiate Complexes

(2009) Kristopher J. Kolonko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Synthesis of Highly Functionalized Cyclopentane Segments for the Preparation of Jatrophane Diterpenes†

(2009) Christoph Lentsch et al.   ORGANIC LETTERS

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)

(2008) Deyu Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates

(2008) Manfred Braun et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Palladium-Catalyzed Alkylation of Acyclic Amides

(2008) Kai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of solvent molecules on negative charge development on α-carbon of Li–enolate from acetaldehyde: A computational study

(2008) Arshad Khan   JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

A Computational Study of Lithium Ketone Enolate Aggregation in the Gas Phase and in THF Solution

(2008) Lawrence M. Pratt et al.   JOURNAL OF ORGANIC CHEMISTRY

Do general nucleophilicity scales exist?

(2008) Herbert Mayr et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Characterization of a Chiral Enolate Aggregate and Observation of6Li−1H Scalar Coupling

(2008) Deyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of Ketone and Aldehyde Enols by Formation of Hydrogen Bonds to Phosphazene Enolates and Their Aldol Products

(2008) Kristopher J. Kolonko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION