4.7 Article

Green synthesis g-C3N4 quantum dots loading h-BN for efficient and stable photocatalytic performance

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 268, Issue -, Pages 561-568

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2018.07.058

Keywords

g-C3N4 quantum dots; 2D h-BN; Red-shift; -OH groups; Metal-free materials

Funding

  1. National Science Foundation of China [U1510126, 21676115, 21676127, U1662125]
  2. Natural Science Foundation of Jiangsu Province [BK20171313, BK20150536]
  3. China Postdoctoral Science Foundation [2016M590418, 2015M571683, 2017M611732, 2017M611716]

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Many recent advances in constructing green metal-free materials have opened new possibilities in catalysis. To explore and enhance the photocatalytic performance of g-C3N4 quantum dots (CN QDs), the metal-free materials of CN QDs embedded in the h-BN was successfully synthesized by calcination the mixture of melamine and h-BN. The studies proved the CNBN has appeared red-shift due to the quantum size effect and 2D h-BN. The CN QDs were embedded into the h-BN could not only facilitate the separation and transfer, but also the h-BN terminated with -OH groups could act as active sites, thus enhanced the photocatalytic performance. Moreover, this work may pave the way for the application of CN QDs and fabricate 2D h-BN composites for green metal-free materials in another field. (C) 2018 Elsevier B.V. All rights reserved.

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