4.7 Article

Green synthesis g-C3N4 quantum dots loading h-BN for efficient and stable photocatalytic performance

期刊

JOURNAL OF MOLECULAR LIQUIDS
卷 268, 期 -, 页码 561-568

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2018.07.058

关键词

g-C3N4 quantum dots; 2D h-BN; Red-shift; -OH groups; Metal-free materials

资金

  1. National Science Foundation of China [U1510126, 21676115, 21676127, U1662125]
  2. Natural Science Foundation of Jiangsu Province [BK20171313, BK20150536]
  3. China Postdoctoral Science Foundation [2016M590418, 2015M571683, 2017M611732, 2017M611716]

向作者/读者索取更多资源

Many recent advances in constructing green metal-free materials have opened new possibilities in catalysis. To explore and enhance the photocatalytic performance of g-C3N4 quantum dots (CN QDs), the metal-free materials of CN QDs embedded in the h-BN was successfully synthesized by calcination the mixture of melamine and h-BN. The studies proved the CNBN has appeared red-shift due to the quantum size effect and 2D h-BN. The CN QDs were embedded into the h-BN could not only facilitate the separation and transfer, but also the h-BN terminated with -OH groups could act as active sites, thus enhanced the photocatalytic performance. Moreover, this work may pave the way for the application of CN QDs and fabricate 2D h-BN composites for green metal-free materials in another field. (C) 2018 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Ceramics

Facile fabrication and characterization of high-performance Borax-PVA hydrogel

Chen Wang, Zhifeng Shen, Pengfei Hu, Tao Wang, Xing Zhang, Lidong Liang, Jianguang Bai, Liewei Qiu, Xiaojuan Lai, Xiaowu Yang, Kang Zhang

Summary: Borax-PVA hydrogels with excellent mechanical properties were prepared by physically mixing PVA and borax, forming a three-dimensional structure with boric ester bonds. The hydrogels exhibited reversible gel-sol conversion and self-healing properties, with the best mechanical performance observed at a borax mass fraction of 5%.

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY (2022)

Article Engineering, Biomedical

Modulating cancer-stroma crosstalk by a nanoparticle-based photodynamic method to pave the way for subsequent therapies

Yan Liu, Xiaodi Wu, Feifan Chen, Hao Li, Tao Wang, Ningning Liu, Kang Sun, Guangdong Zhou, Ke Tao

Summary: In this study, we found that nanoparticle-based photodynamic therapy disrupted the tumor-stroma crosstalk in pancreatic tumor models, leading to persistent inhibition of extracellular matrix secretion and enhanced therapeutic effect. By down-regulating TGF beta signaling pathways, this therapy decreased drug resistance, proliferation, and migration of cancer cells. Furthermore, it inactivated pancreatic stellate cells and hindered ECM secretion. The disruption of tumor-stroma crosstalk also improved tumor penetration in stroma-rich pancreatic tumor models, enhancing subsequent therapy outcomes.

BIOMATERIALS (2022)

Article Materials Science, Multidisciplinary

Numerical Simulation and Industrial Experiment of the Fluid Flow and Heat Transfer in Large Vertical Round Billets with Helical Final Electromagnetic Stirring

Hongjian Wu, Changjun Xu, Chong Lei, Tao Wang, Yingli Gao, Xiaobing Zhang, Huiye Jin

Summary: The effect of helical electromagnetic stirring on the magnetic field, liquid steel flow, and heat transfer in vertical round billets has been studied by numerical simulation and industrial experiments. The results show that the electromagnetic force drives a rotating flow in the liquid steel, and the flow range and velocity are influenced by the current intensity and frequency.
Article Chemistry, Analytical

Selective and ratiometric fluorescence sensing of bisphenol A in canned food based on portable fluorescent test strips

Xiqing Liu, Tao Wang, Yongqing Wang

Summary: In this study, a conversion method and molecular imprinting technology were used to design MIP-based ratiometric fluorescence test papers. The ZnO QDs acted as the background quantum dots and ZIF-8 raw material, while CDs were used as the identification signals. The selective function of the imprinting layer enabled the design of a ZnO@ZIF-8/CDs@MIPs sensor for detecting BPA. The sensor exhibited a fast response time and effective detection in complex environments, with a detection limit of 0.778 nM and a linear range of 0-60 nM.

ANALYTICA CHIMICA ACTA (2023)

Article Materials Science, Multidisciplinary

In-situ metallic Bi deposited Bi12TiO20 with improved photocatalytic activity

Tao Wang, Xiqing Liu, Hongquan Zhan, Runhua Liao, Yongqing Wang

Summary: Boosting photocatalytic activity through surface plasmon resonance (SPR) effect was demonstrated as an effective approach. In this study, metallic Bi was deposited in situ on the surface of Bi12TiO20 (BTO). The morphology, light properties, crystal structure, and chemical composition of the Bi/BTO composite were analyzed. The Bi/BTO composite showed increased light absorption and smaller electron transfer resistance. The SPR effect of metallic Bi generated hot electrons to promote the production of more active species, and the formed Schottky junction promoted electron separation, resulting in higher photocatalytic activity. The possible photocatalytic mechanism was also proposed for further development of plasmonic photocatalysts.

OPTICAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Multi-Dimensional Molecular Self-Assembly Strategy for the Construction of Two-Dimensional Mesoporous Polydiaminopyridine and Carbon Materials

Liangliang Zhang, Yumeng Liu, Tao Wang, Zhilin Liu, Wei Li, Zhen-An Qiao

Summary: Two-dimensional mesoporous polymers, with the combination of organic polymers, porous materials, and 2D materials, have attracted great attention due to their potential applications in adsorption, catalysis, and energy storage. In this study, a facile multi-dimensional molecular self-assembly strategy was developed for the synthesis of 2D mesoporous polydiaminopyridines (MPDAPs) with tunable pore sizes and high N content. The resulting 2D MPDAPs exhibited excellent catalytic performance and could be transformed into N-doped mesoporous carbon with high CO2 uptake density.
Article Chemistry, Multidisciplinary

Construction of Nitrogen-abundant Graphyne Scaffolds via Mechanochemistry-Promoted Cross-Linking of Aromatic Nitriles with Carbide Toward Enhanced Energy Storage

Juntian Fan, Tao Wang, Bishnu P. P. Thapaliya, Meijia Li, Chi-Linh Do-Thanh, Takeshi Kobayashi, Ilja Popovs, Zhenzhen Yang, Sheng Dai

Summary: Researchers have successfully synthesized nitrogen-doped graphyne materials through a mechanochemistry-driven pathway using electron-deficient aromatic nitriles and CaC2 as precursors. The obtained materials exhibit abundant nitrogen content, tunable surface areas, and hierarchical porosity, making them promising for energy storage applications. These materials also demonstrate high capacitance, attractive rate performance, and good long-term stability in supercapacitor-related applications.
Article Instruments & Instrumentation

Damage identification of thin plate-like structures combining improved singular spectrum analysis and multiscale cross-sample entropy (ISSA-MCSEn)

Jiacheng Wang, Guangtao Lu, Huijun Song, Tao Wang, Dan Yang

Summary: In this paper, a new method called ISSA-MCSEn is developed to identify the size of early damages in thin plate-like structures. The algorithm combines improved singular spectrum analysis (ISSA) and multiscale cross-sample entropy (MCSEn) to successfully extract the principal components relevant to the damage and reconstruct the components for damage size detection. Experimental results show that the proposed ISSA-MCSEn algorithm has better performance than the SSA-FuzzyEn algorithm in detecting small-size damages. The relationship between the normalized MCSEn and the damages' size is linear and can be used for damage size detection.

SMART MATERIALS AND STRUCTURES (2023)

Article Spectroscopy

Constructing hollow ZIF-8/CDs@MIPs fluorescent sensor from Osmanthus leaves to specifically recognize bovine hemoglobin

Xiqing Liu, Le Tian, Runping Ren, Tao Wang, Yongqing Wang

Summary: Developing non-toxic, highly efficient, and selective fluorescence sensors is of great importance. In this study, a novel hollow fluorescence sensor was created using biomass carbon dots (CDs), ZIF-8, and molecularly imprinted polymers (MIPs) through aqueous polymerization. The sensor exhibited fast response time, excellent stability, and high selectivity towards bovine hemoglobin (BHb). Even in complex environments, the hollow fluorescence sensor (H-ZIF-8/CDs@MIPs) demonstrated effective recognition of BHb. This work presents a green and unique approach for practical applications of fluorescence sensors.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2023)

Article Materials Science, Multidisciplinary

Experimental study on fire performance of optical cables used in utility tunnel: Influence of cable spacing and heat flux

Weiguang An, Xiaoxiao Sun, Yanhua Tang, Tao Wang, Zhe Wang

Summary: This study conducted cone calorimeter experiments on optical cables widely used in utility tunnels in China to investigate the coupling effect of spacing and heat flux on the fire performance of optical cables. The results showed that the optical cables conformed to the ignition time model of thermally thin material. Increasing the heat flux decreased the ignition time of the cables. The difference in ignition time between cables with different spacing was significant at a heat flux of 30 kW/m(2), but became small when the heat flux was higher. Additionally, both the average mass loss rate and heat release rate of the cables increased with increasing heat flux and spacing. The heat release rate versus time curves exhibited two peaks, with the second peak being significantly smaller.

FIRE AND MATERIALS (2023)

Article Chemistry, Physical

A one-pot synthesis of high-density biofuels through bifunctional mesoporous zeolite-encapsulated Pd catalysts

Qiang Deng, Honggen Peng, Zhenzhen Yang, Tao Wang, Jun Wang, Zheling Zeng, Sheng Dai

Summary: Developing a powerful bifunctional catalyst is crucial for achieving future carbon neutrality by reducing energy consumption in the chemical industry. This study synthesizes mesoporous zeolite-encapsulated palladium nanoparticles (Pd@meso-ZSM-5) using emulsification-demulsification and dry-gel transformation methods, which exhibit remarkable catalytic performance in the one-pot multiple tandem reaction of cyclic ketones to bicyclic alkanes. Unlike traditional two-step synthesis routes, Pd@meso-ZSM-5 efficiently produces bicyclic alkanes instead of monocyclic alkanes, due to the sufficient space for large molecular intermediates provided by mesoporosity and the promoting effect of the acid-Pd interface on intermediate conversion.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Article Multidisciplinary Sciences

Machine-learning-assisted material discovery of oxygen-rich highly porous carbon active materials for aqueous supercapacitors

Tao Wang, Runtong Pan, Murillo L. Martins, Jinlei Cui, Zhennan Huang, Bishnu P. Thapaliya, Chi-Linh Do-Thanh, Musen Zhou, Juntian Fan, Zhenzhen Yang, Miaofang Chi, Takeshi Kobayashi, Jianzhong Wu, Eugene Mamontov, Sheng Dai

Summary: Machine-learning technology is used to find the critical features for ideal carbon-based supercapacitors by analyzing previous research works. In this study, a machine-learning-derived activation strategy is designed to synthesize highly porous carbons with specific surface areas > 4000 m(2)/g using sodium amide and cross-linked polymer precursors. The resulting highly porous carbon-based electrode exhibits a high specific capacitance and approaches the predicted specific capacitance by the machine learning approach.

NATURE COMMUNICATIONS (2023)

Article Chemistry, Multidisciplinary

Facile Synthesis of Ultrafine and Highly Dispersible MnO2 Nanoparticles for Energy Storage in Supercapacitors

Zichuan Liu, Linghui Peng, Lingling Shen, Hongbo Qiu, Weiren Fan, Tao Wang, Bocheng Zhu, Xuchuan Jiang

Summary: This study presents the synthesis of ultrafine MnO2 nanoparticles with excellent dispersibility in water through a simple one-step hydrothermal route. The nanoparticles have a uniform size of 200 nm, a large specific surface area, and a high specific capacitance.

CHEMNANOMAT (2023)

Article Materials Science, Multidisciplinary

Origin of the Coulomb pseudopotential

Tao Wang, Xiansheng Cai, Kun Chen, Boris Svistunov, Nikolay Prokof'ev

Summary: We address the issue of electron pairing in the presence of strong Coulomb repulsion at rs <= 2 and demonstrate the limitations of the pseudopotential framework. Instead, we propose separating the effects of Fermi liquid renormalization and the change in effective low-energy coupling. Our findings indicate a nonmonotonic behavior of the latter quantity with an extremum at rs ti 0.75. The Coulomb interaction enhances the pairing coupling at rs > 2, while the suppression of critical temperature is solely due to renormalized Fermi liquid properties. Leading vertex corrections have only a quantitative impact. Our results challenge the widely accepted repulsive pseudopotential approach and highlight the importance of precise microscopic treatment of Coulomb interactions in the study of superconducting instability.

PHYSICAL REVIEW B (2023)

Article Chemistry, Multidisciplinary

Controlling the elasticity of polyacrylonitrile fibers via ionic liquids containing cyano-based anions

Zongyu Wang, Huimin Luo, Halie J. Martin, Tao Wang, Yifan Sun, Mark A. Arnould, Bishnu P. Thapaliya, Sheng Dai

Summary: The fabrication of polyacrylonitrile (PAN)-based composite fibers plays a crucial role in high-performance carbon fiber manufacturing. Ionic liquids (ILs) have been explored for their plasticizing properties, and their impact on the elasticity and stretchability of PAN/ILs fibers can be controlled by tuning the anion structure of ILs.

RSC ADVANCES (2022)

Article Chemistry, Physical

Dimer-parity dependent odd-even effects in photoinduced transitions to cholesteric and twist grain boundary SmC* mesophases: PBG characteristics

Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad

Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Understanding the CO2 capture potential of tetrapropylammonium-based multifunctional deep eutectic solvent via molecular simulation

Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio

Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Theoretical study of the Cu2+-glycine interaction in ammonia and effects

Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie

Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Morphology study of light- and pH-responsive amphiphiles with DSA for detection of nitrobenzene derivatives

Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin

Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Effect of SBS structure on viscosity of SBS-modified asphalt based on molecular dynamics: Insights from shearing phase morphology, adsorption and swelling mechanisms

Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei

Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Vaporization enthalpy of azeotropes by the solution calorimetry method

Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov

Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Deep machine learning, molecular dynamics and experimental studies of liquid Al-Cu-Co alloys

L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev

Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Surface adsorption of adenine on pristine and B/N/O/P-doped coronene as a biosensing substrate for DNA detection- DFT study

R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena

Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Study on the fine particles deposition law in the bronchus of miners affected by dust pollution in the anchor excavation working environment

Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang

Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Unveiling regularities of B12N12-X nanocages as a drug delivery vehicle for the nitrosourea: The influence of periods and groups

Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu

Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Aromatic aldehyde oxidation by hexacyanoferrate(III) catalyzed by Ru(VI) in alkaline medium

C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete

Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Effective removal of hypnotic drug from the aqueous medium through adsorption on graphene oxide magnetic derivatives

Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden

Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

A sensitivity analysis on thermal conductivity of Al2O3-H2O nanofluid: A case based on molecular dynamics and support vector regression method

Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang

Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.

JOURNAL OF MOLECULAR LIQUIDS (2024)

Correction Chemistry, Physical

Canonical partition function and distance dependent correlation functions of a quasi-one-dimensional system of hard disks (vol 387,122572, 2023)

V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk

JOURNAL OF MOLECULAR LIQUIDS (2024)

Article Chemistry, Physical

Modifying optical nonlinearities of ionic liquid crystal glass by adding gold and carbon nanoparticles

Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy

Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.

JOURNAL OF MOLECULAR LIQUIDS (2024)