4.7 Article

A study on adsorption of Cr (VI) by modified rice straw: Characteristics, performances and mechanism

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 196, Issue -, Pages 626-634

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2018.05.279

Keywords

Rice straw; Graft modification; PVA; Adsorption; Cr (VI)

Funding

  1. National-Level Innovation Training Program of Undergraduate [201510491026]
  2. Chinese Postdoctoral Science Foundation [2017M611533]
  3. Funds for Study on Preparation and Performance of Biomass Macromolecular Composites [2017036019]

Ask authors/readers for more resources

In this study, aminated rice straw-grafted-poly (vinyl alcohol) (A-RS/PVA) was first used to remove Cr (VI) from aqueous solution. The A-RS/PVA was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), element analysis and zeta potential measurement. Batch adsorption experiments showed that the Elovich model and the Freundlich isotherm model fitted the adsorption data very well, and the Cr (VI) adsorption capacity of A-RS/PVA was up to 140.39 mg g(-1) at initial pH 2.0 and 60 degrees C, much larger that of original rice straw (34.90 mg g(-1)). The thermodynamic parameters such as free energy change Delta G, enthalpy change Delta H and entropy change Delta S were evaluated and it has been found that the reaction was spontaneous and endothermic in nature. The effects of initial pH, coexisting anions and reusability were also investigated. Moreover, X-ray photoelectron spectroscopy (XPS) analysis revealed that about 57.4% of the chromium adsorbed on A-RS/PVA had turned into less toxic trivalent chromium. The possible adsorption mechanism was proposed based on the experimental data and analysis results finally. (C) 2018 Elsevier Ltd. All rights reserved.

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