Mechanistic Considerations on Homogeneously Catalyzed Formic Acid Dehydrogenation

Iridium and Ruthenium Complexes of N-Heterocyclic Carbene- and Pyridinol-Derived Chelates as Catalysts for Aqueous Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation: The Role of the Alkali Metal

(2017) Sopheavy Siek et al.   ORGANOMETALLICS

A Bifunctional Iridium Catalyst Modified for Persistent Hydrogen Generation from Formic Acid: Understanding Deactivation via Cyclometalation of a 1,2-Diphenylethylenediamine Motif

(2017) Asuka Matsunami et al.   ACS Catalysis

Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study

(2017) Shirel Cohen et al.   ACS Catalysis

Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand

(2016) Yupeng Pan et al.   Chemistry-An Asian Journal

Iodide-Promoted Dehydrogenation of Formic Acid on a Rhodium Complex

(2016) Zhijun Wang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Dehydrogenation of Formic Acid Catalyzed by a Ruthenium Complex with an N,N′-Diimine Ligand

(2016) Chao Guan et al.   INORGANIC CHEMISTRY

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

(2016) Irene Mellone et al.   ORGANOMETALLICS

A prolific catalyst for dehydrogenation of neat formic acid

(2016) Jeff Joseph A. Celaje et al.   Nature Communications

DFT Study on the Mechanism of Formic Acid Decomposition by a Well-Defined Bifunctional Cyclometalated Iridium(III) Catalyst: Self-Assisted Concerted Dehydrogenation via Long-Range Intermolecular Hydrogen Migration

(2016) Jingjing Li et al.   ACS Catalysis

Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands

(2016) Federica Bertini et al.   ACS Catalysis

Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species

(2016) S. Oldenhof et al.   Catalysis Science & Technology

Reversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation

(2016) L. S. Jongbloed et al.   Catalysis Science & Technology

Hydrogen carriers

(2016) Teng He et al.   Nature Reviews Materials

A Viable Hydrogen Storage and Release System Based on Cesium Formate and Bicarbonate Salts: Mechanistic Insights into the Hydrogen Release Step

(2015) Katerina Sordakis et al.   ChemCatChem

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

(2015) Wan-Hui Wang et al.   CHEMICAL REVIEWS

Enhanced Hydrogen Generation from Formic Acid by Half-Sandwich Iridium(III) Complexes with Metal/NH Bifunctionality: A Pronounced Switch from Transfer Hydrogenation

(2015) Asuka Matsunami et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

(2015) Sander Oldenhof et al.   Chemical Science

A Rechargeable Hydrogen Battery Based on Ru Catalysis

(2014) Shih-Fan Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight

(2014) Wan-Hui Wang et al.   ChemSusChem

Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

(2014) Elizabeth A. Bielinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes

(2014) Yuki Suna et al.   ORGANOMETALLICS

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

CO2Activation and Catalysis Driven by Iridium Complexes

(2013) Francisco J. Fernández-Alvarez et al.   ChemCatChem

Efficient Hydrogen Liberation from Formic Acid Catalyzed by a Well-Defined Iron Pincer Complex under Mild Conditions

(2013) Thomas Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Base-Free Production of H2by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex

(2013) Sander Oldenhof et al.   CHEMISTRY-A EUROPEAN JOURNAL

One Site Is Enough: A Theoretical Investigation of Iron-Catalyzed Dehydrogenation of Formic Acid

(2013) Rocío Sánchez-de-Armas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic insights into iron catalyzed dehydrogenation of formic acid: β-hydride elimination vs. direct hydride transfer

(2013) Xinzheng Yang   DALTON TRANSACTIONS

Inner- versus Outer-Sphere Ru-Catalyzed Formic Acid Dehydrogenation: A Computational Study

(2013) Gabriele Manca et al.   ORGANOMETALLICS

Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP3

(2012) Irene Mellone et al.   DALTON TRANSACTIONS

Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure

(2012) Yuta Maenaka et al.   Energy & Environmental Science

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid

(2012) Jonathan H. Barnard et al.   Chemical Science

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

(2011) Mirza Cokoja et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex

(2011) Ryo Tanaka et al.   ORGANOMETALLICS

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

(2011) A. Boddien et al.   SCIENCE

ortho-Metalation of Iron(0) Tribenzylphosphine Complexes: Homogeneous Catalysts for the Generation of Hydrogen from Formic Acid

(2010) Albert Boddien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water

(2010) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Hydrogen Production from Formic Acid

(2010) Albert Boddien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

(2010) Björn Loges et al.   TOPICS IN CATALYSIS

Hydrogen generation from formic acid and alcohols using homogeneous catalysts

(2009) Tarn C. Johnson et al.   CHEMICAL SOCIETY REVIEWS

Selective Formic Acid Decomposition for High-Pressure Hydrogen Generation: A Mechanistic Study

(2009) Céline Fellay et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine

(2009) Yuichiro Himeda   GREEN CHEMISTRY

Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes

(2009) David J. Morris et al.   ORGANOMETALLICS

Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H2/O2Fuel Cells

(2008) Björn Loges et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst

(2008) Céline Fellay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Generation at Ambient Conditions: Application in Fuel Cells

(2008) Albert Boddien et al.   ChemSusChem

Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2and H/D Exchange with a Water-Soluble Rhodium Complex in Aqueous Solution

(2008) Shunichi Fukuzumi et al.   ChemSusChem

Breakthroughs in Hydrogen Storage-Formic Acid as a Sustainable Storage Material for Hydrogen

(2008) Ferenc Joó   ChemSusChem