4.8 Article

Permeability- and Surface-Energy-Tunable Polyurethane Acrylate Molds for Capillary Force Lithography

Journal

ACS Applied Materials & Interfaces
Volume 7, Issue 43, Pages 23824-23830

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b06975

Keywords

capillary force lithography; degree of cross-linking; permeability; surface energy; micro/nanostructure

Funding

  1. Institute of Basic Science [IBS-R015-D1, NRF-2013- 430 R1A1A1061403]
  2. Basic Science Research Program [2009-0083540]
  3. Pioneer Research Center Program through the National Research Foundation of Korea - Ministry of Science, ICT, & Future Planning [NRF-2014M3C1A3001208]

Ask authors/readers for more resources

A permeability- and surface-energy-controllable polyurethane acrylate (PUA) mold, a capillary-force material (CFM) mold, is introduced for capillary-force lithography (CFL). In CFL, the surface energy and gas permeability of the mold are crucial. However, the modulation of these two main factors at a time is difficult. Here, we introduce new CFM molds in which the surface energy and permeability can be modified by controlling the degree of cross-linking of the CFM. As the degree of cross-linking of the CFM mold increases, the surface energy and air permeability decrease. The high average functionality of the mold material makes it possible to produce patterns relatively finely and rapidly due to the high fate of capillary rise and stiffness, and the low functionality allows for patterns to form on a curved surface with conformal contact. CFMs with different functionality and controllable-interfacial properties will extend the capabilities of capillary force lithography to overcome the geometric limitations of patterning on a scale below 100 nm and micro- and nanopatterning on the curved region.

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