Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes

Recent advances in the synthesis, structural diversity, and applications of mesoionic 1,2,3-triazol-5-ylidene metal complexes

(2018) Kostiantyn O. Marichev et al.   TETRAHEDRON

Gauging Donor/Acceptor Properties and Redox Stability of Chelating Click-Derived Triazoles and Triazolylidenes: A Case Study with Rhenium(I) Complexes

(2017) Lisa Suntrup et al.   INORGANIC CHEMISTRY

The Power of Ferrocene, Mesoionic Carbenes, and Gold: Redox-Switchable Catalysis

(2017) Sinja Klenk et al.   ORGANOMETALLICS

Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

(2017) David Schweinfurth et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Iridium-catalysed regioselective borylation of carboranes via direct B–H activation

(2017) Ruofei Cheng et al.   Nature Communications

Transition metal-induced B–H functionalization of o-carborane

(2017) Xiaolei Zhang et al.   COORDINATION CHEMISTRY REVIEWS

Rhodium-Catalyzed Regioselective Hydroxylation of Cage B−H Bonds ofo-Carboranes with O2or Air

(2016) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis

(2016) Marta Valencia et al.   CHEMICAL COMMUNICATIONS

Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

(2016) Rosario Núñez et al.   CHEMICAL REVIEWS

Selective B(4)−H Activation of ano-Carboranylthioamide Based on a Palladium Precursor

(2016) Yin-Ping Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines

(2016) Hairong Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity

(2016) María Frutos et al.   ORGANIC LETTERS

Bonding and Catalytic Application of Ruthenium N-Heterocyclic Carbene Complexes Featuring Triazole, Triazolylidene, and Imidazolylidene Ligands

(2016) Manuela Hollering et al.   ORGANOMETALLICS

Palladium catalyzed regioselective B–C(sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes

(2016) Yangjian Quan et al.   Chemical Science

Palladium-Catalyzed Regioselective Diarylation of o -Carboranes By Direct Cage B−H Activation

(2015) Yangjian Quan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

(2015) Lara Hettmanczyk et al.   CHEMICAL COMMUNICATIONS

Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

(2015) Bin Xu et al.   DALTON TRANSACTIONS

Steroid Derived Mesoionic Gold and Silver Mono- and Polymetallic Carbenes

(2015) María Frutos et al.   INORGANIC CHEMISTRY

Recent advances in transition metal-mediated functionalization of o-carboranes

(2015) Zaozao Qiu   TETRAHEDRON LETTERS

Beyond click chemistry – supramolecular interactions of 1,2,3-triazoles

(2014) Benjamin Schulze et al.   CHEMICAL SOCIETY REVIEWS

On the Use of Metal Purine Derivatives (M=Ir, Rh) for the Selective Labeling of Nucleosides and Nucleotides

(2014) Marta Valencia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboranes Tuning the Phosphorescence of Iridium Tetrazolate Complexes

(2014) Chao Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium Complexes Containing Mesoionic C Donors: Selective C(sp3)H versus C(sp2)H Bond Activation, Reactivity Towards Acids and Bases, and Catalytic Oxidation of Silanes and Water

(2014) Ana Petronilho et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand Exchange and Redox Processes in Iridium Triazolylidene Complexes Relevant to Catalytic Water Oxidation

(2014) Ana Petronilho et al.   INORGANIC CHEMISTRY

Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B–H Activation

(2014) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Mediated Regioselective B–H/C–H Activation of Carborane Cage: A Facile Synthetic Route to Metallacycles with a Carborane Backbone

(2014) Zi-Jian Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methods to produce B–C, B–P, B–N and B–S bonds in boron clusters

(2013) David Olid et al.   CHEMICAL SOCIETY REVIEWS

Transition metal complexes based on carboranyl ligands containing N, P, and S donors: Synthesis, reactivity and applications

(2013) Zi-Jian Yao et al.   COORDINATION CHEMISTRY REVIEWS

Novel inorganic heterocycles from dimetalated carboranylamidinates

(2013) Nicole Harmgarth et al.   DALTON TRANSACTIONS

Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

(2012) Kate F. Donnelly et al.   CHEMICAL COMMUNICATIONS

Triazoles from N-Alkynylheterocycles and Their Coordination to Iridium

(2012) Glenn A. Burley et al.   ORGANOMETALLICS

Regioselective Electrophilic C–H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent

(2012) Kate F. Donnelly et al.   ORGANOMETALLICS

Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes

(2012) Alexander M. Spokoyny et al.   ORGANOMETALLICS

New Rhodium(I) and Iridium(I) Complexes Containing Mixed Pyrazolyl–1,2,3-Triazolyl Ligands As Catalysts for Hydroamination

(2012) Carol Hua et al.   ORGANOMETALLICS

Organometallic Iridium Catalysts Based on Pyridinecarboxylate Ligands for the Oxidative Splitting of Water

(2012) Alberto Bucci et al.   ORGANOMETALLICS

Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

(2011) Matthias Scholz et al.   CHEMICAL REVIEWS

Versatile Reactivity of Half-Sandwich Ir and Rh Complexes toward Carboranylamidinates and Their Derivatives: Synthesis, Structure, and Catalytic Activity for Norbornene Polymerization

(2011) Zi-Jian Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

The two faces of carboranes

(2011) Andrew Weller   Nature Chemistry

A coordination chemistry dichotomy for icosahedral carborane-based ligands

(2011) Alexander M. Spokoyny et al.   Nature Chemistry

An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst

(2011) Timothy P. Brewster et al.   ORGANOMETALLICS

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY