Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 16, Pages 3344-3347Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00267f
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Funding
- European Commission [615653, 660929]
- European Research Council (ERC) [615653] Funding Source: European Research Council (ERC)
- Marie Curie Actions (MSCA) [660929] Funding Source: Marie Curie Actions (MSCA)
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A bimetallic [Ir3+](2) complex was synthesized based on a bridging 1,2,3-triazole ligand that coordinates to one Cp*Ir unit as N,N-bidentate chelate, and to the other as a C, C-bidentate ligand. When compared to monometallic homologues, the bimetallic complex shows greatly enhanced product selectivity for the acceptorless dehydrogenation of alcohols; spectroscopic and electrochemical analysis suggest significant alteration of the metal properties in the bimetallic system compared to the monometallic species, which offers a rationale for the observed high selectivity.
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