Journal
CRYSTAL GROWTH & DESIGN
Volume 18, Issue 4, Pages 1940-1943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.8b00019
Keywords
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Funding
- National Natural Science Foundation of China [11572295, 11704349, 11372290]
- Presidential Foundation of CAEP [201501018]
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Three new energetic 2,2',4,4',6,6'-hexanitrostil-bene (HNS) cocrystals, HNS/4,4'-bipyridine, HNS/trans-1,2-bis(4-pyridyl)ethylene, and HNS/1,2-bis (4-pyridyl) ethane have been synthesized. A good geometric match and rich H-bonds have been observed between the selected coformer and HNS molecules in all three cocrystals. According to similar configuration and arrangement of HNS coformer H-bonds, coformer coformer pi-stacking, and HNS-HNS H-bonding interactions, the three cocrystals have a common cocrystal architecture and show high thermal stability and improved sensitivity. This study is helpful for understanding the formation mechanism of energetic cocrystals and the design of new energetic cocrystals.
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