Journal
CRYSTAL GROWTH & DESIGN
Volume 18, Issue 2, Pages 1215-1226Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b01769
Keywords
-
Funding
- Swiss National Science Foundation [200020_152777]
- University of Fribourg
- Frimat
Ask authors/readers for more resources
Compartmentalization of metal ions is crucial in biology as well as in materials science. For the synthesis of single source precursors, the preorganization of different metal ions is of particular interest for the low temperature generation of mixed metal oxides. On the basis of a potentially Omega-shaped salen-type ligand providing an N2O2 as well as an O2O2 coordination site, mixed metal coordination compounds with Cu(II) or Ni(II) and alkali metal ions have been studied for their Structural and optical properties. UV-vis and H-1 NMR titrations show that the obtained compounds adopt partially different structures in solution compared to the solid state. In the latter case, the coordination geometry is mainly governed by the size of the alkali metal ion as well as the transition metal ion used.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available