Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 36, Issue 4, Pages 353-362Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700746
Keywords
carbon dioxide; C1 source; carbonylation; homogeneous catalysis
Categories
Funding
- National Natural Science Foundation of China [91745110, 21673261, 21603245, 21633013, 21703265]
- LICP
- CAST
- CAS Interdisciplinary Innovation Team
- Key Research Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH051]
- 'Light of West China' Program
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Carbon dioxide is a sufficient and important carbon resource, which has been widely used as a C1 building block in synthetic chemistry. Carbonylations with CO are important processes in industry. However, due to the toxicity of CO, its storage and transport are problematic. Attentions are gradually focused on using other safe reagents to be the CO surrogates in carbonylation reactions. This review focuses on the summary of recent developments in using CO2 as a CO surrogate in homogeneous catalysis. Reductive processes by using H-2, Si-H, alcohols, etc and redox-neutral processes are separately summarized.
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