Catalytic Hydrodefluorination of C−F Bonds by an Air-Stable PIII Lewis Acid

E–H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations

(2017) Nemanja Đorđević et al.   INORGANIC CHEMISTRY

Phosphorus Lewis acids: emerging reactivity and applications in catalysis

(2016) J. M. Bayne et al.   CHEMICAL SOCIETY REVIEWS

Pyridinium–phosphonium dications: highly electrophilic phosphorus-based Lewis acid catalysts

(2016) Julia M. Bayne et al.   DALTON TRANSACTIONS

A very peculiar family of N-heterocyclic phosphines: unusual structures and the unique reactivity of 1,3,2-diazaphospholenes

(2016) D. Gudat   DALTON TRANSACTIONS

Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination

(2015) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–F Bond Activation by Transient Phosphenium Dications

(2015) Nemanja Đorđević et al.   INORGANIC CHEMISTRY

Review of recent advances in CF bond activation of aliphatic fluorides

(2015) Qian Shen et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines

(2015) Michael H. Holthausen et al.   Chemical Science

Bipyridine complexes of E3+ (E = P, As, Sb, Bi): strong Lewis acids, sources of E(OTf)3 and synthons for EI and EV cations

(2015) Saurabh S. Chitnis et al.   Chemical Science

Metal-Free σ-Bond Metathesis in 1,3,2-Diazaphospholene-Catalyzed Hydroboration of Carbonyl Compounds

(2014) Che Chang Chong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Reversible Intermolecular E–H Oxidative Addition to a Geometrically Deformed and Structurally Dynamic Phosphorous Triamide

(2014) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Sb(C6F5)4][B(C6F5)4]: An Air Stable, Lewis Acidic Stibonium Salt That Activates Strong Element-Fluorine Bonds

(2014) Baofei Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrodefluorination with Late Transition Metal Complexes

(2014) Michael K. Whittlesey et al.   ACS Catalysis

Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species

(2013) Mike Ahrens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs

(2013) Yi Chiao Fan et al.   CHEMICAL COMMUNICATIONS

Lewis acidity of boron compounds

(2013) Igor B. Sivaev et al.   COORDINATION CHEMISTRY REVIEWS

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How Lewis acidic is your cation? Putting phosphenium ions on the fluoride ion affinity scale

(2011) John M. Slattery et al.   DALTON TRANSACTIONS

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Diphosphines with Strongly Polarized P−P Bonds: Hybrids between Covalent Molecules and Donor−Acceptor Adducts with Flexible Molecular Structures

(2009) Sebastian Burck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis

(2009) Weixing Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE