Access to 3-Oxindoles from Allylic Alcohols and Indoles

Tsuji-Trost Reaction of Non-Derivatized Allylic Alcohols

(2018) Sunisa Akkarasamiyo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphoric Acid Catalyzed 1,2-Rearrangements of 3-Hydroxyindolenines to Indoxyls and 2-Oxindoles: Reagent-Controlled Regioselectivity Enabled by Dual Activation

(2017) Eva Schendera et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Modular Construction of Protected 1,2/1,3-Diols, -Amino Alcohols, and -Diamines via Catalytic Asymmetric Dehydrative Allylation: An Application to Synthesis of Sphingosine

(2017) Shinji Tanaka et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis

(2017) Faben A. Cruz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Palladium-Catalyzed Carbonylative Transformation of Allylic Alcohols and Related Derivatives

(2017) Fu-Peng Wu et al.   ORGANIC LETTERS

Planar-Chiral Cyclopentadienyl-Ruthenium-Catalyzed Regio- and Enantioselective Asymmetric Allylic Alkylation of Silyl Enolates under Unusually Mild Conditions

(2016) Naoya Kanbayashi et al.   ADVANCED SYNTHESIS & CATALYSIS

The Cs2CO3–Catalyzed Reaction of 2-Oxindoles with Enones for the Preparation of Indolin-3-Ones and Their Further Transformation

(2016) Ying Shao et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of Racemic and Branched Monosubstituted Allylic Acetates by a Ruthenium-Catalyzed Regioselective Allylic Etherification

(2016) Toru Shinozawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in Direct Catalytic Dehydrative Substitution of Alcohols

(2016) Joseph Moran et al.   SYNTHESIS-STUTTGART

A general and efficient method for the palladium-catalysed conversion of allylic alcohols into their corresponding dienes

(2016) Karoline A. Ostrowski et al.   Catalysis Science & Technology

Silica nanoparticle-generated ROS as a predictor of cellular toxicity: mechanistic insights and safety by design

(2016) Sean E. Lehman et al.   Environmental Science-Nano

Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst

(2015) Yusuke Kita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Carbazole Alkaloids by Ring-Closing Metathesis and Ring Rearrangement-Aromatization

(2015) Kalyan Dhara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Internal Oxidant-Triggered Aerobic Oxygenation and Cyclization of Indoles under Copper Catalysis

(2015) Huawen Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and α,β-unsaturated ketones

(2015) Xiao Liang et al.   CHEMICAL COMMUNICATIONS

Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex

(2015) Naoya Kanbayashi et al.   CHEMICAL COMMUNICATIONS

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

(2015) Nicholas A. Butt et al.   CHEMICAL SOCIETY REVIEWS

Pentacoordinated Carboxylate π-Allyl Nickel Complexes as Key Intermediates for the Ni-Catalyzed Direct Amination of Allylic Alcohols

(2015) Yusuke Kita et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tripping up Trp: Modification of protein tryptophan residues by reactive oxygen species, modes of detection, and biological consequences

(2015) Marilyn Ehrenshaft et al.   FREE RADICAL BIOLOGY AND MEDICINE

Intramolecular Tsuji–Trost-type Allylation of Carboxylic Acids: Asymmetric Synthesis of Highly π-Allyl Donative Lactones

(2015) Yusuke Suzuki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-Catalyzed Redox-Neutral Cleavage of the N–O Bond in Isoxazolidines: Isatogens to Pseudoindoxyls via a One-Pot [3 + 2]-Cycloaddition/N–O Cleavage

(2015) Chepuri V. Suneel Kumar et al.   ORGANIC LETTERS

Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines

(2015) Kun Xu et al.   Nature Communications

Ruthenium-Catalyzed Intramolecular Allylic Dearomatization/Migration Reaction of Indoles and Pyrroles

(2014) Ze-Peng Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Tandem Organocatalysis and Photocatalysis: An Anthraquinone-Catalyzed Indole-C3-Alkylation/Photooxidation/1,2-Shift Sequence

(2014) Stephanie Lerch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

(2014) Xiaohong Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel highly emissive H-aggregates with aggregate fluorescence change in a phenylbenzoxazole-based system

(2014) Lianke Wang et al.   CHEMICAL COMMUNICATIONS

[(p-Cymene)RuCl2]2: An Efficient Catalyst for Highly Regioselective Allylic Alkylations of Chelated Amino Acid Ester Enolates

(2014) Anton Bayer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen-Bond-Assisted Activation of Allylic Alcohols for Palladium-Catalyzed Coupling Reactions

(2014) Yasemin Gumrukcu et al.   ChemSusChem

Selective Peptide Modifications via Ruthenium-Catalyzed Allylic Alkylations

(2014) Anton Bayer et al.   JOURNAL OF ORGANIC CHEMISTRY

Ir-Catalyzed Reverse Prenylation of 3-Substituted Indoles: Total Synthesis of (+)-Aszonalenin and (−)-Brevicompanine B

(2014) Jonathan Ruchti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Michael–Michael Cascade for the Construction of Highly Functionalized N-Fused Piperidinoindoline Derivatives

(2014) Yong-Long Zhao et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regio- and Enantioselective Allylic Amination of Racemic 1-Arylallyl Esters

(2014) Motoi Kawatsura et al.   ORGANIC LETTERS

Semisynthetic Artemisinin, the Chemical Path to Industrial Production

(2014) Joël Turconi et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Photocatalytic aerobic oxidation/semipinacol rearrangement sequence: a concise route to the core of pseudoindoxyl alkaloids

(2014) Wei Ding et al.   TETRAHEDRON LETTERS

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

(2013) Yogesh Goriya et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed Asymmetric Allylic Alkylation of Pyrazol-5-ones with Allylic Alcohols: The Role of the Chiral Phosphoric Acid in C–O Bond Cleavage and Stereocontrol

(2013) Zhong-Lin Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Sulfoxide-Ligated Ruthenium Complex for Asymmetric Catalysis: Enantio- and Regioselective Allylic Substitution

(2013) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of LipidGreen2 and its application in lipid and fatty liver imaging

(2013) Hang-Suk Chun et al.   Molecular BioSystems

Ruthenium-Catalyzed Intramolecular Allylic Dearomatization Reaction of Indole Derivatives

(2013) Xiao Zhang et al.   ORGANIC LETTERS

Ir-catalyzed intermolecular asymmetric allylic dearomatization reaction of indoles

(2013) Xiao Zhang et al.   Chemical Science

Efficient and Convenient Palladium-Catalyzed Amination of Allylic Alcohols with N-Heterocycles

(2012) Debasis Banerjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium-Catalyzed Enantioconvergent Transformations

(2012) Markus Roggen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct, Enantioselective Iridium-Catalyzed Allylic Amination of Racemic Allylic Alcohols

(2012) Marc Lafrance et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular synthesis of optically active lactones by Ru-catalyzed asymmetric allylic carboxylation and ring-closing metathesis reaction

(2012) Koichiro Takii et al.   CHEMICAL COMMUNICATIONS

Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

(2012) Alejandro Parra et al.   CHEMICAL COMMUNICATIONS

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species

(2012) Basker Sundararaju et al.   CHEMICAL SOCIETY REVIEWS

A Labeled Substrate Approach to Discovery of Biocatalytic Reactions: A Proof of Concept Transformation with N-Methylindole

(2012) Jamie L. Rogers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Diels–Alder Reaction of 2-Methyl-3-indolylmethanols via in Situ Generation of o-Quinodimethanes

(2012) You-Cai Xiao et al.   ORGANIC LETTERS

Asymmetric Dehydrative C-, N-, and O-Allylation Using Naph-diPIM-dioxo-i-Pr-CpRu/p-TsOH Combined Catalyst

(2012) Masato Kitamura et al.   SYNTHESIS-STUTTGART

A chemical synthesis of 11-methoxy mitragynine pseudoindoxyl featuring the interrupted Ugi reaction

(2012) Jimin Kim et al.   Chemical Science

Gold-Catalyzed Transformation of 2-Alkynyl Arylazides: Efficient Access to the Valuable Pseudoindoxyl and Indolyl Frameworks

(2011) Alexander Wetzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Umpolung Reactivity of Indole through Gold Catalysis

(2011) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of arynes with amino acid esters

(2011) Kentaro Okuma et al.   CHEMICAL COMMUNICATIONS

Synthesis of a new fluorescent small molecule probe and its use for in vivo lipid imaging

(2011) Jae Hong Lee et al.   CHEMICAL COMMUNICATIONS

Preparation of chiral ruthenium(iv) complexes and applications in regio- and enantioselective allylation of phenols

(2011) Zeyneb Sahli et al.   DALTON TRANSACTIONS

Retention of Regiochemistry and Chirality in the Ruthenium Catalyzed Allylic Alkylation of Disubstituted Allylic Esters

(2011) Motoi Kawatsura et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemoselective and Enantioselective Oxidation of Indoles Employing Aspartyl Peptide Catalysts

(2011) Filip Kolundzic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photo-oxidation of proteins

(2011) David I. Pattison et al.   PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES

Chiral phosphoric acid-catalysed Friedel–Crafts alkylation reaction of indoles with racemic spiro indolin-3-ones

(2011) Qin Yin et al.   Chemical Science

Total Synthesis of (+)-Isatisine A

(2010) Avedis Karadeolian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(IV) Complexes Featuring P,O-Chelating Ligands: Regioselective Substitution Directly from Allylic Alcohols

(2010) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Ruthenium-Catalyzed N-Alkylation of Indoles by Using Alcohols

(2010) Sebastian Bähn et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expedient, one-pot preparation of fused indoles via CAN-catalyzed three-component domino sequences and their transformation into polyheterocyclic compounds containing pyrrolo[1,2-a]azepine fragments

(2010) Padmakar A. Suryavanshi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Regioselective Ruthenium-Catalyzed Allylic Alkylations of Chelated Enolates†

(2010) Anton Bayer et al.   ORGANIC LETTERS

Cationic Ruthenium-Cyclopentadienyl-Diphosphine Complexes as Catalysts for the Allylation of Phenols with Allyl Alcohol; Relation between Structure and Catalytic Performance inO-vs. C-Allylation

(2009) Jimmy A. van Rijn et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Dehydrative Cyclization of ω-Hydroxy Allyl Alcohols Catalyzed by Ruthenium Complexes

(2009) Shinji Tanaka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fast Ruthenium-Catalysed Allylation of Thiols by Using Allyl Alcohols as Substrates

(2009) Alexey B. Zaitsev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkyne-Linked 2,2-Disubstituted-indolin-3-one Oligomers as Extended β-Strand Mimetics

(2009) Pauline N. Wyrembak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid, Selective Ru-Sulfonate-Catalyzed Allylation of Indoles Using Alcohols as Substrates

(2009) Stefan Gruber et al.   ORGANOMETALLICS

Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: Agem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation

(2009) Jimmy A. van Rijn et al.   ORGANOMETALLICS

Preparation of 2,2-disubstituted 1,2-dihydro-3H-indol-3-ones via oxidation of 2-substituted indoles and Mannich-type reaction

(2009) Kazuhiro Higuchi et al.   TETRAHEDRON

Novel [Ruthenium(substituted‐tetramethylcyclopentadiene) (2‐quinolinecarboxylato)(allyl)] Hexafluorophosphate Complexes as Efficient Catalysts for Highly Regioselective Nucleophilic Substitution of Aliphatic Allylic Substrates

(2008) Hui‐Jun Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Regio- and Enantioselective O-Allylation of Phenol and Alcohol Catalyzed by a Planar-Chiral Cyclopentadienyl Ruthenium Complex

(2008) Kiyotaka Onitsuka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Oxidative Rearrangement of 2-Aryl Tryptamine Derivatives

(2008) Mohammad Movassaghi et al.   ORGANIC LETTERS

Allylation ofN-Heterocycles with Allylic Alcohols Employing Self-Assembling Palladium Phosphane Catalysts

(2008) Ippei Usui et al.   ORGANIC LETTERS

Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry

(2008) Stefan Gruber et al.   ORGANOMETALLICS

Synthesis and physical properties of various organic dyes derived from a single core skeleton, 1,2-dihydroindol-3-one

(2008) Shoji Matsumoto et al.   TETRAHEDRON LETTERS