Csp3–H bond functionalization of amines via tunable iminium ions: divergent synthesis of trifluoromethylated arylamines

Redox-Neutral α-C–H Functionalization of Pyrrolidin-3-ol

(2018) Cheng-Bo Yi et al.   ORGANIC LETTERS

Iridium-Catalyzed Dehydrogenative α-Functionalization of (Hetero)aryl-Fused Cyclic Secondary Amines with Indoles

(2018) Xiuwen Chen et al.   ORGANIC LETTERS

Decarboxylative Annulation of α-Amino Acids with β-Ketoaldehydes

(2018) Anirudra Paul et al.   ORGANIC LETTERS

Multicomponent Mannich-Like Reactions of Organometallic Species

(2017) Jérôme Paul et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Selective Ring-Opening of N-Alkyl Pyrrolidines with Chloroformates to 4-Chlorobutyl Carbamates

(2017) Chunghyeon Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct α-C–H bond functionalization of unprotected cyclic amines

(2017) Weijie Chen et al.   Nature Chemistry

Synthesis of Polycyclic Imidazolidinones via Amine Redox-Annulation

(2017) Zhengbo Zhu et al.   ORGANIC LETTERS

Synthesis of 2-(Trifluoromethyl)-dibenzopyranones with Rhodium(III)-catalyzed Formal anti-Michael Addition as Key Step

(2017) Ling Pan et al.   ADVANCED SYNTHESIS & CATALYSIS

Syntheses and Transformations of α-Amino Acids via Palladium-Catalyzed Auxiliary-Directed sp3 C–H Functionalization

(2016) Gang He et al.   ACCOUNTS OF CHEMICAL RESEARCH

Total Synthesis of Millingtonine

(2016) Patrick D. Brown et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2,4-Dinitrophenol-Catalyzed α-C(sp3 )−H and C(sp)−H Bond Functionalization of Cyclic Amines and Alkynes: Highly Regio-/Diastereoselective Synthesis of α-Alkynyl-3-Amino-2-Oxindoles

(2016) Mukesh Kumar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C−H Functionalization

(2016) Longle Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

The cyclopropylimine rearrangement/Povarov reaction cascade for the assembly of pyrrolo[3,2-c]quinoline derivatives

(2016) Jinhui Cai et al.   GREEN CHEMISTRY

Diastereoselective Synthesis of Tetrasubstituted Propargylamines via Hydroamination and Metalation of 1-Alkynes and Their Enantioselective Conversion to Trisubstituted Chiral Allenes

(2016) Mariappan Periasamy et al.   JOURNAL OF ORGANIC CHEMISTRY

Counteranion-Controlled Unprecedented Diastereo- and Enantioselective Tandem Formal Povarov Reaction for Construction of Bioactive Octahydro-Dipyrroloquinolines

(2016) Xiao-Long Yu et al.   ACS Catalysis

4-Trifluoromethyl-p-quinols as dielectrophiles: three-component, double nucleophilic addition/aromatization reactions

(2016) Jinhuan Dong et al.   Scientific Reports

The Azomethine Ylide Route to Amine C–H Functionalization: Redox-Versions of Classic Reactions and a Pathway to New Transformations

(2015) Daniel Seidel   ACCOUNTS OF CHEMICAL RESEARCH

α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp3)–H Coupling

(2015) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Triggered α-C–H Functionalization of Pyrrolidines: Synthesis of Unsymmetrically 2,5-Disubstituted Pyrrolidines

(2015) Yong-Feng Cheng et al.   ORGANIC LETTERS

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

(2014) Andrew McNally et al.   NATURE

The redox-A3 reaction

(2014) Daniel Seidel   Organic Chemistry Frontiers

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Copper(II) Carboxylate Catalyzed α-Alkynylation of Amines

(2013) Deepankar Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis and Structural Revision of the Alkaloid Incargranine B

(2013) Patrick D. Brown et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Double Manipulation of Tetrahydroisoquinolines with Terminal Alkynes and Aldehydes under Copper(I) Catalysis

(2013) Weilong Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral α-Arylation of Amines

(2013) Weijie Chen et al.   ORGANIC LETTERS

1,3-Carbothiolation of 4-(Trifluoromethyl)-p-Quinols: A New Access to Functionalized (Trifluoromethyl)arenes

(2013) Xiao Liu et al.   ORGANIC LETTERS

A walk around the A3-coupling

(2012) Vsevolod A. Peshkov et al.   CHEMICAL SOCIETY REVIEWS

Photoredox functionalization of C–H bonds adjacent to a nitrogen atom

(2012) Lei Shi et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

(2011) Shu̅ Kobayashi et al.   CHEMICAL REVIEWS

Enantioselective Gold-Catalyzed Functionalization of Unreactive sp3 CH Bonds through a Redox-Neutral Domino Reaction

(2011) Guanghua Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction

(2010) Guanghua Zhou et al.   CHEMICAL COMMUNICATIONS

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals

(2007) Chen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY