Journal
ANALYTICAL CHEMISTRY
Volume 90, Issue 7, Pages 4277-4281Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.8b00839
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Funding
- National Natural Science Foundation of China [21327902, 21675080]
- Natural Science Foundation of Jiangsu Province [BK20170073]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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We report herein the energy transfer (ET) between semiconducting polymer dots (Pdots) and gold nanoparticles (Au NPs) in a photoelectrochemical (PEC) system and its feasibility for cathodic bioanalysis application. Specifically, COOH-capped Pdots were first fabricated and then assembled onto the indium tin oxide (ITO) surface, followed by the modification of single-strand (ss) DNA probe (pDNA). After the DNA hybridization with the Au NP tethered complementary ssDNA (Au NPADNA), the Au NPs were brought into the close proximity of Pdots. Upon light stimulation, photoluminescence (PL) was annihilated, fluorescence was attenuated, and the photocurrent intensity was evidently decreased. This ET-based PEC DNA sensor exhibited a linear range from 1 fM to 10 pM with a detection limit of 0.97 fM at a signal-to-noise ratio of 3. The present work first exploited the ET between Pdots and Au NPs, and we believe this phenomenon will spark new interest in the study of various Pdots-based ET-influenced PEC systems and thus catalyze increasing studies for specific bioanalytical purposes.
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