4.6 Article

Trifunctional NiO-Ag-NiO electrodes for ITO-free electrochromic supercapacitors

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 33, Pages 8408-8414

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc03120c

Keywords

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Funding

  1. Jilin Province Science and Technology Research Project [20160520176JH, 20150101039JC]
  2. National Natural Science Foundation of China [51503196]
  3. State Key Laboratory of Luminescence and Applications

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Transparent, conductive, and ITO-free NiO/Ag/NiO (NAN) electrodes, which combined excellent electrochromism and supercapacitance, were successfully fabricated by an easy one-step electron-beam deposition method at room temperature. This NAN film shows a satisfactory average transmittance over 70% in the visible region and extraordinarily low square resistance of only 8.0 Omega square(-1). Large optical modulation (24.3% at 550 nm), fast response time (tau(c) = 4.3 s, tau(b) = 4.0 s) and extremely high coloration efficiency (76.6 cm(2) C-1) are achieved at an EC layer thickness of just 35 nm. Moreover, high specific capacitance (364.0 F g(-1) at 2 A g(-1)), good rate capability, and great long-term cycling stability demonstrated an excellent electrochemical energy storage performance of the NAN film, which can even compete with nanostructured NiO films. Electrochemical kinetics analysis indicates that the essential reasons of such superior comprehensive performances lie in high conductivity, fast charge-transfer, and ion-diffusion dynamics, as well as good contact between Ag and NiO layers.

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