Article
Chemistry, Physical
Wei-Min Zhao, Li Zhu, Zhengwei Nie, Qi-Yuan Li, Qi-Wei Wang, Li-Guo Dou, Ju-Gang Hu, Lede Xian, Sheng Meng, Shao-Chun Li
Summary: The study reveals that moire patterns formed at specific twist angles can trap charge density wave (CDW) states, which persist at room temperature, indicating potential applications in CDW-based technologies.
Article
Materials Science, Multidisciplinary
Shuang-Xing Zhu, Chen Zhang, Qi-Yi Wu, Xiao-Fang Tang, Hao Liu, Zi-Teng Liu, Yang Luo, Jiao-Jiao Song, Fan-Ying Wu, Yin-Zou Zhao, Shu-Yu Liu, Tian Le, Xin Lu, He Ma, Kai-Hui Liu, Ya-Hua Yuan, Han Huang, Jun He, H. Y. Liu, Yu-Xia Duan, Jian-Qiao Meng
Summary: The study on 1T-TiTe2 material revealed the existence of a kink and a flat band, which are more pronounced at low temperatures and become blurred as temperature rises. Ultrafast optical spectroscopy identified multiple distinct time scales, with significant responses to temperature variations.
Article
Chemistry, Multidisciplinary
Mingqiang Ren, Fangjun Cheng, Yufei Zhao, Mingqiang Gu, Qiangjun Cheng, Binghai Yan, Qihang Liu, Xucun Ma, Qikun Xue, Can-Li Song
Summary: Nontrivial electronic states in low-dimensional physics have attracted significant attention. This study reports the observation of a 2 x 2 chiral CDW and the strong suppression of Te-5p hole-band backscattering in monolayer 1T-TiTe2 using scanning tunneling microscopy. Theoretical calculations show that the chirality comes from a helical stacking of the triple-q CDW components and can persist at the two-dimensional limit. The chirality also gives the Te-5p bands an unconventional orbital texture that prohibits electron backscattering. These findings establish TiTe2 as a promising system for manipulating chiral ground states and engineering electronic properties.
Article
Materials Science, Multidisciplinary
Jiayuan Zhang, Fei Wang, Chao-Sheng Lian
Summary: In this study, the distorted lattice and associated energy band renormalization of TiTe2 and ZrTe2 monolayers were investigated using first-principles calculations. It was found that both systems exhibit a soft phonon mode at the M point leading to a 2x2 CDW order, and the CDW phases of monolayer TiTe2 and ZrTe2 maintain semimetallicity. The role of exchange interaction in CDW formation was also explored.
Article
Materials Science, Multidisciplinary
Samuel Beaulieu, Michael Schueler, Jakub Schusser, Shuo Dong, Tommaso Pincelli, Julian Maklar, Alexander Neef, Friedrich Reinert, Martin Wolf, Laurenz Rettig, Jan Minar, Ralph Ernstorfer
Summary: Researchers identified the role of orbital texture in photoemission in crystalline solids through experiments and theoretical calculations, demonstrating the link between momentum-dependent orbital orientation and the emergence of linear dichroism in photoelectron angular distributions. This result is an important step towards understanding electronic wavefunction and orbital texture by exploiting matrix element effects in photoemission spectroscopy beyond band structure mapping.
NPJ QUANTUM MATERIALS
(2021)
Article
Physics, Applied
Weijian Li, Gururaj V. Naik
Summary: Light can change the way CDW domains stack in 1T-TaS2 and affect its optical properties, but the mechanism of light-induced stacking reorganization is not fully understood. Research shows that optical tunability peaks at 250K due to the conflicting effects of larger domains at lower temperatures and less favorable stacking reorganization energetics.
APPLIED PHYSICS LETTERS
(2021)
Article
Multidisciplinary Sciences
Bin Lei, Donghui Ma, Shihao Liu, Zeliang Sun, Mengzhu Shi, Weizhuang Zhuo, Fanghang Yu, Genda Gu, Zhenyu Wang, Xianhui Chen
Summary: This work presents a novel ionic field-effect transistor (iFET) utilizing solid Gd-doped CeO2 as the gate dielectric, which demonstrates exceptional carrier-density-tuning ability through electric-field-controlled oxygen concentration at room temperature. By driving oxygen ions in and out of Bi-2212 thin flakes with electric fields, we achieve a reversible superconductor-insulator transition and map out the phase diagram. Our findings provide a pathway for electric-field control of phase transition in correlated oxides.
NATIONAL SCIENCE REVIEW
(2022)
Article
Materials Science, Multidisciplinary
Xiaxin Ding, Jie Xing, Gang Li, Luis Balicas, Krzysztof Gofryk, Hai-Hu Wen
Summary: The magnetic and magnetotransport properties of metallic 1T-VTe2 single crystals were investigated at temperatures ranging from 1.3 to 300 K and in magnetic fields up to 35 T. The study found a crossover in electrical resistivity from single-impurity Kondo effect to Fermi liquid behavior at low temperatures under high magnetic fields, with detailed characteristics related to intercalated V ions. The temperature-dependent resistivity under various magnetic fields was successfully described, showing a characteristic peak below the Kondo temperature due to the splitting of the Kondo resonance.
Article
Chemistry, Inorganic & Nuclear
Hanlin Wu, Sheng Li, Wenhao Liu, Bing Lv
Summary: We investigate the multiple-intercalation stages and superconductivity of 1T-SnSe2 through Li and organic molecule co-intercalation. By controlling the reaction times and concentrations, we discover well-separated co-intercalation stages with different stacking patterns and enhanced superconducting Tc. Through co-intercalation with Li and various organic species, such as acetone, DMSO, and THF, we observe an increased superconducting Tc compared to solely Li-intercalated SnSe2. These findings provide insights into the electronic structure tuning and offer a new strategy for engineering the physical properties of layered materials through different intercalation stages control.
INORGANIC CHEMISTRY
(2023)
Article
Physics, Multidisciplinary
Xiao-Fang Tang, Shuang-Xing Zhu, Hao Liu, Chen Zhang, Qi-Yi Wu, Zi-Teng Liu, Jiao-Jiao Song, Xiao Guo, Yong-Song Wang, He Ma, Yin-Zou Zhao, Fan-Ying Wu, Shu-Yu Liu, Kai-Hui Liu, Ya-Hua Yuan, Han Huang, Jun He, Wen Xu, Hai-Yun Liu, Yu-Xia Duan, Jian-Qiao Meng
Summary: High-quality large 1T phase of TiX (2) (X = Te, Se, and S) single crystals were grown by chemical vapor transport method using iodine as a transport agent. Raman spectroscopy analysis revealed several phonon modes, including both commonly reported and rarely reported modes, as well as unexpected phonon changes that may be related to charge density wave phase transition. These findings contribute to the understanding of the charge density wave and superconductivity in TiX (2) materials.
Article
Multidisciplinary Sciences
Junyu Zong, Zhao-Yang Dong, Junwei Huang, Kaili Wang, Qi-Wei Wang, Qinghao Meng, Qichao Tian, Xiaodong Qiu, Yuyang Mu, Li Wang, Wei Ren, Xuedong Xie, Wang Chen, Yongheng Zhang, Can Wang, Fang-Sen Li, Shao-Chun Li, Jian-Xin Li, Hongtao Yuan, Yi Zhang
Summary: In this study, the van Hove singularity (VHS) in the epitaxial monolayer (ML) 1T-VSe2 film was successfully manipulated by the giant magnified dielectric constant er of SrTiO3(111) substrate with cooling, leading to a two-dimensional (2D) itinerant ferromagnetic state below 3.3 K. The manipulation of VHS was ascribed to the physical origin of the itinerant ferromagnetic state in ML 1T-VSe2, as supported by angle-resolved photoemission spectroscopy (ARPES) and theoretical analysis. These findings demonstrate the potential of controlling the ferromagnetic state in 2D systems through VHS engineering, expanding the application possibilities of 2D magnets for next-generation information technology.
Article
Chemistry, Multidisciplinary
Qi Sui, He-Chong Wang, Yan-Yan Zhang, Rong Sun, Xin-Xin Jin, Bing-Wu Wang, Lin Wang, Song Gao
Summary: Manipulating the radical concentration in solid multifunctional materials is an attractive topic in various fields. In this study, two crystalline compounds with different molecule-conjugated systems were designed and synthesized, based on the model of viologens. It was found that applying pressure to the viologens led to higher radical concentrations and more sensitive piezochromic behaviors in cross-conjugated compounds compared to linear-conjugated ones. Interestingly, the electrical resistance of one compound decreased significantly with increasing pressure, while the high-radical-concentration compound showed almost no change, contradicting the conventional wisdom regarding the relationship between radicals and conductivity.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Physical
Zhuangchai Lai, Qiyuan He, Thu Ha Tran, D. V. Maheswar Repaka, Dong-Dong Zhou, Ying Sun, Shibo Xi, Yongxin Li, Apoorva Chaturvedi, Chaoliang Tan, Bo Chen, Gwang-Hyeon Nam, Bing Li, Chongyi Ling, Wei Zhai, Zhenyu Shi, Dianyi Hu, Vinay Sharma, Zhaoning Hu, Ye Chen, Zhicheng Zhang, Yifu Yu, Xiao Renshaw Wang, Raju Ramanujan, Yanming Ma, Kedar Hippalgaonkar, Hua Zhang
Summary: A general synthetic method for large-scale preparation of high-purity metastable 1T'-phase transition metal dichalcogenide crystals, including WS2, WSe2, MoS2, MoSe2, WS2xSe2(1-x) and MoS2xSe2(1-x), has been reported. The crystal structures of 1T'-WS2, -WSe2, -MoS2 and -MoSe2 were solved using single-crystal X-ray diffraction. The as-prepared 1T'-WS2 showed thickness-dependent intrinsic superconductivity, demonstrating critical transition temperatures of 8.6 K for a thickness of 90.1 nm and 5.7 K for a single layer, attributed to its high intrinsic carrier concentration and semi-metallic nature. This synthesis method will facilitate a more systematic investigation of the intrinsic properties of metastable TMDs.
Article
Physics, Multidisciplinary
T. Jaouen, A. Pulkkinen, M. Rumo, G. Kremer, B. Salzmann, C. W. Nicholson, M. -L. Mottas, E. Giannini, S. Tricot, B. Hildebrand, C. Monney, P. Schieffer
Summary: Using angle-resolved photoemission spectroscopy, first principle and coupled self-consistent Poisson-Schrodinger calculations, the researchers demonstrate the creation of a two-dimensional electron gas and quantum confinement of its charge-density wave at the surface of 1T-TiSe2 due to potassium adsorption. By adjusting the potassium coverage, the carrier density within the two-dimensional electron gas can be tuned to nullify the energy gain from exciton condensation in the charge-density wave phase while maintaining long-range structural order. This study provides a prime example of a controlled exciton-related many-body quantum state in reduced dimensionality through alkali-metal dosing.
PHYSICAL REVIEW LETTERS
(2023)
Article
Multidisciplinary Sciences
Mengke Liu, Joshua Leveillee, Shuangzan Lu, Jia Yu, Hyunsue Kim, Cheng Tian, Youguo Shi, Keji Lai, Chendong Zhang, Feliciano Giustino, Chih-Kang Shih
Summary: Research on monolayer group V transition metal dichalcogenides in their 1T phase has shown that 1T-NbSe2 is a charge transfer insulator with electron correlation-induced magnetic properties. By creating a vertical 1T/2H NbSe2 heterostructure, exchange interactions between localized magnetic moments in the 1T phase and the metallic/superconducting phase were confirmed.
Article
Chemistry, Multidisciplinary
Sean M. Walker, Tarun Patel, Junichi Okamoto, Deler Langenberg, E. Annelise Bergeron, Jingjing Gao, Xuan Luo, Wenjian Lu, Yuping Sun, Adam W. Tsen, Jonathan Baugh
Summary: This study investigates the properties of ultrathin 1T-TaS2 and reveals the presence of nonequilibrium phases consisting of intertwined NC-like and C-like domains. The relationship between electronic inhomogeneity and bulk resistivity in ultrathin 1T-TaS2 is also explored.
Article
Chemistry, Physical
Wenhao Zhang, Degong Ding, Jingjing Gao, Kunliang Bu, Zongxiu Wu, Li Wang, Fangsen Li, Wei Wang, Xuan Luo, Wenjian Lu, Chuanhong Jin, Yuping Sun, Yi Yin
Summary: Intercalation is an effective method to modify physical properties and induce novel electronic states of transition metal dichalcogenide materials. In this study, the successful synthesis of copper-intercalated 1T-TaS2 is reported, and the structural and electronic modifications are characterized using various techniques. The intercalated copper atom suppresses the commensurate charge density wave phase and two specific electronic modulations are discovered in the near-commensurate charge density wave phase.
Article
Chemistry, Multidisciplinary
Yanan Huang, Jianguo Si, Shuai Lin, Hongyan Lv, Wenhai Song, Ranran Zhang, Xuan Luo, Wenjian Lu, Xuebin Zhu, Yuping Sun
Summary: This study reports the colossal 3D electrical anisotropy of layered MAB-phase MoAlB single crystal. Through experimental and theoretical investigations, it is demonstrated that the crystal structure, chemical bond, phonon vibration, and electronic structure of MoAlB result in its significant electrical conductivity anisotropy. This work provides valuable insights for the design of functional electronic devices and the synthesis of new 2D materials.
Article
Multidisciplinary Sciences
Jianchao Lin, Peng Tong, Kai Zhang, Kun Tao, Wenjian Lu, Xianlong Wang, Xuekai Zhang, Wenhai Song, Yuping Sun
Summary: Emerging caloric cooling technology provides a green alternative to conventional vapor-compression technology. This study reports the barocaloric effect associated with liquid-solid transition in n-alkanes, showing that applying pressure to the liquid state can induce a colossal BC effect.
NATURE COMMUNICATIONS
(2022)
Correction
Engineering, Electrical & Electronic
Arnab Bose, Nathaniel J. Schreiber, Rakshit Jain, Ding-Fu Shao, Hari P. Nair, Jiaxin Sun, Xiyue S. Zhang, David A. Muller, Evgeny Y. Tsymbal, Darrell G. Schlom, Daniel C. Ralph
NATURE ELECTRONICS
(2022)
Article
Physics, Applied
Linlin An, Jianguo Si, Xiangde Zhu, Chuanying Xi, Nanyang Xu, Yuanjun Yang, Lan Wang, Wei Ning, Wenjian Lu, Mingliang Tian
Summary: We report experimental studies on the angular-dependent magnetoresistance (MR) of In3Rh single crystals under high magnetic fields. The crystals exhibit large, non-saturating linear MR and remarkable quantum oscillations with multi-frequencies. Analysis of the quantum oscillations reveals the presence of three bands hosting a nontrivial Berry phase, which is supported by first-principles calculations. Our work provides a platform for exploring topological materials in indium-rich transition metal compounds.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Physical
Xin Liang, Ding-Fu Shao, Run Lv, Rui-Chun Xiao, Hong-Yan Lv, Wen-Jian Lu, Yu-Ping Sun
Summary: Based on symmetry analyses and first-principles calculations, the predictions of topological fermions and superconductivity in Ni-intercalated transition metal chalcogenide NiTe are reported. The self-intercalation of Ni introduces nonsymmorphic symmetry operations, protecting a pair of Dirac points and three intersecting Dirac nodal lines near Fermi energy level (EF), which generate spin-textured surface states across EF. Moreover, the Ni-intercalation strongly enhances electron-phonon coupling in NiTe and makes it an anisotropic Bardeen-Cooper-Schrieffer superconductor with a full superconducting gap and a critical temperature Tc similar to 1.5 K. The coexistence of topological surface states and superconductivity implies that NiTe is a potential material platform for exploring topological superconductivity.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Tengfei Cao, Ding-Fu Shao, Kai Huang, Gautam Gurung, Evgeny Y. Tsymbal
Summary: Based on symmetry analyses and density-functional calculations, this study explores the emergence of the anomalous Hall effect (AHE) in antiferromagnetic MnBi2Te4 films assembled by polar layer stacking. Breaking PT symmetry in an MnBi2Te4 bilayer produces a magnetoelectric effect and a spontaneous AHE switchable by electric polarization. Reversible polarization at one of the interfaces in a three-layer MnBi2Te4 film drives a metal-insulator transition, as well as switching between the AHE and quantum AHE (QAHE). Engineering interlayer polarization in a three-layer MnBi2Te4 film allows converting MnBi2Te4 from a trivial insulator to a Chern insulator.
Article
Chemistry, Physical
D. C. Mahendra, Ding-Fu Shao, Vincent D. -H. Hou, Arturas Vailionis, P. Quarterman, Ali Habiboglu, M. B. Venuti, Fen Xue, Yen-Lin Huang, Chien-Min Lee, Masashi Miura, Brian Kirby, Chong Bi, Xiang Li, Yong Deng, Shy-Jay Lin, Wilman Tsai, Serena Eley, Wei-Gang Wang, Julie A. Borchers, Evgeny Y. Tsymbal, Shan X. Wang
Summary: By utilizing unconventional spins generated in a MnPd3 thin film grown on an oxidized silicon substrate, the authors observed both conventional spin-orbit torques and unconventional out-of-plane and in-plane anti-damping-like torques in MnPd3/CoFeB heterostructures, enabling complete field-free switching of perpendicular cobalt. These unconventional torques are attributed to the low symmetry of the (114)-oriented MnPd3 films. The results provide a path towards practical spin channels in ultrafast magnetic memory and logic devices.
Article
Physics, Multidisciplinary
Ding-Fu Shao, Yuan-Yuan Jiang, Jun Ding, Shu-Hui Zhang, Zi-An Wang, Rui-Chun Xiao, Gautam Gurung, W. J. Lu, Y. P. Sun, Evgeny Y. Tsymbal
Summary: It is demonstrated that fully compensated antiferromagnets can support Néel spin currents, which can be used to drive spin-dependent transport phenomena in antiferromagnetic tunnel junctions (AFMTJs). The study uncovers the potential of fully compensated antiferromagnets and opens a new route for efficient information writing and reading in antiferromagnetic spintronics.
PHYSICAL REVIEW LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Tengfei Cao, Guodong Ren, Ding -Fu Shao, Evgeny Y. Tsymbal, Rohan Mishra
Summary: The recent observation of ferroelectricity in binary metal oxides, such as HfO2, ZrO2, Hf0.5Zr0.5O2, and Ga2O3, has attracted much attention. Hole doping is proposed to play a key role in stabilizing polar phases in these oxides. First-principles calculations demonstrate that holes mainly occupy one of the oxygen sublattices and their localization enhances the electrostatic energy of the system, making the polar phase more stable at high concentrations. The electrostatic mechanism is responsible for the stabilization of the ferroelectric phase in HfO2 doped with elements that introduce holes to the system.
PHYSICAL REVIEW MATERIALS
(2023)
Article
Multidisciplinary Sciences
Cuimei Cao, Shiwei Chen, Rui-Chun Xiao, Zengtai Zhu, Guoqiang Yu, Yangping Wang, Xuepeng Qiu, Liang Liu, Tieyang Zhao, Ding-Fu Shao, Yang Xu, Jingsheng Chen, Qingfeng Zhan
Summary: Cubic materials are not expected to exhibit anisotropy in transport phenomena, but we report an anomalous anisotropy of spin current in the (001) film of the noncollinear antiferromagnetic spin source Mn3Pt. This anisotropy originates from the intertwined time reversal-odd and time reversal-even spin Hall effects. By analyzing the symmetry and characterizing the current-induced spin torques in Mn3Pt-based heterostructures, we find that the spin current in Mn3Pt (001) exhibits exotic dependencies on the current direction for all spin components, deviating from that in conventional cubic systems.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Ding-Fu Shao, Shu-Hui Zhang, Rui-Chun Xiao, Zi-An Wang, W. J. Lu, Y. P. Sun, Evgeny Y. Tsymbal
Summary: In this study, we demonstrate the realization of a spin-neutral tunneling anomalous Hall effect (TAHE) in an antiferromagnetic (AFM) tunnel junction driven by spin-neutral currents. We show that the symmetry mismatch between the AFM electrode and the nonmagnetic barrier with strong spin-orbit coupling (SOC) results in spin-dependent momentum filtering, generating transverse Hall currents in each electrode. This finding opens up new possibilities for research in magnetoelectronics and spintronics.
Article
Physics, Multidisciplinary
J. Yan, Z. Z. Jiang, R. C. Xiao, W. J. Lu, W. H. Song, X. B. Zhu, X. Luo, Y. P. Sun, M. Yamashita
Summary: This study investigates the magnetotransport properties of EuIn2As2 through detailed magnetoresistance and Hall measurements, revealing anomalous Hall effect and large topological Hall effect, suggesting their origins and providing insights for realizing axion insulator states.
PHYSICAL REVIEW RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Jian-Guo Si, Wen-Jian Lu, Yu-Ping Sun, Peng-Fei Liu, Bao-Tian Wang
Summary: The origin of the charge density wave (CDW) order and the superconducting properties of CsV3Sb5 under pressure are studied using first-principles calculations. The momentum-dependent electron-phonon coupling effect is found to play an important role in the formation of CDW order, and the experimentally observed double superconducting domes can be explained by the movement of the van Hove singularity and the redistribution of the electron-phonon coupling. The main contribution to the electron-phonon coupling shifts from in-plane vibrational modes to out-of-plane modes with increasing pressure.
Article
Materials Science, Multidisciplinary
Mengjiao Dong, Liyun Liao, Chensheng Li, Yingxiao Mu, Yanping Huo, Zhong-Min Su, Fushun Liang
Summary: This study investigates the influence of the polarity of polymer matrices on persistent room-temperature phosphorescence (pRTP). It is discovered that intense phosphorescence emission can be achieved in highly polar matrices such as polyacrylic acid (PAA). The dipole-dipole interaction between the polar fluorophore and polar matrix is proposed to stabilize the excited state and facilitate the generation of efficient room-temperature phosphorescence emissions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Han-Jiang Yang, Weijia Xiang, Xiangzhou Zhang, Jin-Yun Wang, Liang-Jin Xu, Zhong-Ning Chen
Summary: This article reports a 2D copper(I)-based cluster material for X-ray imaging, which exhibits ultra-high spatial resolution, high photoluminescence efficiency, and low detection limit. The material shows excellent linear response to X-ray dose rates and light output, and has the best spatial resolution among reported lead-free metal halide hybrids.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Review
Materials Science, Multidisciplinary
Taek Joon Kim, Sang-hun Lee, Dayeong Kwon, Jinsoo Joo
Summary: Donor-acceptor heterostructures using organic-inorganic halide perovskites, two-dimensional transition metal dichalcogenides, pi-conjugated organic small/macro molecules, and quantum dots are promising platforms for exciton-based photonics and optoelectronics. Hetero-interlayer excitons and hetero-intermolecular excitons formed through optical and/or electrical charge transfer in various heterostructures are important quasi-particles for light emission, detection, and harvesting systems.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Liemao Cao, Xiaohui Deng, Zhen-kun Tang, Rui Tan, Yee Sin Ang
Summary: We investigate the interface properties between WSi2N4 and Mo2B, O-modified Mo2B, and OH-modified Mo2B nanosheets. We find that WSi2N4 and Mo2B form n-type Schottky contacts, while functionalizing Mo2B with O and OH leads to the formation of both n-type and p-type ohmic contacts with WSi2N4. Additionally, we demonstrate the emergence of quasi-ohmic contact with ultralow lateral Schottky barrier and zero vertical interfacial tunneling barriers in Mo2B(OH)2-contacted WSi2N4.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ga Eun Kim, Hae-Jin Kim, Heesuk Jung, Minwoo Park
Summary: This study presents a solution to the commercialization challenges of flexible LEDs based on MAPbBr(3) by incorporating polyurethane and an In-Ga-Zn-Sn liquid alloy. The designed devices showed high flexibility, efficiency, and durability, with improved electron injection and reduced defects, making them promising for next-generation displays.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tao Shen, Zeng Wu, Zhen Jiang, Dongsheng Yan, Yan Zhao, Yang Wang, Yunqi Liu
Summary: Sidechain engineering is an important molecular design strategy for tuning the solid-state packing and structural ordering of conjugated polymers. The effects of sidechain direction on the optoelectronic properties of polymers and device performance were systematically investigated in this study. The results demonstrate that tuning the sidechain substitution direction can effectively improve the molecular structure and light absorption properties of polymers, providing new insights for the rational design of functional polymers.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Lotte Clinckemalie, Bapi Pradhan, Roel Vanden Brande, Heng Zhang, Jonathan Vandenwijngaerden, Rafikul Ali Saha, Giacomo Romolini, Li Sun, Dirk Vandenbroucke, Mischa Bonn, Hai I. Wang, Elke Debroye
Summary: In this study, a facile strategy using a non-conductive polymer was proposed to fabricate stable, pinhole-free thick films. The effect of introducing a second phase into CsPbBr3 perovskite crystals on their photophysical properties and charge transport was investigated. The dual phase devices exhibited improved stability and more effective operation at higher voltages in X-ray detection.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jingye Zou, Shenglan Hao, Pascale Gemeiner, Nicolas Guiblin, Omar Ibder, Brahim Dkhil, Charles Paillard
Summary: When rare-earth ions are embedded in a ferroelectric material, their photoluminescence can serve as an all-optical probe for temperature, electric field, and mechanical stimulus. However, the impact of ferroelectric phase transitions on photoluminescence is not well understood. In this study, we demonstrate changes in the photoluminescence of green emission bands during critical ferroelectric transitions in an Er-doped BaTiO3 material. We also find that the intensity ratio and wavelength position difference of sub-peaks provide information on the phase transitions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jiangchao Han, Daming Zhou, Wei Yang, Chen Lv, Xinhe Wang, Guodong Wei, Weisheng Zhao, Xiaoyang Lin, Shengbo Sang
Summary: Rare type-II spin-gapless semiconductors (SGSs) have attracted increasing attention due to their unique spin properties. In this study, the interface contacts and spin transport properties of different devices composed of VSi2P4 ferromagnetic layers were investigated. The results show that VSi2P4 is a promising material for designing vertical van der Waals heterostructures with a giant tunnel magnetoresistance (TMR) in spintronic applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tianqi Zhao, Renagul Abdurahman, Qianting Yang, Ruxiangul Aiwaili, Xue-Bo Yin
Summary: In this study, we designed and prepared Cr and Ba-doped gamma-Ga2O3 nanoparticles to achieve near-infrared emission and enhance the emission intensity. The emission mechanism was proposed based on the trap depth, band gap, and energy levels of Cr ions. The ratiometric temperature sensing and encryption information transfer demonstrated the potential applications of this technology.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Shuvankar Gupta, Jyotirmoy Sau, Manoranjan Kumar, Chandan Mazumdar
Summary: In this study, a new spin-gapless semiconductor material CoFeMnSn is reported, and its stable structure and spin-polarized band structure are determined through experimental realization and theoretical calculations. The compound exhibits a high ferromagnetic transition temperature, making it excellent for room temperature applications. The nearly temperature-independent resistivity, conductivity, and carrier concentration of the compound, adherence to the Slater-Pauling rule, and the high intrinsic anomalous Hall conductivity achieved through hole doping further confirm its spin-gapless semiconductor nature. Additionally, the compound's SGS and topological properties make it suitable for spintronics and magneto-electronics devices.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ikumi Aratani, Yoji Horii, Yoshinori Kotani, Hitoshi Osawa, Hajime Tanida, Toshiaki Ina, Takeshi Watanabe, Yohko F. Yano, Akane Mizoguchi, Daisuke Takajo, Takashi Kajiwara
Summary: In this study, two-dimensional arrays of single-molecule magnets (SMMs) based on metal-organic frameworks (MOFs) were systematically modified through Langmuir-Blodgett methods and chemical modifications. The introduction of bulky alkoxide groups induced structural changes and perpendicular magnetic anisotropy. This research provides a promising strategy for the construction of high-density magnetic memory devices using molecular spintronics.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Zonghao Lei, Houhe Dong, Lijie Sun, Bing Teng, Yanfei Zou, Degao Zhong
Summary: Researchers have successfully developed four different up-conversion phosphors based on the Eulytite-type host Ba3Yb(PO4)(3). The optical temperature sensing properties of these phosphors were thoroughly investigated, and it was found that Ba3Yb(PO4)(3):Tm/Er/Ho showed potential for optical temperature measurement applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
C. Roncero-Barrero, M. A. Carvajal, J. Ribas-Arino, I. de P. R. Moreira, M. Deumal
Summary: This study computationally investigates the conductivity of four isostructural compounds with different Se contents, and reveals the parameters that define their conductivity in stable organic radical materials. The results provide insights into the influence of Se content on the conductivity and highlight the importance of considering multiple parameters in understanding the trends in conductivity.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Remi Arras, Kedar Sharma, Lionel Calmels
Summary: In this study, we investigated the interplay between structural defects in NiFe2O4, showing that the complex formed by a Ni-Oh/Fe-Td-cation swap and a neutral oxygen vacancy is more stable than these two isolated defects, and significantly reduces the width of the minority-spin band gap.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)